49, 1001 Cantrell, Christopher A Atmospheric Chemistry Division/NESL/NCAR HO2 and HO2+RO2 from PeRCIMS at Manitou Experimental Forest BEACHON-RoMBAS 1,1 2011, 08, 23, 2011, 12, 03 0 Start_MST, seconds, number_of_seconds_from_0000_MST 6 1,1,1,1,1,1 -99999,-99999,-99999,-99999,-99999,-99999 Stop_MST, seconds, number_of_seconds_from_0000_MST Mid_MST, seconds, number_of_seconds_from_0000_MST HO2, pptv, HO2_mixing_ratio HO2_uncertainty, pptv, HO2_2_sigma_uncertainty HO2+RO2, pptv, HO2+RO2_mixing_ratio HO2+RO2_uncertainty, pptv, HO2+RO2_2_sigma_uncertainty 5 These data are reduced using four factors determined in the laboratory and in the field: F_lo and F_hi are the radical sensitivities in the HO2+RO2 and HO2 modes, respectively (units pptv/ion ratio). Alpha_lo and alpha_hi are the ratios of RO2 to HO2 sensitivity in the HO2+RO2 and HO2 modes, respectively. HO2+RO2 concentrations are then S_lo*F_lo-(S_lo*F_lo - S_hi*F_hi)*(alpha_lo - 1)/(alpha_lo - alpha_hi) . HO2 concentrations are S_lo*F_lo-(S_lo*F_lo - S_hi*F_hi)*(alpha_lo)/(alpha_lo - alpha_hi) . S_lo is the background corrected ion ratio in the HO2+RO2 mode, and S_hi is the background corrected ion ratio in the HO2 mode. The ion ratios are mass 97 signal count rate minus background count rate divided by mass 62 count rate. 24 PI_CONTACT_INFO: 303-497-1479, NCAR, 3090 Center Green Dr., Boulder, CO 80301, cantrell@ucar.edu PLATFORM: Seacontainer #1 LOCATION: Manitou Experimental Forest, Woodland Park, Colorado, USA ASSOCIATED_DATA: N/A INSTRUMENT_INFO: These data were collected using a CIMS based instrument. An inlet collects ambient air from the free air stream and adds reagents, includling O2 or N2 diluents, and NO and SO2 reagent gases. This method, called oxygen dilution modulation leads to nearly 100% measurement of HO2 and RO2 in the O2 dilution/low reagent concentration mode, whereas RO2 is measured with less than 15% efficiency in the N2 dilution/higher reagent concentration mode. This is because the chemistry converts peroxy radicals to H2SO4 efficiently in the O2 mode, but RO2 radicals are converted to RONO in the N2 mode. The H2SO4 thus produced is ionized by reaction with NO3- ions. The reagent and product ions are detected by mass spectrometry using quadrupole mass filtering and counting by a channel electron multiplier operating in the negative ion mode. DATA_INFO: Signal data for HO2+RO2 are collected during the 0-7 second time interval, and for HO2 in 30-37 second time interval. UNCERTAINTY: approximately 35% (2 sigma) for values well above 2 pptv; estimates are listed for each data point (2 sigma) ULOD_FLAG: -7777 ULOD_VALUE: N/A LLOD_FLAG: -8888 LLOD_VALUE: N/A DM_CONTACT_INFO: N/A PROJECT_INFO: BEACHON-RoMBAS, 20-Jul-2011 to 30-Aug-2011 STIPULATIONS_ON_USE: contact PI BEFORE use/presentation/publication OTHER_COMMENTS: REVISION: R1; R0 R1: final data R0: preliminary data Start_MST,Stop_MST,Mid_MST,HO2,HO2_uncertainty,HO2+RO2,HO2+RO2_uncertainty 0,59,30,2.20,4.00,9.40,4.50 