49, 1001 Cantrell, Christopher A Atmospheric Chemistry Division/NESL/NCAR HO2 and HO2+RO2 from PeRCIMS at Manitou Experimental Forest BEACHON-RoMBAS 1,1 2011, 08, 27, 2011, 12, 03 0 Start_MST, seconds, number_of_seconds_from_0000_MST 6 1,1,1,1,1,1 -99999,-99999,-99999,-99999,-99999,-99999 Stop_MST, seconds, number_of_seconds_from_0000_MST Mid_MST, seconds, number_of_seconds_from_0000_MST HO2, pptv, HO2_mixing_ratio HO2_uncertainty, pptv, HO2_2_sigma_uncertainty HO2+RO2, pptv, HO2+RO2_mixing_ratio HO2+RO2_uncertainty, pptv, HO2+RO2_2_sigma_uncertainty 5 These data are reduced using four factors determined in the laboratory and in the field: F_lo and F_hi are the radical sensitivities in the HO2+RO2 and HO2 modes, respectively (units pptv/ion ratio). Alpha_lo and alpha_hi are the ratios of RO2 to HO2 sensitivity in the HO2+RO2 and HO2 modes, respectively. HO2+RO2 concentrations are then S_lo*F_lo-(S_lo*F_lo - S_hi*F_hi)*(alpha_lo - 1)/(alpha_lo - alpha_hi) . HO2 concentrations are S_lo*F_lo-(S_lo*F_lo - S_hi*F_hi)*(alpha_lo)/(alpha_lo - alpha_hi) . S_lo is the background corrected ion ratio in the HO2+RO2 mode, and S_hi is the background corrected ion ratio in the HO2 mode. The ion ratios are mass 97 signal count rate minus background count rate divided by mass 62 count rate. 24 PI_CONTACT_INFO: 303-497-1479, NCAR, 3090 Center Green Dr., Boulder, CO 80301, cantrell@ucar.edu PLATFORM: Seacontainer #1 LOCATION: Manitou Experimental Forest, Woodland Park, Colorado, USA ASSOCIATED_DATA: N/A INSTRUMENT_INFO: These data were collected using a CIMS based instrument. An inlet collects ambient air from the free air stream and adds reagents, includling O2 or N2 diluents, and NO and SO2 reagent gases. This method, called oxygen dilution modulation leads to nearly 100% measurement of HO2 and RO2 in the O2 dilution/low reagent concentration mode, whereas RO2 is measured with less than 15% efficiency in the N2 dilution/higher reagent concentration mode. This is because the chemistry converts peroxy radicals to H2SO4 efficiently in the O2 mode, but RO2 radicals are converted to RONO in the N2 mode. The H2SO4 thus produced is ionized by reaction with NO3- ions. The reagent and product ions are detected by mass spectrometry using quadrupole mass filtering and counting by a channel electron multiplier operating in the negative ion mode. DATA_INFO: Signal data for HO2+RO2 are collected during the 0-7 second time interval, and for HO2 in 30-37 second time interval. UNCERTAINTY: approximately 35% (2 sigma) for values well above 2 pptv; estimates are listed for each data point (2 sigma) ULOD_FLAG: -7777 ULOD_VALUE: N/A LLOD_FLAG: -8888 LLOD_VALUE: N/A DM_CONTACT_INFO: N/A PROJECT_INFO: BEACHON-RoMBAS, 20-Jul-2011 to 30-Aug-2011 STIPULATIONS_ON_USE: