49, 1001 Cantrell, Christopher A Atmospheric Chemistry Division/NESL/NCAR HO2 and HO2+RO2 from PeRCIMS at Manitou Experimental Forest BEACHON-RoMBAS 1,1 2011, 08, 21, 2011, 12, 03 0 Start_MST, seconds, number_of_seconds_from_0000_MST 6 1,1,1,1,1,1 -99999,-99999,-99999,-99999,-99999,-99999 Stop_MST, seconds, number_of_seconds_from_0000_MST Mid_MST, seconds, number_of_seconds_from_0000_MST HO2, pptv, HO2_mixing_ratio HO2_uncertainty, pptv, HO2_2_sigma_uncertainty HO2+RO2, pptv, HO2+RO2_mixing_ratio HO2+RO2_uncertainty, pptv, HO2+RO2_2_sigma_uncertainty 5 These data are reduced using four factors determined in the laboratory and in the field: F_lo and F_hi are the radical sensitivities in the HO2+RO2 and HO2 modes, respectively (units pptv/ion ratio). Alpha_lo and alpha_hi are the ratios of RO2 to HO2 sensitivity in the HO2+RO2 and HO2 modes, respectively. HO2+RO2 concentrations are then S_lo*F_lo-(S_lo*F_lo - S_hi*F_hi)*(alpha_lo - 1)/(alpha_lo - alpha_hi) . HO2 concentrations are S_lo*F_lo-(S_lo*F_lo - S_hi*F_hi)*(alpha_lo)/(alpha_lo - alpha_hi) . S_lo is the background corrected ion ratio in the HO2+RO2 mode, and S_hi is the background corrected ion ratio in the HO2 mode. The ion ratios are mass 97 signal count rate minus background count rate divided by mass 62 count rate. 24 PI_CONTACT_INFO: 303-497-1479, NCAR, 3090 Center Green Dr., Boulder, CO 80301, cantrell@ucar.edu PLATFORM: Seacontainer #1 LOCATION: Manitou Experimental Forest, Woodland Park, Colorado, USA ASSOCIATED_DATA: N/A INSTRUMENT_INFO: These data were collected using a CIMS based instrument. An inlet collects ambient air from the free air stream and adds reagents, includling O2 or N2 diluents, and NO and SO2 reagent gases. This method, called oxygen dilution modulation leads to nearly 100% measurement of HO2 and RO2 in the O2 dilution/low reagent concentration mode, whereas RO2 is measured with less than 15% efficiency in the N2 dilution/higher reagent concentration mode. This is because the chemistry converts peroxy radicals to H2SO4 efficiently in the O2 mode, but RO2 radicals are converted to RONO in the N2 mode. The H2SO4 thus produced is ionized by reaction with NO3- ions. The reagent and product ions are detected by mass spectrometry using quadrupole mass filtering and counting by a channel electron multiplier operating in the negative ion mode. DATA_INFO: Signal data for HO2+RO2 are collected during the 0-7 second time interval, and for HO2 in 30-37 second time interval. UNCERTAINTY: approximately 35% (2 sigma) for values well above 2 pptv; estimates are listed for each data point (2 sigma) ULOD_FLAG: -7777 ULOD_VALUE: N/A LLOD_FLAG: -8888 LLOD_VALUE: N/A DM_CONTACT_INFO: N/A PROJECT_INFO: BEACHON-RoMBAS, 20-Jul-2011 to 30-Aug-2011 STIPULATIONS_ON_USE: contact PI BEFORE use/presentation/publication OTHER_COMMENTS: REVISION: R1; R0 R1: final data R0: preliminary data Start_MST,Stop_MST,Mid_MST,HO2,HO2_uncertainty,HO2+RO2,HO2+RO2_uncertainty 0,59,30,4.90,4.10,7.60,4.30 60,119,90,4.70,4.10,7.10,4.30 