49, 1001
Cantrell, Christopher A
Atmospheric Chemistry Division/NESL/NCAR
HO2 and HO2+RO2 from PeRCIMS at Manitou Experimental Forest
BEACHON-RoMBAS
1,1
2011, 08, 22, 2011, 12, 03
0
Start_MST, seconds, number_of_seconds_from_0000_MST
6
1,1,1,1,1,1
-99999,-99999,-99999,-99999,-99999,-99999
Stop_MST, seconds, number_of_seconds_from_0000_MST
Mid_MST, seconds, number_of_seconds_from_0000_MST
HO2, pptv, HO2_mixing_ratio
HO2_uncertainty, pptv, HO2_2_sigma_uncertainty
HO2+RO2, pptv, HO2+RO2_mixing_ratio
HO2+RO2_uncertainty, pptv, HO2+RO2_2_sigma_uncertainty
5
These data are reduced using four factors determined in the laboratory and in the field: F_lo and F_hi are the radical sensitivities in the
HO2+RO2 and HO2 modes, respectively (units pptv/ion ratio).  Alpha_lo and alpha_hi are the ratios of RO2 to HO2 sensitivity in the HO2+RO2
and HO2 modes, respectively.  HO2+RO2 concentrations are then S_lo*F_lo-(S_lo*F_lo - S_hi*F_hi)*(alpha_lo - 1)/(alpha_lo - alpha_hi) .
HO2 concentrations are S_lo*F_lo-(S_lo*F_lo - S_hi*F_hi)*(alpha_lo)/(alpha_lo - alpha_hi) . S_lo is the background corrected ion ratio in the HO2+RO2
mode, and S_hi is the background corrected ion ratio in the HO2 mode.  The ion ratios are mass 97 signal count rate minus background count rate divided by mass 62 count rate.
24
PI_CONTACT_INFO: 303-497-1479, NCAR, 3090 Center Green Dr., Boulder, CO 80301, cantrell@ucar.edu
PLATFORM: Seacontainer #1
LOCATION: Manitou Experimental Forest, Woodland Park, Colorado, USA
ASSOCIATED_DATA: N/A
INSTRUMENT_INFO: These data were collected using a CIMS based instrument.  An inlet collects ambient air from the
free air stream and adds reagents, includling O2 or N2 diluents, and NO and SO2 reagent gases.  This method, called oxygen dilution modulation leads to nearly 100%
measurement of HO2 and RO2 in the O2 dilution/low reagent concentration mode, whereas RO2 is measured with less than 15% efficiency in the N2 dilution/higher reagent concentration mode.
This is because the chemistry converts peroxy radicals to H2SO4 efficiently in the O2 mode, but RO2 radicals are converted to RONO in the N2 mode.  The H2SO4 thus produced
is ionized by reaction with NO3- ions.  The reagent and product ions are detected by mass spectrometry using quadrupole mass filtering and counting by a channel
electron multiplier operating in the negative ion mode.  
DATA_INFO: Signal data for HO2+RO2 are collected during the 0-7 second time interval, and for HO2 in 30-37 second time interval.