contact PI BEFORE use/presentation/publication OTHER_COMMENTS: REVISION: R1; R0 R1: final data R0: preliminary data Start_MST,Stop_MST,Mid_MST,HO2,HO2_uncertainty,HO2+RO2,HO2+RO2_uncertainty 0,59,30,1.60,4.00,5.90,4.20 60,119,90,1.60,4.00,5.50,4.20 120,179,150,2.30,4.00,5.40,4.20 180,239,210,3.60,4.10,6.00,4.20 240,299,270,4.40,4.10,6.40,4.20 300,359,330,5.00,4.10,6.60,4.30 360,419,390,4.90,4.10,7.90,4.40 420,479,450,5.30,4.20,10.20,4.60 480,539,510,3.70,4.10,13.00,4.90 540,599,570,2.90,4.00,14.70,5.20 600,659,630,2.80,4.00,14.50,5.10 660,719,690,4.10,4.10,12.40,4.80 720,779,750,4.60,4.10,10.50,4.60 780,839,810,4.50,4.10,12.10,4.80 840,899,870,3.50,4.10,12.20,4.80 900,959,930,3.10,4.10,11.30,4.70 960,1019,990,2.10,4.00,9.10,4.50 1020,1079,1050,2.80,4.00,8.80,4.40 1080,1139,1110,3.40,4.10,7.90,4.40 1140,1199,1170,6.10,4.20,7.00,4.30 1200,1259,1230,6.10,4.20,7.60,4.30 1260,1319,1290,5.30,4.20,7.30,4.30 1320,1379,1350,3.30,4.10,7.50,4.30 1380,1439,1410,3.40,4.10,7.30,4.30 1440,1499,1470,3.10,4.10,7.60,4.30 1500,1559,1530,2.20,4.00,6.10,4.20 1560,1619,1590,3.20,4.10,4.70,4.10 1620,1679,1650,4.60,4.10,5.30,4.20 1680,1739,1710,6.30,4.20,6.70,4.30 1740,1799,1770,5.00,4.10,6.50,4.30 1800,1859,1830,5.60,4.20,7.20,4.30 1860,1919,1890,4.80,4.10,8.20,4.40 1920,1979,1950,4.90,4.10,7.40,4.30 1980,2039,2010,6.50,4.20,9.60,4.50 2040,2099,2070,6.30,4.20,9.20,4.50 2100,2159,2130,6.80,4.30,12.80,4.90 2160,2219,2190,3.60,4.10,10.30,4.60 2220,2279,2250,3.70,4.10,10.70,4.60 2280,2339,2310,3.10,4.10,8.50,4.40 2340,2399,2370,3.70,4.10,8.40,4.40 2400,2459,2430,3.80,4.10,8.60,4.40 2460,2519,2490,4.00,4.10,8.50,4.40 2520,2579,2550,4.10,4.10,8.10,4.40 2580,2639,2610,4.60,4.10,9.00,4.50 2640,2699,2670,4.40,4.10,14.40,5.10 2700,2759,2730,3.60,4.10,15.90,5.30 2760,2819,2790,3.60,4.10,16.10,5.30 2820,2879,2850,3.80,4.10,11.00,4.70 2880,2939,2910,3.80,4.10,9.60,4.50 2940,2999,2970,2.60,4.00,7.10,4.30 3000,3059,3030,3.30,4.10,10.30,4.60 3060,3119,3090,3.90,4.10,12.00,4.80 3120,3179,3150,4.30,4.10,12.10,4.80 3180,3239,3210,4.00,4.10,12.30,4.80 3240,3299,3270,4.00,4.10,11.90,4.80 3300,3359,3330,4.50,4.10,14.30,5.10 3360,3419,3390,4.90,4.10,11.00,4.70 3420,3479,3450,5.70,4.20,12.60,4.90 3480,3539,3510,4.70,4.10,11.30,4.70 3540,3599,3570,4.40,4.10,12.70,4.90 3600,3659,3630,4.20,4.10,13.40,5.00 3660,3719,3690,5.70,4.20,13.60,5.00 3720,3779,3750,5.70,4.20,13.70,5.00 3780,3839,3810,4.70,4.10,10.30,4.60 3840,3899,3870,5.40,4.20,11.20,4.70 3900,3959,3930,5.60,4.20,10.00,4.60 3960,4019,3990,6.00,4.20,10.10,4.60 4020,4079,4050,4.40,4.10,8.60,4.40 4080,4139,4110,4.10,4.10,9.10,4.50 4140,4199,4170,4.10,4.10,9.00,4.50 4200,4259,4230,4.30,4.10,10.20,4.60 4260,4319,4290,4.50,4.10,11.60,4.80 4320,4379,4350,4.60,4.10,11.50,4.70 4380,4439,4410,5.50,4.20,13.10,4.90 