120,179,150,4.40,4.10,5.40,4.20 180,239,210,4.60,4.10,3.30,4.10 240,299,270,4.20,4.10,3.20,4.10 300,359,330,4.20,4.10,4.00,4.10 360,419,390,3.90,4.10,6.60,4.30 420,479,450,4.70,4.10,7.90,4.40 480,539,510,4.60,4.10,6.90,4.30 540,599,570,4.60,4.10,5.60,4.20 600,659,630,5.00,4.10,4.10,4.10 660,719,690,5.20,4.20,6.70,4.30 720,779,750,3.90,4.10,7.10,4.30 780,839,810,2.70,4.00,7.90,4.40 840,899,870,1.90,4.00,7.40,4.30 900,959,930,2.50,4.00,8.20,4.40 960,1019,990,3.30,4.10,7.70,4.30 1020,1079,1050,4.10,4.10,6.90,4.30 1080,1139,1110,4.10,4.10,4.70,4.10 1140,1199,1170,4.40,4.10,5.70,4.20 1200,1259,1230,3.90,4.10,7.10,4.30 1260,1319,1290,4.80,4.10,7.80,4.30 1320,1379,1350,5.00,4.10,8.40,4.40 1380,1439,1410,5.50,4.20,1.80,4.00 1440,1499,1470,5.90,4.20,1.80,4.00 1500,1559,1530,5.40,4.20,0.00,4.00 1560,1619,1590,5.40,4.20,5.90,4.20 1620,1679,1650,4.50,4.10,6.00,4.20 1680,1739,1710,4.00,4.10,4.40,4.10 1740,1799,1770,3.50,4.10,2.60,4.00 1800,1859,1830,3.70,4.10,2.50,4.00 1860,1919,1890,4.10,4.10,3.40,4.10 1920,1979,1950,5.30,4.20,4.40,4.10 1980,2039,2010,5.10,4.20,5.00,4.10 2040,2099,2070,4.10,4.10,5.50,4.20 2100,2159,2130,2.40,4.00,5.50,4.20 2160,2219,2190,2.80,4.00,5.30,4.20 2220,2279,2250,3.40,4.10,5.80,4.20 2280,2339,2310,4.10,4.10,6.60,4.30 2340,2399,2370,3.30,4.10,6.40,4.20 2400,2459,2430,2.60,4.00,6.30,4.20 2460,2519,2490,2.10,4.00,5.90,4.20 2520,2579,2550,2.30,4.00,5.60,4.20 2580,2639,2610,2.50,4.00,5.90,4.20 2640,2699,2670,2.50,4.00,6.80,4.30 2700,2759,2730,3.20,4.10,8.40,4.40 2760,2819,2790,3.40,4.10,9.20,4.50 2820,2879,2850,3.20,4.10,9.50,4.50 2880,2939,2910,1.50,4.00,8.60,4.40 2940,2999,2970,0.00,4.00,6.80,4.30 3000,3059,3030,0.40,4.00,6.90,4.30 3060,3119,3090,0.80,4.00,6.00,4.20 3120,3179,3150,2.10,4.00,6.70,4.30 3180,3239,3210,2.70,4.00,4.60,4.10 3240,3299,3270,3.20,4.10,4.00,4.10 3300,3359,3330,2.90,4.10,3.20,4.10 3360,3419,3390,2.40,4.00,3.50,4.10 3420,3479,3450,1.80,4.00,3.00,4.10 3480,3539,3510,2.50,4.00,4.30,4.10 3540,3599,3570,2.20,4.00,4.20,4.10 3600,3659,3630,2.60,4.00,5.70,4.20 3660,3719,3690,1.60,4.00,5.10,4.20 3720,3779,3750,1.40,4.00,5.70,4.20 3780,3839,3810,0.90,4.00,4.90,4.10 3840,3899,3870,1.10,4.00,4.30,4.10 3900,3959,3930,1.20,4.00,3.20,4.10 3960,4019,3990,2.00,4.00,3.10,4.10 4020,4079,4050,2.00,4.00,2.20,4.00 4080,4139,4110,2.50,4.00,3.30,4.10 4140,4199,4170,1.90,4.00,3.00,4.10 4200,4259,4230,1.90,4.00,3.20,4.10 4260,4319,4290,1.80,4.00,2.90,4.10 4320,4379,4350,2.00,4.00,2.90,4.10 4380,4439,4410,2.60,4.00,3.50,4.10 4440,4499,4470,2.30,4.00,4.30,4.10 4500,4559,4530,3.00,4.10,4.20,4.10 4560,4619,4590,2.50,4.00,3.50,4.10 4620,4679,4650,3.00,4.10,2.20,4.00 4680,4739,4710,3.00,4.10,2.00,4.00 4740,4799,4770,2.80,4.00,2.20,4.00 4800,4859,4830,2.40,4.00,4.00,4.10 4860,4919,4890,2.10,4.00,5.70,4.20 4920,4979,4950,2.60,4.00,7.40,4.30 4980,5039,5010,2.40,4.00,7.10,4.30 5040,5099,5070,1.50,4.00,5.50,4.20 5100,5159,5130,1.40,4.00,4.40,4.10 5160,5219,5190,1.30,4.00,4.10,4.10 5220,5279,5250,1.70,4.00,5.10,4.20 5280,5339,5310,1.60,4.00,4.80,4.10 5340,5399,5370,1.90,4.00,3.90,4.10 