60,119,90,2.10,4.00,10.30,4.60 120,179,150,1.90,4.00,12.40,4.80 180,239,210,2.00,4.00,14.90,5.20 240,299,270,1.70,4.00,13.60,5.00 300,359,330,3.70,4.10,12.80,4.90 360,419,390,4.90,4.10,10.60,4.60 420,479,450,5.40,4.20,12.10,4.80 480,539,510,4.50,4.10,13.00,4.90 540,599,570,3.70,4.10,15.50,5.30 600,659,630,4.80,4.10,16.90,5.50 660,719,690,4.10,4.10,15.50,5.30 720,779,750,4.30,4.10,13.20,4.90 780,839,810,3.70,4.10,10.50,4.60 840,899,870,4.30,4.10,11.70,4.80 900,959,930,3.40,4.10,12.10,4.80 960,1019,990,3.20,4.10,12.90,4.90 1020,1079,1050,1.80,4.00,13.30,5.00 1080,1139,1110,1.90,4.00,12.00,4.80 1140,1199,1170,1.80,4.00,13.30,5.00 1200,1259,1230,2.40,4.00,11.90,4.80 1260,1319,1290,3.50,4.10,16.20,5.40 1320,1379,1350,1.10,4.00,14.20,5.10 1380,1439,1410,1.00,4.00,13.80,5.00 1440,1499,1470,-0.20,4.00,10.50,4.60 1500,1559,1530,1.10,4.00,10.90,4.70 1560,1619,1590,0.50,4.00,10.00,4.60 1620,1679,1650,1.10,4.00,9.10,4.50 1680,1739,1710,3.00,4.10,9.90,4.60 1740,1799,1770,4.30,4.10,12.00,4.80 1800,1859,1830,3.10,4.10,13.60,5.00 1860,1919,1890,1.80,4.00,14.10,5.10 1920,1979,1950,2.30,4.00,13.60,5.00 1980,2039,2010,3.80,4.10,12.80,4.90 2040,2099,2070,4.50,4.10,12.00,4.80 2100,2159,2130,5.00,4.10,12.30,4.80 2160,2219,2190,5.10,4.20,13.40,5.00 2220,2279,2250,5.00,4.20,14.90,5.20 2280,2339,2310,4.50,4.10,17.30,5.50 2340,2399,2370,3.50,4.10,16.80,5.40 2400,2459,2430,3.50,4.10,16.50,5.40 2460,2519,2490,3.20,4.10,14.10,5.10 2520,2579,2550,3.80,4.10,14.90,5.20 2580,2639,2610,4.00,4.10,15.10,5.20 2640,2699,2670,3.50,4.10,14.30,5.10 2700,2759,2730,4.20,4.10,13.30,5.00 2760,2819,2790,3.80,4.10,11.90,4.80 2820,2879,2850,3.90,4.10,12.00,4.80 2880,2939,2910,3.50,4.10,11.80,4.80 2940,2999,2970,3.50,4.10,11.00,4.70 3000,3059,3030,3.80,4.10,12.10,4.80 3060,3119,3090,3.20,4.10,12.90,4.90 3120,3179,3150,2.90,4.10,14.30,5.10 3180,3239,3210,2.00,4.00,15.00,5.20 3240,3299,3270,1.70,4.00,15.10,5.20 3300,3359,3330,1.10,4.00,13.00,4.90 3360,3419,3390,3.00,4.10,10.50,4.60 3420,3479,3450,3.30,4.10,10.20,4.60 3480,3539,3510,3.90,4.10,14.50,5.10 3540,3599,3570,2.60,4.00,14.70,5.10 3600,3659,3630,2.40,4.00,13.90,5.00 3660,3719,3690,3.10,4.10,11.20,4.70 3720,3779,3750,3.70,4.10,11.30,4.70 3780,3839,3810,4.60,4.10,11.00,4.70 3840,3899,3870,4.20,4.10,12.00,4.80 3900,3959,3930,4.20,4.10,11.80,4.80 3960,4019,3990,3.70,4.10,12.80,4.90 4020,4079,4050,3.60,4.10,11.20,4.70 4080,4139,4110,3.80,4.10,12.50,4.90 4140,4199,4170,4.50,4.10,12.10,4.80 4200,4259,4230,4.60,4.10,12.30,4.80 4260,4319,4290,4.00,4.10,11.90,4.80 4320,4379,4350,3.20,4.10,11.60,4.80 4380,4439,4410,2.80,4.00,14.10,5.10 4440,4499,4470,2.20,4.00,14.40,5.10 4500,4559,4530,1.20,4.00,14.00,5.00 4560,4619,4590,1.80,4.00,13.00,4.90 4620,4679,4650,2.30,4.00,12.70,4.90 4680,4739,4710,3.10,4.10,13.50,5.00 4740,4799,4770,2.60,4.00,13.20,4.90 4800,4859,4830,2.70,4.00,14.10,5.10 4860,4919,4890,3.90,4.10,13.90,5.00 4920,4979,4950,3.60,4.10,13.70,5.00 4980,5039,5010,3.30,4.10,11.90,4.80 5040,5099,5070,2.80,4.00,13.30,5.00 5100,5159,5130,3.90,4.10,12.80,4.90 