UNCERTAINTY: approximately 35% (2 sigma) for values well above 2 pptv; estimates are listed for each data point (2 sigma)
ULOD_FLAG: -7777
ULOD_VALUE: N/A
LLOD_FLAG: -8888
LLOD_VALUE: N/A
DM_CONTACT_INFO: N/A
PROJECT_INFO: BEACHON-RoMBAS, 20-Jul-2011 to 30-Aug-2011
STIPULATIONS_ON_USE: contact PI BEFORE use/presentation/publication
OTHER_COMMENTS: 
REVISION: R1; R0
R1: final data
R0: preliminary data
Start_MST,Stop_MST,Mid_MST,HO2,HO2_uncertainty,HO2+RO2,HO2+RO2_uncertainty
0,59,30,8.70,4.40,14.40,5.10
60,119,90,9.10,4.50,15.00,5.20
120,179,150,10.10,4.60,17.60,5.60
180,239,210,9.40,4.50,18.10,5.60
240,299,270,9.30,4.50,19.20,5.80
300,359,330,9.30,4.50,18.40,5.70
360,419,390,10.30,4.60,22.00,6.30
420,479,450,10.20,4.60,23.80,6.60
480,539,510,7.60,4.30,22.50,6.40
540,599,570,6.80,4.30,19.80,5.90
600,659,630,5.20,4.20,16.70,5.40
660,719,690,7.50,4.30,15.40,5.20
720,779,750,8.10,4.40,14.10,5.10
780,839,810,8.70,4.40,13.70,5.00
840,899,870,7.20,4.30,16.30,5.40
900,959,930,6.10,4.20,18.80,5.80
960,1019,990,6.20,4.20,20.40,6.00
1020,1079,1050,6.10,4.20,20.30,6.00
1080,1139,1110,6.30,4.20,20.40,6.00
1140,1199,1170,6.20,4.20,20.80,6.10
1200,1259,1230,6.80,4.30,21.00,6.10
1260,1319,1290,6.40,4.20,18.80,5.80
1320,1379,1350,5.70,4.20,19.40,5.90
1380,1439,1410,4.90,4.10,16.80,5.50
1440,1499,1470,6.70,4.30,19.60,5.90
1500,1559,1530,8.00,4.40,18.70,5.70
1560,1619,1590,8.60,4.40,19.30,5.80
1620,1679,1650,7.40,4.30,17.80,5.60
1680,1739,1710,7.00,4.30,15.90,5.30
1740,1799,1770,7.00,4.30,15.80,5.30
1800,1859,1830,7.80,4.30,14.90,5.20
1860,1919,1890,7.40,4.30,18.80,5.80
1920,1979,1950,7.80,4.40,21.70,6.20
1980,2039,2010,6.90,4.30,23.70,6.60
2040,2099,2070,7.30,4.30,23.40,6.50
2100,2159,2130,6.40,4.20,21.20,6.10
2160,2219,2190,5.90,4.20,19.20,5.80
2220,2279,2250,4.70,4.10,16.60,5.40
2280,2339,2310,5.10,4.20,15.50,5.30
2340,2399,2370,5.50,4.20,16.70,5.40
2400,2459,2430,5.80,4.20,19.70,5.90
2460,2519,2490,6.00,4.20,22.80,6.40
2520,2579,2550,7.30,4.30,26.50,7.10
2580,2639,2610,7.20,4.30,23.70,6.60
2640,2699,2670,7.40,4.30,23.90,6.60
2700,2759,2730,7.10,4.30,17.70,5.60
2760,2819,2790,8.70,4.40,20.80,6.10
2820,2879,2850,8.10,4.40,17.00,5.50
2880,2939,2910,7.70,4.30,18.60,5.70
2940,2999,2970,7.20,4.30,18.20,5.70
3000,3059,3030,6.70,4.30,21.30,6.20
3060,3119,3090,6.70,4.30,20.60,6.10
3120,3179,3150,7.10,4.30,19.30,5.80
3180,3239,3210,6.60,4.30,17.30,5.50
3240,3299,3270,5.80,4.20,15.90,5.30
3300,3359,3330,4.20,4.10,12.80,4.90
3360,3419,3390,4.70,4.10,12.30,4.80
3420,3479,3450,4.90,4.10,13.10,4.90
3480,3539,3510,5.00,4.10,13.20,4.90
3540,3599,3570,4.70,4.10,12.90,4.90
3600,3659,3630,4.20,4.10,13.80,5.00