5400,5459,5430,2.00,4.00,4.40,4.10 5460,5519,5490,1.60,4.00,4.30,4.10 5520,5579,5550,1.60,4.00,5.80,4.20 5580,5639,5610,0.80,4.00,4.50,4.10 5640,5699,5670,0.90,4.00,4.30,4.10 5700,5759,5730,0.60,4.00,3.10,4.10 5760,5819,5790,1.10,4.00,3.70,4.10 5820,5879,5850,0.80,4.00,4.20,4.10 5880,5939,5910,0.30,4.00,3.30,4.10 5940,5999,5970,0.50,4.00,3.50,4.10 6000,6059,6030,0.00,4.00,2.30,4.00 6060,6119,6090,0.90,4.00,3.70,4.10 6120,6179,6150,0.60,4.00,4.80,4.10 6180,6239,6210,1.50,4.00,6.70,4.30 6240,6299,6270,1.40,4.00,6.10,4.20 6300,6359,6330,1.70,4.00,4.00,4.10 6360,6419,6390,2.30,4.00,4.00,4.10 6420,6479,6450,1.80,4.00,4.80,4.10 6480,6539,6510,1.40,4.00,5.90,4.20 6540,6599,6570,0.40,4.00,5.30,4.20 6600,6659,6630,0.30,4.00,4.00,4.10 6660,6719,6690,0.60,4.00,3.40,4.10 6720,6779,6750,1.50,4.00,4.40,4.10 6780,6839,6810,1.70,4.00,4.00,4.10 6840,6899,6870,1.30,4.00,3.40,4.10 6900,6959,6930,0.30,4.00,1.40,4.00 6960,7019,6990,0.70,4.00,1.60,4.00 7020,7079,7050,1.30,4.00,2.80,4.00 7080,7139,7110,2.50,4.00,3.10,4.10 7140,7199,7170,2.20,4.00,4.20,4.10 7200,7259,7230,2.10,4.00,4.40,4.10 7260,7319,7290,1.10,4.00,5.10,4.20 7320,7379,7350,1.30,4.00,4.40,4.10 7380,7439,7410,1.40,4.00,3.10,4.10 7440,7499,7470,1.60,4.00,2.90,4.10 7500,7559,7530,1.90,4.00,3.00,4.10 7560,7619,7590,2.30,4.00,3.50,4.10 7620,7679,7650,2.00,4.00,4.20,4.10 7680,7739,7710,1.20,4.00,6.10,4.20 7740,7799,7770,0.50,4.00,5.60,4.20 7800,7859,7830,0.50,4.00,6.50,4.20 7860,7919,7890,0.80,4.00,4.30,4.10 7920,7979,7950,1.20,4.00,5.90,4.20 7980,8039,8010,0.70,4.00,3.10,4.10 8040,8099,8070,0.80,4.00,4.80,4.10 8100,8159,8130,0.70,4.00,4.10,4.10 8160,8219,8190,2.00,4.00,6.70,4.30 8220,8279,8250,1.80,4.00,5.80,4.20 8280,8339,8310,1.50,4.00,3.60,4.10 8340,8399,8370,1.30,4.00,2.80,4.00 8400,8459,8430,1.60,4.00,2.00,4.00 8460,8519,8490,1.60,4.00,3.10,4.10 8520,8579,8550,2.50,4.00,3.30,4.10 8580,8639,8610,2.90,4.10,4.10,4.10 8640,8699,8670,2.40,4.00,6.20,4.20 8700,8759,8730,1.40,4.00,6.00,4.20 8760,8819,8790,0.20,4.00,5.40,4.20 8820,8879,8850,0.20,4.00,3.90,4.10 8880,8939,8910,-0.40,4.00,4.00,4.10 8940,8999,8970,0.70,4.00,4.60,4.10 9000,9059,9030,1.60,4.00,4.90,4.10 9060,9119,9090,1.40,4.00,5.00,4.10 9120,9179,9150,1.00,4.00,4.90,4.10 9180,9239,9210,1.00,4.00,4.60,4.10 9240,9299,9270,1.90,4.00,5.40,4.20 9300,9359,9330,2.40,4.00,5.10,4.20 9360,9419,9390,2.00,4.00,4.90,4.10 9420,9479,9450,2.00,4.00,4.20,4.10 9480,9539,9510,2.50,4.00,3.40,4.10 9540,9599,9570,3.20,4.10,4.20,4.10 9600,9659,9630,2.80,4.00,2.80,4.00 9660,9719,9690,1.70,4.00,3.40,4.10 9720,9779,9750,1.00,4.00,3.60,4.10 9780,9839,9810,0.90,4.00,4.30,4.10 9840,9899,9870,1.20,4.00,3.60,4.10 9900,9959,9930,1.60,4.00,3.60,4.10 9960,10019,9990,2.60,4.00,5.40,4.20 10020,10079,10050,3.00,4.10,6.90,4.30 10080,10139,10110,3.00,4.10,5.20,4.20 10140,10199,10170,2.20,4.00,2.80,4.00 10200,10259,10230,1.80,4.00,1.60,4.00 10260,10319,10290,1.70,4.00,2.40,4.00 10320,10379,10350,1.40,4.00,2.60,4.00 10380,10439,10410,1.20,4.00,3.30,4.10 10440,10499,10470,1.20,4.00,2.90,4.10 10500,10559,10530,2.80,4.00,4.40,4.10 