5160,5219,5190,4.50,4.10,14.50,5.10 5220,5279,5250,4.40,4.10,13.30,5.00 5280,5339,5310,4.40,4.10,13.20,4.90 5340,5399,5370,4.30,4.10,12.00,4.80 5400,5459,5430,4.30,4.10,11.60,4.70 5460,5519,5490,4.40,4.10,12.00,4.80 5520,5579,5550,3.80,4.10,12.00,4.80 5580,5639,5610,4.00,4.10,12.80,4.90 5640,5699,5670,3.60,4.10,12.80,4.90 5700,5759,5730,3.40,4.10,12.20,4.80 5760,5819,5790,3.50,4.10,12.00,4.80 5820,5879,5850,3.90,4.10,12.50,4.80 5880,5939,5910,4.80,4.10,14.70,5.10 5940,5999,5970,3.90,4.10,15.20,5.20 6000,6059,6030,2.20,4.00,17.70,5.60 6060,6119,6090,1.10,4.00,18.90,5.80 6120,6179,6150,2.20,4.00,18.80,5.80 6180,6239,6210,4.70,4.10,16.10,5.30 6240,6299,6270,5.00,4.20,14.90,5.20 6300,6359,6330,5.80,4.20,14.10,5.10 6360,6419,6390,5.10,4.20,14.10,5.10 6420,6479,6450,5.20,4.20,13.60,5.00 6480,6539,6510,3.80,4.10,14.20,5.10 6540,6599,6570,3.30,4.10,13.10,4.90 6600,6659,6630,4.30,4.10,12.40,4.80 6660,6719,6690,4.60,4.10,11.50,4.70 6720,6779,6750,5.40,4.20,14.70,5.10 6780,6839,6810,4.90,4.10,16.10,5.30 6840,6899,6870,4.50,4.10,17.60,5.60 6900,6959,6930,3.10,4.10,14.80,5.20 6960,7019,6990,2.50,4.00,13.30,5.00 7020,7079,7050,2.10,4.00,12.00,4.80 7080,7139,7110,2.90,4.00,15.60,5.30 7140,7199,7170,3.10,4.10,16.20,5.40 7200,7259,7230,3.50,4.10,16.40,5.40 7260,7319,7290,2.80,4.00,13.10,4.90 7320,7379,7350,3.60,4.10,12.70,4.90 7380,7439,7410,3.30,4.10,12.90,4.90 7440,7499,7470,4.10,4.10,12.90,4.90 7500,7559,7530,3.10,4.10,12.80,4.90 7560,7619,7590,2.90,4.00,12.80,4.90 7620,7679,7650,2.50,4.00,13.10,4.90 7680,7739,7710,3.00,4.10,13.70,5.00 7740,7799,7770,3.50,4.10,14.30,5.10 7800,7859,7830,4.60,4.10,15.00,5.20 7860,7919,7890,4.50,4.10,14.30,5.10 7920,7979,7950,5.00,4.20,13.60,5.00 7980,8039,8010,4.60,4.10,13.00,4.90 8040,8099,8070,4.70,4.10,12.60,4.90 8100,8159,8130,4.30,4.10,12.70,4.90 8160,8219,8190,3.60,4.10,14.10,5.10 8220,8279,8250,2.90,4.10,15.90,5.30 8280,8339,8310,3.90,4.10,15.60,5.30 8340,8399,8370,3.70,4.10,11.70,4.80 8400,8459,8430,4.60,4.10,10.90,4.70 8460,8519,8490,4.60,4.10,10.80,4.70 8520,8579,8550,6.10,4.20,14.60,5.10 8580,8639,8610,6.30,4.20,15.40,5.20 8640,8699,8670,5.90,4.20,16.50,5.40 8700,8759,8730,5.00,4.10,15.10,5.20 8760,8819,8790,4.10,4.10,14.10,5.10 8820,8879,8850,3.90,4.10,13.90,5.00 8880,8939,8910,4.30,4.10,14.30,5.10 8940,8999,8970,3.80,4.10,13.20,4.90 9000,9059,9030,4.10,4.10,12.70,4.90 9060,9119,9090,3.70,4.10,12.30,4.80 9120,9179,9150,4.00,4.10,12.60,4.90 9180,9239,9210,3.50,4.10,13.50,5.00 9240,9299,9270,3.90,4.10,15.30,5.20 9300,9359,9330,4.60,4.10,16.30,5.40 9360,9419,9390,4.40,4.10,16.10,5.30 9420,9479,9450,4.20,4.10,14.40,5.10 9480,9539,9510,4.20,4.10,13.10,4.90 9540,9599,9570,4.30,4.10,12.50,4.80 9600,9659,9630,4.10,4.10,13.90,5.00 9660,9719,9690,2.80,4.00,14.50,5.10 9720,9779,9750,4.30,4.10,15.60,5.30 9780,9839,9810,4.60,4.10,14.40,5.10 9840,9899,9870,6.10,4.20,14.50,5.10 9900,9959,9930,5.30,4.20,13.90,5.00 9960,10019,9990,4.60,4.10,14.60,5.10 10020,10079,10050,3.70,4.10,13.50,5.00 10080,10139,10110,3.40,4.10,15.50,5.30 