3660,3719,3690,5.30,4.20,14.80,5.20
3720,3779,3750,6.70,4.30,16.00,5.30
3780,3839,3810,8.10,4.40,15.70,5.30
3840,3899,3870,7.20,4.30,18.50,5.70
3900,3959,3930,7.60,4.30,20.50,6.00
3960,4019,3990,7.70,4.30,22.30,6.30
4020,4079,4050,7.70,4.30,20.80,6.10
4080,4139,4110,7.00,4.30,21.70,6.20
4140,4199,4170,5.60,4.20,18.60,5.70
4200,4259,4230,6.00,4.20,17.90,5.60
4260,4319,4290,3.60,4.10,15.10,5.20
4320,4379,4350,3.20,4.10,17.30,5.50
4380,4439,4410,3.70,4.10,19.90,5.90
4440,4499,4470,5.80,4.20,21.60,6.20
4500,4559,4530,5.40,4.20,21.20,6.20
4560,4619,4590,4.30,4.10,18.00,5.60
4620,4679,4650,4.00,4.10,14.20,5.10
4680,4739,4710,5.30,4.20,12.70,4.90
4740,4799,4770,4.60,4.10,12.50,4.90
4800,4859,4830,4.10,4.10,14.70,5.10
4860,4919,4890,5.20,4.20,20.20,6.00
4920,4979,4950,6.50,4.20,21.80,6.20
4980,5039,5010,6.70,4.30,23.10,6.50
5040,5099,5070,4.50,4.10,21.40,6.20
5100,5159,5130,3.90,4.10,19.50,5.90
5160,5219,5190,3.50,4.10,17.60,5.60
5220,5279,5250,3.80,4.10,14.50,5.10
5280,5339,5310,3.30,4.10,14.40,5.10
5340,5399,5370,3.00,4.10,14.10,5.10
5400,5459,5430,3.90,4.10,14.50,5.10
5460,5519,5490,4.00,4.10,15.20,5.20
5520,5579,5550,4.80,4.10,17.50,5.60
5580,5639,5610,5.90,4.20,18.50,5.70
5640,5699,5670,6.50,4.20,19.20,5.80
5700,5759,5730,5.70,4.20,17.90,5.60
5760,5819,5790,4.30,4.10,17.30,5.50
5820,5879,5850,4.40,4.10,16.30,5.40
5880,5939,5910,5.20,4.20,16.70,5.40
5940,5999,5970,4.30,4.10,16.70,5.40
6000,6059,6030,3.20,4.10,16.10,5.30
6060,6119,6090,3.10,4.10,15.90,5.30
6120,6179,6150,2.50,4.00,16.70,5.40
6180,6239,6210,2.90,4.00,17.10,5.50
6240,6299,6270,3.20,4.10,16.50,5.40
6300,6359,6330,4.00,4.10,13.00,4.90
6360,6419,6390,3.90,4.10,10.60,4.60
6420,6479,6450,4.30,4.10,8.90,4.50
6480,6539,6510,4.70,4.10,10.90,4.70
6540,6599,6570,3.20,4.10,12.50,4.90
6600,6659,6630,0.90,4.00,12.60,4.90
6660,6719,6690,2.50,4.00,14.70,5.10
6720,6779,6750,4.70,4.10,19.40,5.80
6780,6839,6810,5.60,4.20,21.50,6.20
6840,6899,6870,4.70,4.10,22.40,6.30
6900,6959,6930,4.30,4.10,15.60,5.30
6960,7019,6990,5.50,4.20,14.70,5.10
7020,7079,7050,4.20,4.10,13.10,4.90
7080,7139,7110,2.60,4.00,14.70,5.10
7140,7199,7170,0.80,4.00,15.50,5.30
7200,7259,7230,1.30,4.00,18.40,5.70
7260,7319,7290,2.00,4.00,19.60,5.90
7320,7379,7350,2.30,4.00,17.90,5.60
7380,7439,7410,2.70,4.00,16.20,5.40
7440,7499,7470,4.10,4.10,17.30,5.50
7500,7559,7530,5.10,4.20,19.70,5.90
7560,7619,7590,5.10,4.20,19.20,5.80
7620,7679,7650,5.30,4.20,19.10,5.80
7680,7739,7710,4.60,4.10,17.30,5.50
7740,7799,7770,5.50,4.20,16.80,5.40
7800,7859,7830,5.20,4.20,15.50,5.30
7860,7919,7890,6.80,4.30,15.80,5.30
7920,7979,7950,6.20,4.20,14.70,5.10