10560,10619,10590,2.20,4.00,4.00,4.10 10620,10679,10650,0.70,4.00,3.50,4.10 10680,10739,10710,0.00,4.00,2.50,4.00 10740,10799,10770,0.70,4.00,3.00,4.10 10800,10859,10830,1.30,4.00,2.90,4.00 10860,10919,10890,1.60,4.00,2.40,4.00 10920,10979,10950,1.30,4.00,2.10,4.00 10980,11039,11010,2.10,4.00,3.20,4.10 11040,11099,11070,1.60,4.00,4.00,4.10 11100,11159,11130,1.40,4.00,4.40,4.10 11160,11219,11190,1.40,4.00,4.90,4.10 11220,11279,11250,1.80,4.00,4.80,4.10 11280,11339,11310,2.70,4.00,4.90,4.10 11340,11399,11370,2.10,4.00,3.40,4.10 11400,11459,11430,2.00,4.00,4.60,4.10 11460,11519,11490,1.30,4.00,5.20,4.20 11520,11579,11550,1.00,4.00,7.10,4.30 11580,11639,11610,0.20,4.00,5.00,4.10 11640,11699,11670,0.30,4.00,4.30,4.10 11700,11759,11730,0.10,4.00,3.60,4.10 11760,11819,11790,0.00,4.00,4.30,4.10 11820,11879,11850,1.10,4.00,5.00,4.10 11880,11939,11910,1.40,4.00,4.90,4.10 11940,11999,11970,2.00,4.00,5.30,4.20 12000,12059,12030,1.50,4.00,4.10,4.10 12060,12119,12090,2.10,4.00,4.10,4.10 12120,12179,12150,2.80,4.00,3.70,4.10 12180,12239,12210,2.90,4.00,3.60,4.10 12240,12299,12270,2.60,4.00,2.90,4.10 12300,12359,12330,2.30,4.00,2.20,4.00 12360,12419,12390,2.30,4.00,2.90,4.00 12420,12479,12450,1.90,4.00,3.70,4.10 12480,12539,12510,1.30,4.00,4.90,4.10 12540,12599,12570,0.60,4.00,3.20,4.10 12600,12659,12630,0.60,4.00,2.60,4.00 12660,12719,12690,1.20,4.00,2.40,4.00 12720,12779,12750,2.30,4.00,5.40,4.20 12780,12839,12810,2.20,4.00,5.30,4.20 12840,12899,12870,1.80,4.00,6.20,4.20 12900,12959,12930,1.20,4.00,5.60,4.20 12960,13019,12990,2.30,4.00,5.90,4.20 13020,13079,13050,2.20,4.00,4.30,4.10 13080,13139,13110,1.30,4.00,3.50,4.10 13140,13199,13170,0.40,4.00,3.90,4.10 13200,13259,13230,0.80,4.00,3.20,4.10 13260,13319,13290,1.90,4.00,2.80,4.00 13320,13379,13350,2.10,4.00,1.90,4.00 13380,13439,13410,1.70,4.00,1.70,4.00 13440,13499,13470,1.60,4.00,1.50,4.00 13500,13559,13530,1.60,4.00,1.20,4.00 13560,13619,13590,1.50,4.00,1.90,4.00 13620,13679,13650,1.40,4.00,2.50,4.00 13680,13739,13710,1.00,4.00,2.70,4.00 13740,13799,13770,1.30,4.00,2.00,4.00 13800,13859,13830,1.60,4.00,1.50,4.00 13860,13919,13890,2.00,4.00,3.90,4.10 13920,13979,13950,1.70,4.00,4.10,4.10 13980,14039,14010,1.50,4.00,4.20,4.10 14040,14099,14070,1.80,4.00,2.10,4.00 14100,14159,14130,2.30,4.00,2.20,4.00 14160,14219,14190,1.40,4.00,1.80,4.00 14220,14279,14250,0.60,4.00,2.50,4.00 14280,14339,14310,1.30,4.00,3.70,4.10 14340,14399,14370,2.60,4.00,5.20,4.20 14400,14459,14430,3.10,4.10,5.00,4.20 14460,14519,14490,2.10,4.00,4.10,4.10 14520,14579,14550,1.20,4.00,3.30,4.10 14580,14639,14610,0.20,4.00,2.20,4.00 14640,14699,14670,0.40,4.00,2.60,4.00 14700,14759,14730,1.50,4.00,3.50,4.10 14760,14819,14790,2.30,4.00,5.10,4.20 14820,14879,14850,1.60,4.00,4.70,4.10 14880,14939,14910,1.10,4.00,5.00,4.10 14940,14999,14970,1.50,4.00,4.40,4.10 15000,15059,15030,1.80,4.00,5.40,4.20 15060,15119,15090,1.60,4.00,4.70,4.10 15120,15179,15150,1.60,4.00,4.50,4.10 15180,15239,15210,2.20,4.00,3.00,4.10 15240,15299,15270,2.00,4.00,3.40,4.10 15300,15359,15330,2.10,4.00,4.10,4.10 