10140,10199,10170,3.30,4.10,14.40,5.10 10200,10259,10230,4.00,4.10,15.00,5.20 10260,10319,10290,4.30,4.10,13.10,4.90 10320,10379,10350,5.60,4.20,15.50,5.20 10380,10439,10410,4.80,4.10,16.00,5.30 10440,10499,10470,2.70,4.00,14.20,5.10 10500,10559,10530,0.60,4.00,11.00,4.70 10560,10619,10590,0.70,4.00,9.90,4.60 10620,10679,10650,3.20,4.10,12.50,4.90 10680,10739,10710,4.40,4.10,14.80,5.20 10740,10799,10770,4.10,4.10,15.50,5.30 10800,10859,10830,3.40,4.10,14.50,5.10 10860,10919,10890,2.90,4.10,13.20,4.90 10920,10979,10950,3.20,4.10,13.20,4.90 10980,11039,11010,3.30,4.10,14.50,5.10 11040,11099,11070,3.40,4.10,16.70,5.40 11100,11159,11130,3.60,4.10,20.00,5.90 11160,11219,11190,3.60,4.10,18.40,5.70 11220,11279,11250,4.00,4.10,15.90,5.30 11280,11339,11310,4.50,4.10,12.50,4.80 11340,11399,11370,3.70,4.10,12.80,4.90 11400,11459,11430,3.00,4.10,12.90,4.90 11460,11519,11490,2.30,4.00,14.20,5.10 11520,11579,11550,2.30,4.00,13.90,5.00 11580,11639,11610,2.50,4.00,13.30,5.00 11640,11699,11670,2.50,4.00,11.20,4.70 11700,11759,11730,2.40,4.00,10.30,4.60 11760,11819,11790,2.50,4.00,10.80,4.70 11820,11879,11850,3.40,4.10,13.00,4.90 11880,11939,11910,3.30,4.10,14.70,5.10 11940,11999,11970,3.30,4.10,16.60,5.40 12000,12059,12030,1.40,4.00,14.40,5.10 12060,12119,12090,3.00,4.10,12.50,4.90 12120,12179,12150,2.80,4.00,11.90,4.80 12180,12239,12210,5.50,4.20,15.10,5.20 12240,12299,12270,3.70,4.10,15.10,5.20 12300,12359,12330,3.40,4.10,14.60,5.10 12360,12419,12390,2.10,4.00,13.40,5.00 12420,12479,12450,3.00,4.10,15.30,5.20 12480,12539,12510,3.90,4.10,16.50,5.40 12540,12599,12570,3.90,4.10,17.50,5.60 12600,12659,12630,3.30,4.10,17.00,5.50 12660,12719,12690,2.00,4.00,15.10,5.20 12720,12779,12750,1.70,4.00,14.60,5.10 12780,12839,12810,1.60,4.00,15.10,5.20 12840,12899,12870,2.20,4.00,17.60,5.60 12900,12959,12930,1.70,4.00,16.10,5.30 12960,13019,12990,1.60,4.00,16.20,5.40 13020,13079,13050,1.60,4.00,14.70,5.10 13080,13139,13110,3.20,4.10,16.30,5.40 13140,13199,13170,4.30,4.10,16.30,5.40 13200,13259,13230,4.30,4.10,17.60,5.60 13260,13319,13290,4.00,4.10,16.90,5.50 13320,13379,13350,2.70,4.00,16.80,5.40 13380,13439,13410,2.30,4.00,16.30,5.40 13440,13499,13470,1.80,4.00,15.00,5.20 13500,13559,13530,3.10,4.10,13.20,4.90 13560,13619,13590,4.30,4.10,12.10,4.80 13620,13679,13650,4.30,4.10,13.90,5.00 13680,13739,13710,2.90,4.10,15.00,5.20 13740,13799,13770,1.90,4.00,14.40,5.10 13800,13859,13830,1.70,4.00,11.00,4.70 13860,13919,13890,2.00,4.00,11.50,4.70 13920,13979,13950,1.70,4.00,10.90,4.70 13980,14039,14010,1.60,4.00,10.80,4.60 14040,14099,14070,2.40,4.00,7.90,4.40 14100,14159,14130,2.60,4.00,8.40,4.40 14160,14219,14190,2.40,4.00,10.80,4.70 14220,14279,14250,0.60,4.00,11.50,4.70 14280,14339,14310,1.00,4.00,10.40,4.60 14340,14399,14370,1.70,4.00,8.20,4.40 14400,14459,14430,3.10,4.10,7.30,4.30 14460,14519,14490,2.50,4.00,6.20,4.20 14520,14579,14550,1.90,4.00,7.60,4.30 14580,14639,14610,2.10,4.00,10.10,4.60 14640,14699,14670,3.40,4.10,14.20,5.10 14700,14759,14730,4.20,4.10,16.30,5.40 14760,14819,14790,3.40,4.10,14.60,5.10 