4440,4499,4470,5.60,4.20,13.20,4.90 4500,4559,4530,4.70,4.10,14.00,5.00 4560,4619,4590,3.60,4.10,11.70,4.80 4620,4679,4650,3.40,4.10,13.40,5.00 4680,4739,4710,4.00,4.10,12.40,4.80 4740,4799,4770,3.50,4.10,10.40,4.60 4800,4859,4830,4.00,4.10,8.60,4.40 4860,4919,4890,2.80,4.00,8.90,4.50 4920,4979,4950,3.60,4.10,12.00,4.80 4980,5039,5010,2.90,4.10,10.50,4.60 5040,5099,5070,3.30,4.10,13.40,5.00 5100,5159,5130,3.40,4.10,11.80,4.80 5160,5219,5190,3.80,4.10,10.60,4.60 5220,5279,5250,4.80,4.10,8.10,4.40 5280,5339,5310,3.30,4.10,8.20,4.40 5340,5399,5370,2.10,4.00,7.80,4.40 5400,5459,5430,2.20,4.00,9.40,4.50 5460,5519,5490,3.40,4.10,10.20,4.60 5520,5579,5550,3.90,4.10,11.60,4.70 5580,5639,5610,3.90,4.10,11.90,4.80 5640,5699,5670,2.90,4.10,12.90,4.90 5700,5759,5730,2.20,4.00,13.90,5.00 5760,5819,5790,0.40,4.00,10.80,4.70 5820,5879,5850,0.60,4.00,8.20,4.40 5880,5939,5910,1.80,4.00,8.40,4.40 5940,5999,5970,2.70,4.00,9.60,4.50 6000,6059,6030,3.20,4.10,8.40,4.40 6060,6119,6090,3.30,4.10,8.90,4.50 6120,6179,6150,4.00,4.10,11.10,4.70 6180,6239,6210,5.50,4.20,14.50,5.10 6240,6299,6270,6.70,4.30,13.70,5.00 6300,6359,6330,5.80,4.20,12.50,4.90 6360,6419,6390,4.90,4.10,10.30,4.60 6420,6479,6450,4.40,4.10,10.40,4.60 6480,6539,6510,4.30,4.10,11.10,4.70 6540,6599,6570,5.60,4.20,12.00,4.80 6600,6659,6630,5.60,4.20,11.60,4.70 6660,6719,6690,6.20,4.20,10.70,4.60 6720,6779,6750,5.40,4.20,9.00,4.50 6780,6839,6810,5.20,4.20,10.40,4.60 6840,6899,6870,6.40,4.20,10.50,4.60 6900,6959,6930,6.60,4.30,12.70,4.90 6960,7019,6990,6.70,4.30,12.00,4.80 7020,7079,7050,6.10,4.20,12.80,4.90 7080,7139,7110,4.70,4.10,9.90,4.50 7140,7199,7170,5.50,4.20,14.20,5.10 7200,7259,7230,6.40,4.20,14.60,5.10 7260,7319,7290,5.70,4.20,17.00,5.50 7320,7379,7350,4.00,4.10,11.30,4.70 7380,7439,7410,4.00,4.10,11.30,4.70 7440,7499,7470,4.40,4.10,11.00,4.70 7500,7559,7530,4.70,4.10,14.20,5.10 7560,7619,7590,5.00,4.20,11.40,4.70 7620,7679,7650,6.60,4.30,11.40,4.70 7680,7739,7710,7.70,4.30,10.00,4.60 7740,7799,7770,7.40,4.30,12.40,4.80 7800,7859,7830,6.10,4.20,12.30,4.80 7860,7919,7890,6.50,4.30,11.80,4.80 7920,7979,7950,7.20,4.30,9.40,4.50 7980,8039,8010,9.10,4.50,9.40,4.50 8040,8099,8070,8.50,4.40,10.10,4.60 8100,8159,8130,7.40,4.30,11.60,4.70 8160,8219,8190,6.00,4.20,11.40,4.70 8220,8279,8250,7.10,4.30,9.70,4.50 8280,8339,8310,6.90,4.30,7.90,4.40 8340,8399,8370,9.30,4.50,10.20,4.60 8400,8459,8430,7.80,4.30,11.70,4.80 8460,8519,8490,6.20,4.20,11.00,4.70 8520,8579,8550,3.30,4.10,9.80,4.50 8580,8639,8610,4.00,4.10,10.30,4.60 8640,8699,8670,5.00,4.10,10.20,4.60 8700,8759,8730,5.50,4.20,10.60,4.60 8760,8819,8790,4.20,4.10,7.20,4.30 8820,8879,8850,5.10,4.20,11.20,4.70 8880,8939,8910,4.70,4.10,10.90,4.70 8940,8999,8970,4.20,4.10,10.50,4.60 9000,9059,9030,4.60,4.10,7.80,4.40 9060,9119,9090,5.30,4.20,6.60,4.30 