15360,15419,15390,1.20,4.00,4.40,4.10 15420,15479,15450,1.00,4.00,2.90,4.00 15480,15539,15510,0.60,4.00,2.10,4.00 15540,15599,15570,1.10,4.00,2.60,4.00 15600,15659,15630,2.50,4.00,4.60,4.10 15660,15719,15690,2.00,4.00,4.70,4.10 15720,15779,15750,2.40,4.00,5.60,4.20 15780,15839,15810,1.30,4.00,5.50,4.20 15840,15899,15870,0.80,4.00,4.70,4.10 15900,15959,15930,0.40,4.00,5.20,4.20 15960,16019,15990,0.50,4.00,4.70,4.10 16020,16079,16050,2.30,4.00,5.40,4.20 16080,16139,16110,2.70,4.00,3.90,4.10 16140,16199,16170,3.80,4.10,4.30,4.10 16200,16259,16230,2.90,4.00,6.20,4.20 16260,16319,16290,1.90,4.00,6.10,4.20 16320,16379,16350,0.70,4.00,6.50,4.30 16380,16439,16410,0.30,4.00,4.60,4.10 16440,16499,16470,0.70,4.00,5.70,4.20 16500,16559,16530,1.10,4.00,6.50,4.30 16560,16619,16590,1.40,4.00,7.20,4.30 16620,16679,16650,2.10,4.00,4.80,4.10 16680,16739,16710,1.40,4.00,1.60,4.00 16740,16799,16770,1.90,4.00,1.30,4.00 16800,16859,16830,1.80,4.00,3.80,4.10 16860,16919,16890,1.70,4.00,5.10,4.20 16920,16979,16950,0.80,4.00,5.10,4.20 16980,17039,17010,0.70,4.00,4.80,4.10 17040,17099,17070,0.80,4.00,3.90,4.10 17100,17159,17130,1.70,4.00,5.20,4.20 17160,17219,17190,1.50,4.00,4.90,4.10 17220,17279,17250,2.50,4.00,5.00,4.10 17280,17339,17310,2.30,4.00,3.10,4.10 17340,17399,17370,2.80,4.00,2.60,4.00 17400,17459,17430,2.60,4.00,2.90,4.10 17460,17519,17490,2.70,4.00,3.80,4.10 17520,17579,17550,2.50,4.00,3.90,4.10 17580,17639,17610,2.30,4.00,3.80,4.10 17640,17699,17670,2.20,4.00,3.20,4.10 17700,17759,17730,1.80,4.00,1.80,4.00 17760,17819,17790,1.20,4.00,1.20,4.00 17820,17879,17850,0.70,4.00,1.60,4.00 17880,17939,17910,0.80,4.00,2.80,4.00 17940,17999,17970,0.90,4.00,2.80,4.00 18000,18059,18030,1.20,4.00,2.30,4.00 18060,18119,18090,1.00,4.00,1.50,4.00 18120,18179,18150,1.80,4.00,3.10,4.10 18180,18239,18210,1.80,4.00,2.90,4.10 18240,18299,18270,1.60,4.00,4.00,4.10 18300,18359,18330,1.10,4.00,3.00,4.10 18360,18419,18390,1.70,4.00,4.70,4.10 18420,18479,18450,0.50,4.00,4.90,4.10 18480,18539,18510,-0.20,4.00,4.70,4.10 18540,18599,18570,-0.40,4.00,3.40,4.10 18600,18659,18630,1.80,4.00,3.10,4.10 18660,18719,18690,2.30,4.00,1.50,4.00 18720,18779,18750,1.60,4.00,2.20,4.00 18780,18839,18810,1.10,4.00,1.60,4.00 18840,18899,18870,0.80,4.00,3.20,4.10 18900,18959,18930,0.40,4.00,2.50,4.00 18960,19019,18990,0.40,4.00,1.60,4.00 19020,19079,19050,1.20,4.00,3.20,4.10 19080,19139,19110,2.10,4.00,3.90,4.10 19140,19199,19170,2.00,4.00,4.60,4.10 19200,19259,19230,1.10,4.00,3.50,4.10 19260,19319,19290,0.70,4.00,4.10,4.10 19320,19379,19350,0.30,4.00,3.50,4.10 19380,19439,19410,1.70,4.00,3.50,4.10 19440,19499,19470,1.50,4.00,2.40,4.00 19500,19559,19530,2.10,4.00,4.30,4.10 19560,19619,19590,0.70,4.00,3.40,4.10 19620,19679,19650,1.00,4.00,3.30,4.10 19680,19739,19710,0.60,4.00,2.90,4.00 19740,19799,19770,0.70,4.00,3.70,4.10 19800,19859,19830,0.30,4.00,3.70,4.10 19860,19919,19890,0.80,4.00,3.90,4.10 19920,19979,19950,2.30,4.00,4.90,4.10 19980,20039,20010,3.50,4.10,3.70,4.10 20040,20099,20070,4.10,4.10,4.50,4.10 