14820,14879,14850,2.30,4.00,11.30,4.70 14880,14939,14910,1.50,4.00,8.90,4.40 14940,14999,14970,2.30,4.00,9.00,4.50 15000,15059,15030,3.50,4.10,9.80,4.50 15060,15119,15090,4.10,4.10,10.80,4.70 15120,15179,15150,3.80,4.10,13.10,4.90 15180,15239,15210,2.80,4.00,12.30,4.80 15240,15299,15270,3.40,4.10,13.60,5.00 15300,15359,15330,3.40,4.10,12.20,4.80 15360,15419,15390,4.40,4.10,14.90,5.20 15420,15479,15450,4.20,4.10,14.50,5.10 15480,15539,15510,4.20,4.10,15.30,5.20 15540,15599,15570,4.20,4.10,13.90,5.00 15600,15659,15630,2.90,4.00,13.30,5.00 15660,15719,15690,2.30,4.00,12.50,4.90 15720,15779,15750,1.40,4.00,15.40,5.20 15780,15839,15810,2.20,4.00,14.50,5.10 15840,15899,15870,3.50,4.10,15.40,5.20 15900,15959,15930,5.00,4.20,14.90,5.20 15960,16019,15990,4.20,4.10,14.70,5.10 16020,16079,16050,3.70,4.10,12.70,4.90 16080,16139,16110,2.30,4.00,10.50,4.60 16140,16199,16170,3.20,4.10,11.20,4.70 16200,16259,16230,3.30,4.10,10.30,4.60 16260,16319,16290,2.50,4.00,10.10,4.60 16320,16379,16350,1.90,4.00,11.70,4.80 16380,16439,16410,1.10,4.00,14.50,5.10 16440,16499,16470,2.10,4.00,14.50,5.10 16500,16559,16530,2.90,4.00,13.30,5.00 16560,16619,16590,3.70,4.10,10.00,4.60 16620,16679,16650,3.90,4.10,7.60,4.30 16680,16739,16710,4.30,4.10,6.40,4.20 16740,16799,16770,5.10,4.20,8.80,4.40 16800,16859,16830,5.30,4.20,12.70,4.90 16860,16919,16890,4.60,4.10,13.80,5.00 16920,16979,16950,3.90,4.10,14.00,5.10 16980,17039,17010,3.30,4.10,12.00,4.80 17040,17099,17070,3.20,4.10,10.20,4.60 17100,17159,17130,2.80,4.00,8.60,4.40 17160,17219,17190,2.20,4.00,7.60,4.30 17220,17279,17250,2.60,4.00,8.90,4.40 17280,17339,17310,2.60,4.00,9.20,4.50 17340,17399,17370,2.00,4.00,8.60,4.40 17400,17459,17430,1.90,4.00,8.50,4.40 17460,17519,17490,1.30,4.00,8.90,4.50 17520,17579,17550,2.50,4.00,10.90,4.70 17580,17639,17610,2.80,4.00,10.40,4.60 17640,17699,17670,4.10,4.10,12.00,4.80 17700,17759,17730,4.30,4.10,14.10,5.10 17760,17819,17790,3.60,4.10,16.00,5.30 17820,17879,17850,2.20,4.00,13.40,5.00 17880,17939,17910,1.80,4.00,11.40,4.70 17940,17999,17970,2.20,4.00,9.70,4.50 18000,18059,18030,2.90,4.10,11.10,4.70 18060,18119,18090,2.80,4.00,11.60,4.70 18120,18179,18150,2.10,4.00,12.70,4.90 18180,18239,18210,2.50,4.00,15.00,5.20 18240,18299,18270,2.50,4.00,15.00,5.20 18300,18359,18330,2.60,4.00,15.30,5.20 18360,18419,18390,2.70,4.00,13.00,4.90 18420,18479,18450,2.50,4.00,10.90,4.70 18480,18539,18510,2.80,4.00,7.90,4.40 18540,18599,18570,2.20,4.00,8.50,4.40 18600,18659,18630,1.80,4.00,9.60,4.50 18660,18719,18690,1.40,4.00,10.40,4.60 18720,18779,18750,1.70,4.00,9.30,4.50 18780,18839,18810,2.30,4.00,9.80,4.50 18840,18899,18870,2.20,4.00,10.70,4.60 18900,18959,18930,2.30,4.00,11.00,4.70 18960,19019,18990,2.60,4.00,9.70,4.50 19020,19079,19050,3.40,4.10,9.90,4.60 19080,19139,19110,3.10,4.10,9.90,4.60 19140,19199,19170,2.40,4.00,10.70,4.60 19200,19259,19230,2.10,4.00,10.20,4.60 19260,19319,19290,1.60,4.00,9.50,4.50 19320,19379,19350,2.40,4.00,10.80,4.70 19380,19439,19410,2.90,4.10,12.20,4.80 