9120,9179,9150,7.50,4.30,8.90,4.50 9180,9239,9210,8.50,4.40,11.70,4.80 9240,9299,9270,8.20,4.40,12.40,4.80 9300,9359,9330,8.50,4.40,14.30,5.10 9360,9419,9390,6.90,4.30,12.00,4.80 9420,9479,9450,7.50,4.30,12.20,4.80 9480,9539,9510,6.20,4.20,10.90,4.70 9540,9599,9570,4.90,4.10,11.10,4.70 9600,9659,9630,4.50,4.10,13.70,5.00 9660,9719,9690,5.10,4.20,14.50,5.10 9720,9779,9750,5.20,4.20,14.80,5.20 9780,9839,9810,4.70,4.10,10.30,4.60 9840,9899,9870,4.80,4.10,8.90,4.50 9900,9959,9930,5.50,4.20,7.60,4.30 9960,10019,9990,6.20,4.20,11.60,4.70 10020,10079,10050,4.30,4.10,10.80,4.70 10080,10139,10110,4.40,4.10,12.50,4.90 10140,10199,10170,3.60,4.10,10.10,4.60 10200,10259,10230,4.80,4.10,12.20,4.80 10260,10319,10290,3.90,4.10,10.50,4.60 10320,10379,10350,3.80,4.10,9.90,4.60 10380,10439,10410,3.70,4.10,8.00,4.40 10440,10499,10470,4.80,4.10,8.60,4.40 10500,10559,10530,5.50,4.20,10.00,4.60 10560,10619,10590,6.00,4.20,10.60,4.60 10620,10679,10650,6.20,4.20,11.00,4.70 10680,10739,10710,6.30,4.20,10.90,4.70 10740,10799,10770,5.90,4.20,12.30,4.80 10800,10859,10830,5.10,4.20,13.10,4.90 10860,10919,10890,4.40,4.10,13.90,5.00 10920,10979,10950,2.80,4.00,11.80,4.80 10980,11039,11010,2.00,4.00,9.30,4.50 11040,11099,11070,2.10,4.00,6.50,4.20 11100,11159,11130,4.00,4.10,6.90,4.30 11160,11219,11190,5.00,4.10,8.60,4.40 11220,11279,11250,5.30,4.20,9.70,4.50 11280,11339,11310,4.60,4.10,8.60,4.40 11340,11399,11370,5.20,4.20,12.00,4.80 11400,11459,11430,4.80,4.10,11.30,4.70 11460,11519,11490,5.50,4.20,12.20,4.80 11520,11579,11550,5.40,4.20,9.20,4.50 11580,11639,11610,6.30,4.20,8.50,4.40 11640,11699,11670,7.30,4.30,9.70,4.50 11700,11759,11730,7.50,4.30,8.80,4.40 11760,11819,11790,6.70,4.30,8.40,4.40 11820,11879,11850,5.30,4.20,9.40,4.50 11880,11939,11910,4.10,4.10,9.30,4.50 11940,11999,11970,4.50,4.10,11.90,4.80 12000,12059,12030,4.60,4.10,9.00,4.50 12060,12119,12090,5.50,4.20,9.70,4.50 12120,12179,12150,5.70,4.20,10.30,4.60 12180,12239,12210,5.30,4.20,10.60,4.60 12240,12299,12270,5.50,4.20,11.00,4.70 12300,12359,12330,4.80,4.10,7.50,4.30 12360,12419,12390,4.50,4.10,7.60,4.30 12420,12479,12450,2.90,4.10,7.30,4.30 12480,12539,12510,1.70,4.00,8.00,4.40 12540,12599,12570,1.80,4.00,8.40,4.40 12600,12659,12630,2.00,4.00,6.20,4.20 12660,12719,12690,2.80,4.00,7.20,4.30 12720,12779,12750,3.20,4.10,8.60,4.40 12780,12839,12810,4.10,4.10,10.70,4.60 12840,12899,12870,5.00,4.20,11.70,4.80 12900,12959,12930,4.70,4.10,12.50,4.90 12960,13019,12990,4.40,4.10,14.50,5.10 13020,13079,13050,4.00,4.10,15.20,5.20 13080,13139,13110,3.40,4.10,16.10,5.30 13140,13199,13170,1.90,4.00,12.40,4.80 13200,13259,13230,1.60,4.00,10.80,4.60 13260,13319,13290,3.50,4.10,8.30,4.40 13320,13379,13350,4.50,4.10,9.50,4.50 13380,13439,13410,4.40,4.10,9.90,4.60 13440,13499,13470,3.20,4.10,10.70,4.60 