20100,20159,20130,3.20,4.10,3.10,4.10 20160,20219,20190,2.10,4.00,4.70,4.10 20220,20279,20250,1.30,4.00,4.40,4.10 20280,20339,20310,1.60,4.00,6.50,4.20 20340,20399,20370,1.60,4.00,6.50,4.20 20400,20459,20430,1.40,4.00,5.20,4.20 20460,20519,20490,0.60,4.00,4.00,4.10 20520,20579,20550,0.80,4.00,3.70,4.10 20580,20639,20610,1.10,4.00,4.10,4.10 20640,20699,20670,1.80,4.00,3.00,4.10 20700,20759,20730,2.60,4.00,3.20,4.10 20760,20819,20790,1.90,4.00,2.70,4.00 20820,20879,20850,1.40,4.00,2.40,4.00 20880,20939,20910,1.20,4.00,1.70,4.00 20940,20999,20970,2.60,4.00,2.50,4.00 21000,21059,21030,3.50,4.10,3.30,4.10 21060,21119,21090,4.00,4.10,4.50,4.10 21120,21179,21150,3.10,4.10,6.10,4.20 21180,21239,21210,3.10,4.10,6.50,4.20 21240,21299,21270,2.30,4.00,7.20,4.30 21300,21359,21330,2.70,4.00,6.00,4.20 21360,21419,21390,1.70,4.00,5.30,4.20 21420,21479,21450,1.70,4.00,3.10,4.10 21480,21539,21510,1.10,4.00,2.40,4.00 21540,21599,21570,0.50,4.00,2.70,4.00 21600,21659,21630,-0.30,4.00,3.90,4.10 21660,21719,21690,0.30,4.00,4.00,4.10 21720,21779,21750,1.10,4.00,4.10,4.10 21780,21839,21810,1.60,4.00,3.60,4.10 21840,21899,21870,0.90,4.00,3.90,4.10 21900,21959,21930,0.40,4.00,3.30,4.10 21960,22019,21990,0.50,4.00,4.30,4.10 22020,22079,22050,0.50,4.00,4.60,4.10 22080,22139,22110,0.50,4.00,4.90,4.10 22140,22199,22170,0.20,4.00,3.20,4.10 22200,22259,22230,0.20,4.00,1.30,4.00 22260,22319,22290,0.80,4.00,1.00,4.00 22320,22379,22350,2.00,4.00,3.60,4.10 22380,22439,22410,2.40,4.00,5.40,4.20 22440,22499,22470,2.50,4.00,6.70,4.30 22500,22559,22530,1.10,4.00,2.80,4.00 22560,22619,22590,0.50,4.00,2.20,4.00 22620,22679,22650,0.00,4.00,0.80,4.00 22680,22739,22710,0.50,4.00,1.80,4.00 22740,22799,22770,1.50,4.00,2.70,4.00 22800,22859,22830,1.80,4.00,2.40,4.00 22860,22919,22890,2.70,4.00,3.40,4.10 22920,22979,22950,1.90,4.00,2.10,4.00 22980,23039,23010,2.00,4.00,3.70,4.10 23040,23099,23070,0.70,4.00,3.10,4.10 23100,23159,23130,0.80,4.00,3.50,4.10 23160,23219,23190,0.60,4.00,3.10,4.10 23220,23279,23250,0.30,4.00,2.70,4.00 23280,23339,23310,0.30,4.00,1.70,4.00 23340,23399,23370,0.60,4.00,0.90,4.00 23400,23459,23430,1.20,4.00,1.70,4.00 23460,23519,23490,1.00,4.00,3.00,4.10 23520,23579,23550,0.60,4.00,3.10,4.10 23580,23639,23610,0.80,4.00,2.90,4.10 23640,23699,23670,0.50,4.00,2.00,4.00 23700,23759,23730,0.60,4.00,1.60,4.00 23760,23819,23790,0.50,4.00,1.90,4.00 23820,23879,23850,0.90,4.00,3.30,4.10 23880,23939,23910,0.70,4.00,3.90,4.10 23940,23999,23970,1.20,4.00,4.70,4.10 24000,24059,24030,1.70,4.00,5.20,4.20 24060,24119,24090,1.90,4.00,8.20,4.40 24120,24179,24150,0.90,4.00,9.50,4.50 24180,24239,24210,0.50,4.00,8.40,4.40 24240,24299,24270,0.80,4.00,6.80,4.30 24300,24359,24330,1.80,4.00,5.80,4.20 24360,24419,24390,1.40,4.00,7.00,4.30 24420,24479,24450,1.50,4.00,6.30,4.20 24480,24539,24510,1.50,4.00,5.10,4.20 24540,24599,24570,2.60,4.00,6.70,4.30 24600,24659,24630,2.10,4.00,6.00,4.20 24660,24719,24690,1.20,4.00,7.80,4.40 24720,24779,24750,0.40,4.00,7.50,4.30 24780,24839,24810,0.70,4.00,10.20,4.60 24840,24899,24870,0.80,4.00,12.60,4.90 