19440,19499,19470,2.70,4.00,13.00,4.90 19500,19559,19530,2.90,4.10,11.90,4.80 19560,19619,19590,3.30,4.10,11.10,4.70 19620,19679,19650,4.10,4.10,12.20,4.80 19680,19739,19710,3.60,4.10,12.70,4.90 19740,19799,19770,2.30,4.00,14.60,5.10 19800,19859,19830,3.20,4.10,12.60,4.90 19860,19919,19890,3.40,4.10,13.90,5.00 19920,19979,19950,4.00,4.10,11.80,4.80 19980,20039,20010,3.70,4.10,11.80,4.80 20040,20099,20070,3.80,4.10,9.70,4.50 20100,20159,20130,3.70,4.10,9.10,4.50 20160,20219,20190,3.40,4.10,10.50,4.60 20220,20279,20250,2.30,4.00,11.20,4.70 20280,20339,20310,2.10,4.00,11.20,4.70 20340,20399,20370,1.90,4.00,11.00,4.70 20400,20459,20430,3.20,4.10,11.90,4.80 20460,20519,20490,2.90,4.00,13.30,5.00 20520,20579,20550,2.80,4.00,13.60,5.00 20580,20639,20610,2.20,4.00,13.50,5.00 20640,20699,20670,0.90,4.00,12.60,4.90 20700,20759,20730,0.70,4.00,14.40,5.10 20760,20819,20790,0.30,4.00,11.70,4.80 20820,20879,20850,3.20,4.10,11.50,4.70 20880,20939,20910,3.20,4.10,8.60,4.40 20940,20999,20970,3.40,4.10,10.00,4.60 21000,21059,21030,1.70,4.00,9.70,4.50 21060,21119,21090,1.90,4.00,11.10,4.70 21120,21179,21150,2.20,4.00,11.40,4.70 21180,21239,21210,2.50,4.00,12.70,4.90 21240,21299,21270,2.50,4.00,12.90,4.90 21300,21359,21330,2.90,4.00,13.50,5.00 21360,21419,21390,2.90,4.10,14.50,5.10 21420,21479,21450,3.90,4.10,14.10,5.10 21480,21539,21510,3.30,4.10,14.60,5.10 21540,21599,21570,3.60,4.10,12.00,4.80 21600,21659,21630,2.50,4.00,10.40,4.60 21660,21719,21690,2.30,4.00,8.10,4.40 21720,21779,21750,2.40,4.00,6.70,4.30 21780,21839,21810,2.90,4.10,4.80,4.10 21840,21899,21870,4.00,4.10,7.50,4.30 21900,21959,21930,3.30,4.10,10.00,4.60 21960,22019,21990,1.40,4.00,12.60,4.90 22020,22079,22050,0.40,4.00,10.80,4.70 22080,22139,22110,0.60,4.00,10.20,4.60 22140,22199,22170,1.70,4.00,10.70,4.60 22200,22259,22230,2.20,4.00,10.60,4.60 22260,22319,22290,2.90,4.00,11.40,4.70 22320,22379,22350,2.40,4.00,11.70,4.80 22380,22439,22410,0.90,4.00,13.30,5.00 22440,22499,22470,0.30,4.00,13.30,5.00 22500,22559,22530,0.40,4.00,14.50,5.10 22560,22619,22590,1.30,4.00,14.30,5.10 22620,22679,22650,1.40,4.00,13.70,5.00 22680,22739,22710,3.30,4.10,16.60,5.40 22740,22799,22770,3.80,4.10,17.60,5.60 22800,22859,22830,4.20,4.10,17.00,5.50 22860,22919,22890,3.90,4.10,12.10,4.80 22920,22979,22950,4.40,4.10,10.50,4.60 22980,23039,23010,5.10,4.20,12.10,4.80 23040,23099,23070,4.30,4.10,12.20,4.80 23100,23159,23130,3.30,4.10,15.00,5.20 23160,23219,23190,2.20,4.00,15.20,5.20 23220,23279,23250,2.60,4.00,17.10,5.50 23280,23339,23310,3.00,4.10,14.00,5.10 23340,23399,23370,3.80,4.10,12.50,4.90 23400,23459,23430,3.90,4.10,11.10,4.70 23460,23519,23490,4.40,4.10,12.20,4.80 23520,23579,23550,4.60,4.10,12.80,4.90 23580,23639,23610,4.80,4.10,14.30,5.10 23640,23699,23670,3.90,4.10,12.50,4.80 23700,23759,23730,3.70,4.10,11.50,4.70 23760,23819,23790,2.40,4.00,10.70,4.60 23820,23879,23850,3.50,4.10,11.80,4.80 23880,23939,23910,3.20,4.10,17.80,5.60 23940,23999,23970,4.30,4.10,17.10,5.50 24000,24059,24030,4.10,4.10,17.70,5.60 