13500,13559,13530,2.70,4.00,11.70,4.80 13560,13619,13590,3.30,4.10,12.60,4.90 13620,13679,13650,3.40,4.10,11.80,4.80 13680,13739,13710,4.30,4.10,12.80,4.90 13740,13799,13770,3.40,4.10,12.70,4.90 13800,13859,13830,2.30,4.00,12.00,4.80 13860,13919,13890,1.30,4.00,8.00,4.40 13920,13979,13950,2.20,4.00,6.50,4.20 13980,14039,14010,3.60,4.10,6.90,4.30 14040,14099,14070,4.00,4.10,9.10,4.50 14100,14159,14130,2.80,4.00,9.70,4.50 14160,14219,14190,2.70,4.00,10.30,4.60 14220,14279,14250,3.10,4.10,10.70,4.60 14280,14339,14310,4.30,4.10,11.40,4.70 14340,14399,14370,4.90,4.10,12.50,4.90 14400,14459,14430,4.90,4.10,12.50,4.80 14460,14519,14490,4.30,4.10,11.00,4.70 14520,14579,14550,3.30,4.10,8.80,4.40 14580,14639,14610,2.60,4.00,6.90,4.30 14640,14699,14670,2.80,4.00,8.30,4.40 14700,14759,14730,3.00,4.10,9.60,4.50 14760,14819,14790,3.00,4.10,10.00,4.60 14820,14879,14850,2.60,4.00,8.50,4.40 14880,14939,14910,3.00,4.10,6.70,4.30 14940,14999,14970,4.60,4.10,8.50,4.40 15000,15059,15030,5.30,4.20,8.70,4.40 15060,15119,15090,5.90,4.20,9.20,4.50 15120,15179,15150,6.40,4.20,8.40,4.40 15180,15239,15210,6.10,4.20,7.50,4.30 15240,15299,15270,5.70,4.20,9.00,4.50 15300,15359,15330,4.70,4.10,8.20,4.40 15360,15419,15390,5.30,4.20,10.50,4.60 15420,15479,15450,5.80,4.20,10.60,4.60 15480,15539,15510,6.80,4.30,13.40,5.00 15540,15599,15570,6.00,4.20,10.30,4.60 15600,15659,15630,5.20,4.20,9.90,4.60 15660,15719,15690,4.00,4.10,5.60,4.20 15720,15779,15750,4.00,4.10,6.20,4.20 15780,15839,15810,3.50,4.10,4.70,4.10 15840,15899,15870,2.90,4.10,7.40,4.30 15900,15959,15930,2.60,4.00,8.30,4.40 15960,16019,15990,2.00,4.00,6.70,4.30 16020,16079,16050,1.70,4.00,5.70,4.20 16080,16139,16110,2.60,4.00,8.00,4.40 16140,16199,16170,3.00,4.10,11.40,4.70 16200,16259,16230,3.30,4.10,11.60,4.70 16260,16319,16290,2.20,4.00,8.50,4.40 16320,16379,16350,3.00,4.10,9.00,4.50 16380,16439,16410,3.40,4.10,9.00,4.50 16440,16499,16470,3.80,4.10,9.10,4.50 16500,16559,16530,3.60,4.10,6.90,4.30 16560,16619,16590,3.80,4.10,7.30,4.30 16620,16679,16650,4.80,4.10,9.50,4.50 16680,16739,16710,4.10,4.10,8.80,4.40 16740,16799,16770,4.20,4.10,9.00,4.50 16800,16859,16830,4.20,4.10,8.40,4.40 16860,16919,16890,3.10,4.10,8.50,4.40 16920,16979,16950,2.10,4.00,6.00,4.20 16980,17039,17010,0.80,4.00,7.10,4.30 17040,17099,17070,2.70,4.00,6.20,4.20 17100,17159,17130,3.20,4.10,6.50,4.20 17160,17219,17190,4.40,4.10,3.30,4.10 17220,17279,17250,5.00,4.10,4.20,4.10 17280,17339,17310,5.30,4.20,5.90,4.20 17340,17399,17370,4.80,4.10,8.80,4.40 17400,17459,17430,3.70,4.10,10.40,4.60 17460,17519,17490,2.90,4.00,12.90,4.90 17520,17579,17550,2.30,4.00,12.30,4.80 17580,17639,17610,2.60,4.00,10.60,4.60 17640,17699,17670,2.10,4.00,6.50,4.20 17700,17759,17730,2.20,4.00,4.50,4.10 17760,17819,17790,2.00,4.00,4.10,4.10 17820,17879,17850,2.30,4.00,3.80,4.10 