7980,8039,8010,5.60,4.20,14.80,5.20
8040,8099,8070,4.30,4.10,14.10,5.10
8100,8159,8130,5.80,4.20,13.30,5.00
8160,8219,8190,4.60,4.10,10.60,4.60
8220,8279,8250,5.80,4.20,11.70,4.80
8280,8339,8310,4.30,4.10,12.40,4.80
8340,8399,8370,6.20,4.20,16.00,5.30
8400,8459,8430,6.30,4.20,16.60,5.40
8460,8519,8490,5.10,4.20,16.10,5.30
8520,8579,8550,6.10,4.20,16.60,5.40
8580,8639,8610,6.00,4.20,16.10,5.30
8640,8699,8670,7.70,4.30,16.90,5.50
8700,8759,8730,7.60,4.30,16.10,5.30
8760,8819,8790,6.10,4.20,15.10,5.20
8820,8879,8850,4.20,4.10,15.40,5.20
8880,8939,8910,2.80,4.00,13.90,5.00
8940,8999,8970,3.20,4.10,15.20,5.20
9000,9059,9030,3.80,4.10,13.60,5.00
9060,9119,9090,3.80,4.10,14.40,5.10
9120,9179,9150,3.90,4.10,13.20,4.90
9180,9239,9210,2.90,4.10,10.70,4.60
9240,9299,9270,3.30,4.10,13.40,5.00
9300,9359,9330,1.30,4.00,11.90,4.80
9360,9419,9390,2.20,4.00,13.20,4.90
9420,9479,9450,3.20,4.10,13.60,5.00
9480,9539,9510,4.80,4.10,14.40,5.10
9540,9599,9570,5.50,4.20,17.60,5.60
9600,9659,9630,5.20,4.20,15.90,5.30
9660,9719,9690,6.90,4.30,17.80,5.60
9720,9779,9750,6.80,4.30,18.10,5.60
9780,9839,9810,6.30,4.20,17.60,5.60
9840,9899,9870,5.00,4.10,14.90,5.20
9900,9959,9930,5.00,4.10,12.50,4.90
9960,10019,9990,4.40,4.10,11.40,4.70
10020,10079,10050,4.70,4.10,13.30,5.00
10080,10139,10110,5.10,4.20,13.50,5.00
10140,10199,10170,4.60,4.10,12.70,4.90
10200,10259,10230,4.60,4.10,11.20,4.70
10260,10319,10290,4.50,4.10,11.50,4.70
10320,10379,10350,5.00,4.10,12.50,4.90
10380,10439,10410,4.30,4.10,16.90,5.50
10440,10499,10470,4.70,4.10,19.40,5.80
10500,10559,10530,4.40,4.10,18.70,5.70
10560,10619,10590,5.00,4.10,14.00,5.10
10620,10679,10650,4.80,4.10,11.90,4.80
10680,10739,10710,5.90,4.20,13.00,4.90
10740,10799,10770,5.60,4.20,15.60,5.30
10800,10859,10830,4.70,4.10,15.70,5.30
10860,10919,10890,3.40,4.10,13.80,5.00
10920,10979,10950,4.80,4.10,13.80,5.00
10980,11039,11010,6.60,4.30,15.80,5.30
11040,11099,11070,8.30,4.40,16.70,5.40
11100,11159,11130,6.50,4.30,10.30,4.60
11160,11219,11190,3.20,4.10,2.90,4.00
11220,11279,11250,-99999.00,-99999.00,-99999.00,-99999.00
11280,11339,11310,-99999.00,-99999.00,-99999.00,-99999.00
11340,11399,11370,-99999.00,-99999.00,-99999.00,-99999.00
11400,11459,11430,-99999.00,-99999.00,-99999.00,-99999.00
11460,11519,11490,-99999.00,-99999.00,-99999.00,-99999.00
11520,11579,11550,-99999.00,-99999.00,-99999.00,-99999.00
11580,11639,11610,-99999.00,-99999.00,-99999.00,-99999.00
11640,11699,11670,-99999.00,-99999.00,-99999.00,-99999.00
11700,11759,11730,-99999.00,-99999.00,-99999.00,-99999.00
11760,11819,11790,-99999.00,-99999.00,-99999.00,-99999.00