24060,24119,24090,4.40,4.10,12.40,4.80 24120,24179,24150,4.50,4.10,15.00,5.20 24180,24239,24210,4.50,4.10,14.80,5.20 24240,24299,24270,4.40,4.10,17.90,5.60 24300,24359,24330,4.30,4.10,18.00,5.60 24360,24419,24390,4.10,4.10,19.90,5.90 24420,24479,24450,4.40,4.10,19.50,5.90 24480,24539,24510,4.00,4.10,20.20,6.00 24540,24599,24570,3.90,4.10,21.50,6.20 24600,24659,24630,3.20,4.10,20.40,6.00 24660,24719,24690,3.80,4.10,20.30,6.00 24720,24779,24750,3.80,4.10,19.10,5.80 24780,24839,24810,4.00,4.10,20.10,6.00 24840,24899,24870,3.30,4.10,21.70,6.20 24900,24959,24930,3.00,4.10,19.40,5.90 24960,25019,24990,3.30,4.10,20.00,5.90 25020,25079,25050,2.60,4.00,16.30,5.40 25080,25139,25110,2.90,4.10,19.80,5.90 25140,25199,25170,2.50,4.00,19.80,5.90 25200,25259,25230,2.60,4.00,25.00,6.80 25260,25319,25290,1.40,4.00,25.40,6.90 25320,25379,25350,0.50,4.00,27.80,7.30 25380,25439,25410,1.50,4.00,25.90,7.00 25440,25499,25470,4.20,4.10,24.20,6.70 25500,25559,25530,5.70,4.20,20.60,6.00 25560,25619,25590,6.10,4.20,18.50,5.70 25620,25679,25650,4.70,4.10,18.20,5.70 25680,25739,25710,3.90,4.10,21.60,6.20 25740,25799,25770,3.50,4.10,28.20,7.40 25800,25859,25830,3.80,4.10,27.80,7.30 25860,25919,25890,3.70,4.10,24.90,6.80 25920,25979,25950,3.80,4.10,18.90,5.80 25980,26039,26010,5.60,4.20,19.90,5.90 26040,26099,26070,6.70,4.30,19.90,5.90 26100,26159,26130,7.30,4.30,19.40,5.80 26160,26219,26190,6.00,4.20,18.70,5.70 26220,26279,26250,6.50,4.20,20.40,6.00 26280,26339,26310,5.80,4.20,18.50,5.70 26340,26399,26370,7.40,4.30,19.90,5.90 26400,26459,26430,7.00,4.30,17.00,5.50 26460,26519,26490,7.30,4.30,19.10,5.80 26520,26579,26550,6.40,4.20,16.90,5.50 26580,26639,26610,6.80,4.30,16.70,5.40 26640,26699,26670,6.80,4.30,22.00,6.30 26700,26759,26730,5.40,4.20,26.30,7.00 26760,26819,26790,4.90,4.10,32.40,8.20 26820,26879,26850,5.10,4.20,29.30,7.60 26880,26939,26910,5.80,4.20,26.20,7.00 26940,26999,26970,7.00,4.30,23.90,6.60 27000,27059,27030,7.70,4.30,24.00,6.60 27060,27119,27090,7.20,4.30,25.90,7.00 27120,27179,27150,6.00,4.20,23.90,6.60 27180,27239,27210,5.80,4.20,25.60,6.90 27240,27299,27270,5.70,4.20,30.10,7.70 27300,27359,27330,6.10,4.20,34.40,8.60 27360,27419,27390,6.10,4.20,31.30,8.00 27420,27479,27450,6.30,4.20,26.30,7.00 27480,27539,27510,6.50,4.30,23.10,6.50 27540,27599,27570,7.20,4.30,23.90,6.60 27600,27659,27630,6.90,4.30,23.50,6.50 27660,27719,27690,6.00,4.20,28.70,7.50 27720,27779,27750,5.40,4.20,31.40,8.00 27780,27839,27810,6.30,4.20,32.30,8.20 27840,27899,27870,6.60,4.30,29.10,7.60 27900,27959,27930,8.30,4.40,29.60,7.60 27960,28019,27990,10.00,4.60,29.90,7.70 28020,28079,28050,11.90,4.80,31.20,7.90 28080,28139,28110,11.90,4.80,33.10,8.30 28140,28199,28170,12.60,4.90,35.30,8.70 28200,28259,28230,11.70,4.80,36.00,8.90 28260,28319,28290,10.30,4.60,35.40,8.70 28320,28379,28350,7.60,4.30,43.10,10.30 28380,28439,28410,6.80,4.30,49.80,11.70 28440,28499,28470,6.80,4.30,55.50,12.90 28500,28559,28530,7.00,4.30,49.40,11.60 28560,28619,28590,7.30,4.30,48.00,11.30 28620,28679,28650,8.30,4.40,42.50,10.20 