17880,17939,17910,2.80,4.00,3.80,4.10 17940,17999,17970,3.00,4.10,4.80,4.10 18000,18059,18030,3.70,4.10,5.20,4.20 18060,18119,18090,4.10,4.10,6.40,4.20 18120,18179,18150,3.60,4.10,6.40,4.20 18180,18239,18210,2.50,4.00,7.10,4.30 18240,18299,18270,1.20,4.00,6.60,4.30 18300,18359,18330,1.30,4.00,6.40,4.20 18360,18419,18390,3.20,4.10,8.30,4.40 18420,18479,18450,4.10,4.10,9.10,4.50 18480,18539,18510,4.10,4.10,8.70,4.40 18540,18599,18570,3.20,4.10,6.20,4.20 18600,18659,18630,2.60,4.00,5.50,4.20 18660,18719,18690,3.50,4.10,6.70,4.30 18720,18779,18750,2.40,4.00,6.50,4.20 18780,18839,18810,3.70,4.10,7.10,4.30 18840,18899,18870,2.50,4.00,5.00,4.10 18900,18959,18930,3.70,4.10,4.90,4.10 18960,19019,18990,3.00,4.10,6.80,4.30 19020,19079,19050,3.10,4.10,12.80,4.90 19080,19139,19110,2.10,4.00,16.10,5.30 19140,19199,19170,0.70,4.00,11.90,4.80 19200,19259,19230,0.60,4.00,9.10,4.50 19260,19319,19290,0.00,4.00,8.40,4.40 19320,19379,19350,2.40,4.00,8.70,4.40 19380,19439,19410,3.90,4.10,7.10,4.30 19440,19499,19470,6.00,4.20,8.30,4.40 19500,19559,19530,4.00,4.10,9.00,4.50 19560,19619,19590,4.00,4.10,12.00,4.80 19620,19679,19650,2.50,4.00,9.50,4.50 19680,19739,19710,3.50,4.10,10.60,4.60 19740,19799,19770,2.80,4.00,8.00,4.40 19800,19859,19830,4.20,4.10,10.50,4.60 19860,19919,19890,3.70,4.10,13.90,5.00 19920,19979,19950,4.60,4.10,16.20,5.40 19980,20039,20010,4.00,4.10,16.20,5.40 20040,20099,20070,4.70,4.10,12.80,4.90 20100,20159,20130,2.80,4.00,10.10,4.60 20160,20219,20190,2.00,4.00,5.70,4.20 20220,20279,20250,0.60,4.00,5.20,4.20 20280,20339,20310,1.50,4.00,4.10,4.10 20340,20399,20370,3.00,4.10,7.30,4.30 20400,20459,20430,4.00,4.10,7.00,4.30 20460,20519,20490,3.80,4.10,7.60,4.30 20520,20579,20550,2.90,4.00,6.70,4.30 20580,20639,20610,2.60,4.00,8.70,4.40 20640,20699,20670,3.00,4.10,11.00,4.70 20700,20759,20730,2.40,4.00,9.20,4.50 20760,20819,20790,3.30,4.10,7.80,4.40 20820,20879,20850,4.00,4.10,6.80,4.30 20880,20939,20910,5.00,4.10,8.20,4.40 20940,20999,20970,4.60,4.10,5.80,4.20 21000,21059,21030,3.40,4.10,5.90,4.20 21060,21119,21090,2.00,4.00,7.00,4.30 21120,21179,21150,1.20,4.00,11.30,4.70 21180,21239,21210,0.50,4.00,11.20,4.70 21240,21299,21270,0.40,4.00,7.90,4.40 21300,21359,21330,1.40,4.00,7.00,4.30 21360,21419,21390,1.80,4.00,6.50,4.20 21420,21479,21450,3.10,4.10,8.40,4.40 21480,21539,21510,3.20,4.10,6.70,4.30 21540,21599,21570,3.40,4.10,7.20,4.30 21600,21659,21630,2.40,4.00,8.50,4.40 21660,21719,21690,2.20,4.00,10.00,4.60 21720,21779,21750,3.60,4.10,11.60,4.70 21780,21839,21810,5.30,4.20,12.00,4.80 21840,21899,21870,5.30,4.20,11.90,4.80 21900,21959,21930,4.30,4.10,10.10,4.60 21960,22019,21990,4.10,4.10,8.70,4.40 22020,22079,22050,4.70,4.10,8.40,4.40 22080,22139,22110,4.50,4.10,8.50,4.40 22140,22199,22170,3.00,4.10,8.50,4.40 