24900,24959,24930,0.70,4.00,10.50,4.60 24960,25019,24990,2.00,4.00,11.00,4.70 25020,25079,25050,2.00,4.00,8.80,4.40 25080,25139,25110,2.00,4.00,10.30,4.60 25140,25199,25170,0.90,4.00,8.40,4.40 25200,25259,25230,1.30,4.00,6.70,4.30 25260,25319,25290,2.00,4.00,6.40,4.20 25320,25379,25350,1.40,4.00,6.80,4.30 25380,25439,25410,2.10,4.00,7.10,4.30 25440,25499,25470,2.80,4.00,6.50,4.20 25500,25559,25530,2.60,4.00,5.70,4.20 25560,25619,25590,1.70,4.00,6.30,4.20 25620,25679,25650,0.40,4.00,5.90,4.20 25680,25739,25710,1.30,4.00,6.00,4.20 25740,25799,25770,2.30,4.00,8.30,4.40 25800,25859,25830,2.30,4.00,9.30,4.50 25860,25919,25890,1.30,4.00,8.70,4.40 25920,25979,25950,0.40,4.00,7.10,4.30 25980,26039,26010,1.40,4.00,6.60,4.30 26040,26099,26070,2.20,4.00,7.60,4.30 26100,26159,26130,2.20,4.00,6.90,4.30 26160,26219,26190,1.50,4.00,6.50,4.20 26220,26279,26250,1.20,4.00,6.10,4.20 26280,26339,26310,1.70,4.00,6.30,4.20 26340,26399,26370,3.80,4.10,9.10,4.50 26400,26459,26430,3.50,4.10,8.30,4.40 26460,26519,26490,3.50,4.10,8.90,4.50 26520,26579,26550,1.00,4.00,8.90,4.50 26580,26639,26610,1.40,4.00,9.60,4.50 26640,26699,26670,0.90,4.00,8.30,4.40 26700,26759,26730,0.80,4.00,5.40,4.20 26760,26819,26790,-0.40,4.00,6.00,4.20 26820,26879,26850,-0.80,4.00,6.90,4.30 26880,26939,26910,-0.80,4.00,7.80,4.40 26940,26999,26970,0.40,4.00,7.90,4.40 27000,27059,27030,1.20,4.00,7.50,4.30 27060,27119,27090,2.50,4.00,7.10,4.30 27120,27179,27150,3.40,4.10,9.00,4.50 27180,27239,27210,2.60,4.00,9.40,4.50 27240,27299,27270,2.30,4.00,10.70,4.60 27300,27359,27330,2.30,4.00,8.40,4.40 27360,27419,27390,2.50,4.00,8.00,4.40 27420,27479,27450,2.20,4.00,7.50,4.30 27480,27539,27510,1.30,4.00,8.10,4.40 27540,27599,27570,0.80,4.00,7.30,4.30 27600,27659,27630,1.20,4.00,7.90,4.40 27660,27719,27690,2.60,4.00,7.70,4.30 27720,27779,27750,4.00,4.10,12.00,4.80 27780,27839,27810,4.40,4.10,11.20,4.70 27840,27899,27870,3.50,4.10,11.60,4.70 27900,27959,27930,3.70,4.10,9.00,4.50 27960,28019,27990,3.60,4.10,10.40,4.60 28020,28079,28050,4.00,4.10,9.80,4.50 28080,28139,28110,3.70,4.10,8.80,4.40 28140,28199,28170,3.20,4.10,6.40,4.20 28200,28259,28230,3.40,4.10,7.30,4.30 28260,28319,28290,3.40,4.10,9.80,4.50 28320,28379,28350,3.30,4.10,12.80,4.90 28380,28439,28410,2.40,4.00,13.10,4.90 28440,28499,28470,2.50,4.00,12.40,4.80 28500,28559,28530,3.60,4.10,12.90,4.90 28560,28619,28590,4.40,4.10,15.90,5.30 28620,28679,28650,3.90,4.10,19.30,5.80 28680,28739,28710,3.30,4.10,20.20,6.00 28740,28799,28770,2.30,4.00,18.20,5.70 28800,28859,28830,2.40,4.00,15.10,5.20 28860,28919,28890,2.30,4.00,13.30,5.00 28920,28979,28950,3.90,4.10,13.20,4.90 28980,29039,29010,5.30,4.20,13.50,5.00 29040,29099,29070,5.50,4.20,15.50,5.30 29100,29159,29130,6.20,4.20,15.90,5.30 29160,29219,29190,5.00,4.10,14.30,5.10 29220,29279,29250,6.50,4.30,10.80,4.70 29280,29339,29310,7.10,4.30,11.80,4.80 29340,29399,29370,7.50,4.30,14.70,5.10 29400,29459,29430,4.90,4.10,15.20,5.20 29460,29519,29490,3.80,4.10,17.40,5.50 29520,29579,29550,4.30,4.10,18.00,5.60 29580,29639,29610,6.60,4.30,19.20,5.80 