11820,11879,11850,-99999.00,-99999.00,-99999.00,-99999.00
11880,11939,11910,-99999.00,-99999.00,-99999.00,-99999.00
11940,11999,11970,-99999.00,-99999.00,-99999.00,-99999.00
12000,12059,12030,-99999.00,-99999.00,-99999.00,-99999.00
12060,12119,12090,-99999.00,-99999.00,-99999.00,-99999.00
12120,12179,12150,-99999.00,-99999.00,-99999.00,-99999.00
12180,12239,12210,-99999.00,-99999.00,-99999.00,-99999.00
12240,12299,12270,-99999.00,-99999.00,-99999.00,-99999.00
12300,12359,12330,-99999.00,-99999.00,-99999.00,-99999.00
12360,12419,12390,-99999.00,-99999.00,-99999.00,-99999.00
12420,12479,12450,-99999.00,-99999.00,-99999.00,-99999.00
12480,12539,12510,-99999.00,-99999.00,-99999.00,-99999.00
12540,12599,12570,-99999.00,-99999.00,-99999.00,-99999.00
12600,12659,12630,-99999.00,-99999.00,-99999.00,-99999.00
12660,12719,12690,-99999.00,-99999.00,-99999.00,-99999.00
12720,12779,12750,-99999.00,-99999.00,-99999.00,-99999.00
12780,12839,12810,-99999.00,-99999.00,-99999.00,-99999.00
12840,12899,12870,-99999.00,-99999.00,-99999.00,-99999.00
12900,12959,12930,-99999.00,-99999.00,-99999.00,-99999.00
12960,13019,12990,-99999.00,-99999.00,-99999.00,-99999.00
13020,13079,13050,-99999.00,-99999.00,-99999.00,-99999.00
13080,13139,13110,-99999.00,-99999.00,-99999.00,-99999.00
13140,13199,13170,-99999.00,-99999.00,-99999.00,-99999.00
13200,13259,13230,-99999.00,-99999.00,-99999.00,-99999.00
13260,13319,13290,-99999.00,-99999.00,-99999.00,-99999.00
13320,13379,13350,-99999.00,-99999.00,-99999.00,-99999.00
13380,13439,13410,-99999.00,-99999.00,-99999.00,-99999.00
13440,13499,13470,-99999.00,-99999.00,-99999.00,-99999.00
13500,13559,13530,-99999.00,-99999.00,-99999.00,-99999.00
13560,13619,13590,-99999.00,-99999.00,-99999.00,-99999.00
13620,13679,13650,-99999.00,-99999.00,-99999.00,-99999.00
13680,13739,13710,-99999.00,-99999.00,-99999.00,-99999.00
13740,13799,13770,-99999.00,-99999.00,-99999.00,-99999.00
13800,13859,13830,-99999.00,-99999.00,-99999.00,-99999.00
13860,13919,13890,-99999.00,-99999.00,-99999.00,-99999.00
13920,13979,13950,-99999.00,-99999.00,-99999.00,-99999.00
13980,14039,14010,-99999.00,-99999.00,-99999.00,-99999.00
14040,14099,14070,-99999.00,-99999.00,-99999.00,-99999.00
14100,14159,14130,-99999.00,-99999.00,-99999.00,-99999.00
14160,14219,14190,-99999.00,-99999.00,-99999.00,-99999.00
14220,14279,14250,-99999.00,-99999.00,-99999.00,-99999.00
14280,14339,14310,-99999.00,-99999.00,-99999.00,-99999.00
14340,14399,14370,-99999.00,-99999.00,-99999.00,-99999.00
14400,14459,14430,-99999.00,-99999.00,-99999.00,-99999.00
14460,14519,14490,-99999.00,-99999.00,-99999.00,-99999.00