22200,22259,22230,1.60,4.00,8.60,4.40 22260,22319,22290,1.50,4.00,9.50,4.50 22320,22379,22350,1.80,4.00,8.40,4.40 22380,22439,22410,2.30,4.00,8.90,4.50 22440,22499,22470,2.80,4.00,9.00,4.50 22500,22559,22530,4.20,4.10,12.60,4.90 22560,22619,22590,4.30,4.10,11.40,4.70 22620,22679,22650,3.40,4.10,9.90,4.60 22680,22739,22710,1.80,4.00,7.30,4.30 22740,22799,22770,0.90,4.00,8.00,4.40 22800,22859,22830,1.50,4.00,7.90,4.40 22860,22919,22890,2.70,4.00,7.10,4.30 22920,22979,22950,3.60,4.10,5.90,4.20 22980,23039,23010,3.20,4.10,5.70,4.20 23040,23099,23070,2.90,4.10,6.70,4.30 23100,23159,23130,3.40,4.10,8.80,4.40 23160,23219,23190,4.50,4.10,9.80,4.50 23220,23279,23250,5.40,4.20,10.20,4.60 23280,23339,23310,4.50,4.10,9.40,4.50 23340,23399,23370,2.50,4.00,10.20,4.60 23400,23459,23430,1.10,4.00,10.60,4.60 23460,23519,23490,1.10,4.00,10.80,4.60 23520,23579,23550,2.00,4.00,9.40,4.50 23580,23639,23610,2.70,4.00,10.00,4.60 23640,23699,23670,2.30,4.00,11.20,4.70 23700,23759,23730,2.50,4.00,11.60,4.70 23760,23819,23790,1.90,4.00,9.00,4.50 23820,23879,23850,2.20,4.00,7.30,4.30 23880,23939,23910,1.50,4.00,7.70,4.30 23940,23999,23970,1.50,4.00,11.00,4.70 24000,24059,24030,0.90,4.00,12.90,4.90 24060,24119,24090,0.20,4.00,12.70,4.90 24120,24179,24150,1.10,4.00,13.50,5.00 24180,24239,24210,2.20,4.00,12.00,4.80 24240,24299,24270,3.20,4.10,13.40,5.00 24300,24359,24330,2.40,4.00,14.70,5.10 24360,24419,24390,1.80,4.00,17.80,5.60 24420,24479,24450,1.30,4.00,18.30,5.70 24480,24539,24510,0.90,4.00,15.40,5.20 24540,24599,24570,2.60,4.00,17.50,5.60 24600,24659,24630,4.00,4.10,18.50,5.70 24660,24719,24690,5.90,4.20,21.90,6.30 24720,24779,24750,4.10,4.10,18.70,5.70 24780,24839,24810,2.30,4.00,17.80,5.60 24840,24899,24870,-0.20,4.00,15.80,5.30 24900,24959,24930,0.00,4.00,13.90,5.00 24960,25019,24990,1.20,4.00,12.00,4.80 25020,25079,25050,2.50,4.00,9.80,4.50 25080,25139,25110,2.30,4.00,8.50,4.40 25140,25199,25170,3.90,4.10,9.10,4.50 25200,25259,25230,4.80,4.10,7.70,4.30 25260,25319,25290,5.80,4.20,9.70,4.50 25320,25379,25350,3.40,4.10,8.40,4.40 25380,25439,25410,3.00,4.10,10.10,4.60 25440,25499,25470,2.80,4.00,9.60,4.50 25500,25559,25530,3.30,4.10,14.40,5.10 25560,25619,25590,3.30,4.10,19.00,5.80 25620,25679,25650,1.70,4.00,18.30,5.70 25680,25739,25710,2.30,4.00,14.70,5.10 25740,25799,25770,0.80,4.00,8.70,4.40 25800,25859,25830,1.30,4.00,9.60,4.50 25860,25919,25890,0.80,4.00,15.10,5.20 25920,25979,25950,0.50,4.00,16.60,5.40 25980,26039,26010,1.60,4.00,15.80,5.30 26040,26099,26070,1.30,4.00,9.40,4.50 26100,26159,26130,2.40,4.00,9.00,4.50 26160,26219,26190,1.90,4.00,9.60,4.50 26220,26279,26250,2.70,4.00,10.10,4.60 26280,26339,26310,3.80,4.10,11.40,4.70 26340,26399,26370,2.60,4.00,8.90,4.40 26400,26459,26430,3.10,4.10,7.90,4.40 26460,26519,26490,2.60,4.00,6.70,4.30 