29640,29699,29670,6.40,4.20,17.30,5.50 29700,29759,29730,7.10,4.30,16.50,5.40 29760,29819,29790,5.70,4.20,16.20,5.40 29820,29879,29850,6.10,4.20,17.20,5.50 29880,29939,29910,4.90,4.10,17.30,5.50 29940,29999,29970,4.90,4.10,20.40,6.00 30000,30059,30030,5.30,4.20,18.80,5.80 30060,30119,30090,6.60,4.30,20.20,6.00 30120,30179,30150,8.30,4.40,22.10,6.30 30180,30239,30210,8.50,4.40,24.50,6.70 30240,30299,30270,8.10,4.40,23.80,6.60 30300,30359,30330,7.40,4.30,20.90,6.10 30360,30419,30390,6.70,4.30,19.50,5.90 30420,30479,30450,5.70,4.20,19.70,5.90 30480,30539,30510,6.10,4.20,21.40,6.20 30540,30599,30570,6.50,4.20,20.80,6.10 30600,30659,30630,8.90,4.50,25.00,6.80 30660,30719,30690,7.70,4.30,23.40,6.50 30720,30779,30750,8.10,4.40,24.00,6.60 30780,30839,30810,6.40,4.20,20.80,6.10 30840,30899,30870,7.90,4.40,22.30,6.30 30900,30959,30930,8.30,4.40,23.60,6.50 30960,31019,30990,8.60,4.40,26.20,7.00 31020,31079,31050,10.00,4.60,24.50,6.70 31080,31139,31110,11.10,4.70,27.10,7.20 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81600,81659,81630,5.50,4.20,14.60,5.10 81660,81719,81690,5.50,4.20,15.10,5.20 81720,81779,81750,7.70,4.30,15.50,5.30 81780,81839,81810,9.60,4.50,19.00,5.80 81840,81899,81870,7.80,4.40,21.60,6.20 81900,81959,81930,5.70,4.20,23.50,6.50 81960,82019,81990,3.80,4.10,20.50,6.00 82020,82079,82050,4.90,4.10,16.90,5.50 82080,82139,82110,5.50,4.20,14.50,5.10 82140,82199,82170,5.90,4.20,11.80,4.80 82200,82259,82230,6.00,4.20,12.50,4.90 82260,82319,82290,6.00,4.20,13.40,5.00 82320,82379,82350,5.50,4.20,15.10,5.20 82380,82439,82410,5.00,4.20,15.20,5.20 82440,82499,82470,4.20,4.10,14.30,5.10 82500,82559,82530,4.40,4.10,16.10,5.30 82560,82619,82590,5.40,4.20,16.70,5.40 82620,82679,82650,6.90,4.30,19.00,5.80 82680,82739,82710,8.30,4.40,20.30,6.00 82740,82799,82770,8.80,4.40,21.10,6.10 82800,82859,82830,8.50,4.40,22.10,6.30 82860,82919,82890,7.60,4.30,21.80,6.20 82920,82979,82950,6.80,4.30,20.90,6.10 82980,83039,83010,6.00,4.20,20.30,6.00 83040,83099,83070,5.30,4.20,18.50,5.70 83100,83159,83130,5.70,4.20,18.00,5.60 83160,83219,83190,9.30,4.50,18.70,5.70 83220,83279,83250,10.00,4.60,20.50,6.00 83280,83339,83310,10.00,4.60,20.90,6.10 83340,83399,83370,6.90,4.30,18.80,5.80 83400,83459,83430,5.90,4.20,18.40,5.70 83460,83519,83490,4.50,4.10,17.60,5.60 83520,83579,83550,3.40,4.10,18.90,5.80 83580,83639,83610,3.50,4.10,16.60,5.40 83640,83699,83670,5.30,4.20,16.60,5.40 83700,83759,83730,5.90,4.20,14.40,5.10 83760,83819,83790,6.20,4.20,15.40,5.20 83820,83879,83850,4.50,4.10,16.00,5.30 83880,83939,83910,3.10,4.10,14.70,5.10 83940,83999,83970,3.40,4.10,13.20,4.90 84000,84059,84030,4.40,4.10,12.30,4.80 84060,84119,84090,6.40,4.20,14.10,5.10 84120,84179,84150,4.70,4.10,13.30,5.00 84180,84239,84210,3.30,4.10,12.50,4.90 84240,84299,84270,2.20,4.00,12.30,4.80 84300,84359,84330,4.10,4.10,14.90,5.20 84360,84419,84390,5.10,4.20,17.50,5.50 84420,84479,84450,4.80,4.10,18.30,5.70 84480,84539,84510,6.60,4.30,19.70,5.90 84540,84599,84570,6.70,4.30,15.50,5.30 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