14520,14579,14550,-99999.00,-99999.00,-99999.00,-99999.00
14580,14639,14610,-99999.00,-99999.00,-99999.00,-99999.00
14640,14699,14670,-99999.00,-99999.00,-99999.00,-99999.00
14700,14759,14730,-99999.00,-99999.00,-99999.00,-99999.00
14760,14819,14790,-99999.00,-99999.00,-99999.00,-99999.00
14820,14879,14850,-99999.00,-99999.00,-99999.00,-99999.00
14880,14939,14910,-99999.00,-99999.00,-99999.00,-99999.00
14940,14999,14970,-99999.00,-99999.00,-99999.00,-99999.00
15000,15059,15030,-99999.00,-99999.00,-99999.00,-99999.00
15060,15119,15090,-99999.00,-99999.00,-99999.00,-99999.00
15120,15179,15150,-99999.00,-99999.00,-99999.00,-99999.00
15180,15239,15210,-99999.00,-99999.00,-99999.00,-99999.00
15240,15299,15270,-99999.00,-99999.00,-99999.00,-99999.00
15300,15359,15330,-99999.00,-99999.00,-99999.00,-99999.00
15360,15419,15390,-99999.00,-99999.00,-99999.00,-99999.00
15420,15479,15450,-99999.00,-99999.00,-99999.00,-99999.00
15480,15539,15510,-99999.00,-99999.00,-99999.00,-99999.00
15540,15599,15570,-99999.00,-99999.00,-99999.00,-99999.00
15600,15659,15630,-99999.00,-99999.00,-99999.00,-99999.00
15660,15719,15690,-99999.00,-99999.00,-99999.00,-99999.00
15720,15779,15750,-99999.00,-99999.00,-99999.00,-99999.00
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84300,84359,84330,5.80,4.20,15.60,5.30
84360,84419,84390,5.50,4.20,14.30,5.10
84420,84479,84450,4.60,4.10,14.90,5.20
84480,84539,84510,3.70,4.10,13.20,4.90
84540,84599,84570,2.80,4.00,14.30,5.10
84600,84659,84630,3.60,4.10,16.30,5.40
84660,84719,84690,3.90,4.10,15.30,5.20
84720,84779,84750,4.70,4.10,15.90,5.30
84780,84839,84810,4.70,4.10,14.70,5.10
84840,84899,84870,4.90,4.10,15.80,5.30
84900,84959,84930,4.00,4.10,13.80,5.00
84960,85019,84990,4.30,4.10,14.30,5.10
85020,85079,85050,3.80,4.10,14.50,5.10
85080,85139,85110,4.30,4.10,13.30,5.00
85140,85199,85170,3.30,4.10,9.70,4.50
85200,85259,85230,2.10,4.00,9.40,4.50
85260,85319,85290,2.80,4.00,14.10,5.10
85320,85379,85350,2.20,4.00,17.20,5.50
85380,85439,85410,3.40,4.10,17.30,5.50
85440,85499,85470,3.00,4.10,14.90,5.20
85500,85559,85530,4.40,4.10,15.00,5.20
85560,85619,85590,5.20,4.20,15.00,5.20
85620,85679,85650,5.30,4.20,15.30,5.20
85680,85739,85710,3.50,4.10,15.00,5.20
85740,85799,85770,2.70,4.00,15.60,5.30
85800,85859,85830,3.10,4.10,15.40,5.20
85860,85919,85890,4.20,4.10,13.70,5.00
85920,85979,85950,5.40,4.20,12.10,4.80
85980,86039,86010,4.90,4.10,12.30,4.80
86040,86099,86070,5.40,4.20,15.10,5.20
86100,86159,86130,4.60,4.10,14.20,5.10
86160,86219,86190,5.10,4.20,15.30,5.20
86220,86279,86250,5.10,4.20,13.90,5.00
86280,86339,86310,5.00,4.10,17.00,5.50
86340,86399,86370,4.80,4.10,16.40,5.40