28680,28739,28710,10.40,4.60,44.90,10.70 28740,28799,28770,12.40,4.80,46.00,10.90 28800,28859,28830,12.50,4.90,52.00,12.10 28860,28919,28890,11.90,4.80,56.90,13.10 28920,28979,28950,11.30,4.70,58.20,13.40 28980,29039,29010,11.70,4.80,57.60,13.30 29040,29099,29070,12.90,4.90,54.30,12.60 29100,29159,29130,13.50,5.00,50.30,11.80 29160,29219,29190,14.80,5.20,48.70,11.40 29220,29279,29250,15.00,5.20,48.60,11.40 29280,29339,29310,15.10,5.20,52.20,12.20 29340,29399,29370,14.20,5.10,53.90,12.50 29400,29459,29430,14.20,5.10,55.30,12.80 29460,29519,29490,15.80,5.30,53.40,12.40 29520,29579,29550,17.90,5.60,54.60,12.70 29580,29639,29610,18.50,5.70,57.70,13.30 29640,29699,29670,17.90,5.60,60.40,13.90 29700,29759,29730,18.20,5.70,61.90,14.20 29760,29819,29790,17.70,5.60,56.40,13.00 29820,29879,29850,17.90,5.60,54.50,12.60 29880,29939,29910,17.00,5.50,53.00,12.30 29940,29999,29970,17.10,5.50,62.50,14.30 30000,30059,30030,16.50,5.40,79.10,17.90 30060,30119,30090,16.60,5.40,75.70,17.10 30120,30179,30150,18.50,5.70,81.30,18.30 30180,30239,30210,20.80,6.10,72.80,16.50 30240,30299,30270,22.00,6.30,77.20,17.50 30300,30359,30330,21.90,6.30,65.90,15.00 30360,30419,30390,21.80,6.20,59.60,13.70 30420,30479,30450,21.70,6.20,58.60,13.50 30480,30539,30510,25.00,6.80,60.30,13.90 30540,30599,30570,24.90,6.80,60.80,14.00 30600,30659,30630,26.00,7.00,64.90,14.80 30660,30719,30690,24.70,6.80,62.30,14.30 30720,30779,30750,27.40,7.20,66.80,15.20 30780,30839,30810,28.20,7.40,67.20,15.30 30840,30899,30870,28.90,7.50,70.30,16.00 30900,30959,30930,28.70,7.50,67.00,15.30 30960,31019,30990,29.30,7.60,64.10,14.70 31020,31079,31050,29.40,7.60,62.90,14.40 31080,31139,31110,31.10,7.90,64.40,14.70 31140,31199,31170,32.40,8.20,66.70,15.20 31200,31259,31230,32.90,8.30,68.80,15.70 31260,31319,31290,32.20,8.10,68.80,15.70 31320,31379,31350,30.30,7.80,67.80,15.40 31380,31439,31410,29.80,7.70,68.90,15.70 31440,31499,31470,29.50,7.60,70.10,15.90 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84180,84239,84210,8.50,4.40,23.60,6.60 84240,84299,84270,9.60,4.50,25.70,6.90 84300,84359,84330,8.00,4.40,24.90,6.80 84360,84419,84390,7.00,4.30,24.30,6.70 84420,84479,84450,6.70,4.30,20.30,6.00 84480,84539,84510,8.20,4.40,19.10,5.80 84540,84599,84570,8.00,4.40,21.20,6.10 84600,84659,84630,7.10,4.30,27.90,7.30 84660,84719,84690,5.40,4.20,27.10,7.20 84720,84779,84750,4.40,4.10,26.40,7.00 84780,84839,84810,5.00,4.20,24.30,6.70 84840,84899,84870,7.70,4.30,29.70,7.70 84900,84959,84930,8.80,4.40,30.30,7.80 84960,85019,84990,9.20,4.50,29.00,7.50 85020,85079,85050,8.40,4.40,29.20,7.60 85080,85139,85110,9.40,4.50,29.50,7.60 85140,85199,85170,8.30,4.40,30.80,7.90 85200,85259,85230,6.70,4.30,26.30,7.00 85260,85319,85290,5.90,4.20,23.30,6.50 85320,85379,85350,6.30,4.20,21.50,6.20 85380,85439,85410,6.70,4.30,21.80,6.20 85440,85499,85470,8.50,4.40,25.70,6.90 85500,85559,85530,8.80,4.40,26.60,7.10 85560,85619,85590,8.30,4.40,26.70,7.10 85620,85679,85650,7.10,4.30,25.00,6.80 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