26520,26579,26550,3.80,4.10,10.40,4.60 26580,26639,26610,2.20,4.00,10.50,4.60 26640,26699,26670,1.90,4.00,8.20,4.40 26700,26759,26730,2.00,4.00,18.30,5.70 26760,26819,26790,3.20,4.10,17.60,5.60 26820,26879,26850,2.90,4.00,20.10,6.00 26880,26939,26910,2.90,4.10,12.40,4.80 26940,26999,26970,2.50,4.00,14.20,5.10 27000,27059,27030,2.70,4.00,20.40,6.00 27060,27119,27090,4.30,4.10,18.10,5.60 27120,27179,27150,6.10,4.20,18.60,5.70 27180,27239,27210,7.30,4.30,13.80,5.00 27240,27299,27270,7.40,4.30,13.30,5.00 27300,27359,27330,6.70,4.30,12.40,4.80 27360,27419,27390,6.60,4.30,11.40,4.70 27420,27479,27450,5.90,4.20,13.60,5.00 27480,27539,27510,5.10,4.20,15.50,5.30 27540,27599,27570,3.50,4.10,14.30,5.10 27600,27659,27630,3.20,4.10,12.60,4.90 27660,27719,27690,4.80,4.10,14.80,5.20 27720,27779,27750,7.20,4.30,19.90,5.90 27780,27839,27810,7.60,4.30,22.40,6.40 27840,27899,27870,6.40,4.20,29.00,7.50 27900,27959,27930,6.20,4.20,31.00,7.90 27960,28019,27990,7.20,4.30,32.90,8.30 28020,28079,28050,8.00,4.40,25.60,6.90 28080,28139,28110,9.40,4.50,25.90,7.00 28140,28199,28170,9.30,4.50,26.60,7.10 28200,28259,28230,11.20,4.70,32.40,8.20 28260,28319,28290,9.00,4.50,33.70,8.40 28320,28379,28350,10.00,4.60,30.90,7.90 28380,28439,28410,9.00,4.50,28.40,7.40 28440,28499,28470,10.70,4.60,25.60,6.90 28500,28559,28530,11.70,4.80,33.10,8.30 28560,28619,28590,11.60,4.70,29.90,7.70 28620,28679,28650,11.10,4.70,33.90,8.50 28680,28739,28710,6.20,4.20,37.50,9.20 28740,28799,28770,4.10,4.10,46.30,10.90 28800,28859,28830,3.40,4.10,46.50,11.00 28860,28919,28890,6.40,4.20,38.60,9.40 28920,28979,28950,8.40,4.40,36.10,8.90 28980,29039,29010,7.90,4.40,37.90,9.30 29040,29099,29070,9.00,4.50,39.80,9.60 29100,29159,29130,8.90,4.50,40.90,9.80 29160,29219,29190,9.10,4.50,39.90,9.60 29220,29279,29250,8.80,4.40,48.30,11.30 29280,29339,29310,12.20,4.80,49.80,11.70 29340,29399,29370,15.10,5.20,45.20,10.70 29400,29459,29430,16.10,5.30,35.70,8.80 29460,29519,29490,14.30,5.10,32.50,8.20 29520,29579,29550,14.10,5.10,37.90,9.20 29580,29639,29610,15.30,5.20,39.00,9.50 29640,29699,29670,15.80,5.30,40.40,9.70 29700,29759,29730,16.00,5.30,35.10,8.70 29760,29819,29790,15.80,5.30,35.50,8.80 29820,29879,29850,17.00,5.50,35.10,8.70 29880,29939,29910,18.50,5.70,40.40,9.80 29940,29999,29970,19.50,5.90,45.10,10.70 30000,30059,30030,17.90,5.60,56.90,13.10 30060,30119,30090,16.00,5.30,61.60,14.10 30120,30179,30150,16.90,5.50,60.20,13.80 30180,30239,30210,18.60,5.70,53.60,12.50 30240,30299,30270,18.60,5.70,56.40,13.00 30300,30359,30330,14.60,5.10,64.70,14.80 30360,30419,30390,15.90,5.30,66.40,15.10 30420,30479,30450,15.40,5.20,60.80,14.00 30480,30539,30510,16.20,5.40,51.80,12.10 30540,30599,30570,14.80,5.20,45.00,10.70 30600,30659,30630,16.40,5.40,42.90,10.30 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