49, 1001 Cantrell, Christopher A Atmospheric Chemistry Division/NESL/NCAR HO2 and HO2+RO2 from PeRCIMS at Manitou Experimental Forest BEACHON-RoMBAS 1,1 2011, 08, 14, 2011, 11, 24 0 Start_MST, seconds, number_of_seconds_from_0000_MST 6 1,1,1,1,1,1 -99999,-99999,-99999,-99999,-99999,-99999 Stop_MST, seconds, number_of_seconds_from_0000_MST Mid_MST, seconds, number_of_seconds_from_0000_MST HO2, pptv, HO2_mixing_ratio HO2_uncertainty, pptv, HO2_2_sigma_uncertainty HO2+RO2, pptv, HO2+RO2_mixing_ratio HO2+RO2_uncertainty, pptv, HO2+RO2_2_sigma_uncertainty 5 These data are reduced using four factors determined in the laboratory and in the field: F_lo and F_hi are the radical sensitivities in the HO2+RO2 and HO2 modes, respectively (units pptv/ion ratio). Alpha_lo and alpha_hi are the ratios of RO2 to HO2 sensitivity in the HO2+RO2 and HO2 modes, respectively. HO2+RO2 concentrations are then S_lo*F_lo-(S_lo*F_lo - S_hi*F_hi)*(alpha_lo - 1)/(alpha_lo - alpha_hi) . HO2 concentrations are S_lo*F_lo-(S_lo*F_lo - S_hi*F_hi)*(alpha_lo)/(alpha_lo - alpha_hi) . S_lo is the background corrected ion ratio in the HO2+RO2 mode, and S_hi is the background corrected ion ratio in the HO2 mode. The ion ratios are mass 97 signal count rate minus background count rate divided by mass 62 count rate. 24 PI_CONTACT_INFO: 303-497-1479, NCAR, 3090 Center Green Dr., Boulder, CO 80301, cantrell@ucar.edu PLATFORM: Seacontainer #1 LOCATION: Manitou Experimental Forest, Woodland Park, Colorado, USA ASSOCIATED_DATA: N/A INSTRUMENT_INFO: These data were collected using a CIMS based instrument. An inlet collects ambient air from the free air stream and adds reagents, includling O2 or N2 diluents, and NO and SO2 reagent gases. This method, called oxygen dilution modulation leads to nearly 100% measurement of HO2 and RO2 in the O2 dilution/low reagent concentration mode, whereas RO2 is measured with less than 15% efficiency in the N2 dilution/higher reagent concentration mode. This is because the chemistry converts peroxy radicals to H2SO4 efficiently in the O2 mode, but RO2 radicals are converted to RONO in the N2 mode. The H2SO4 thus produced is ionized by reaction with NO3- ions. The reagent and product ions are detected by mass spectrometry using quadrupole mass filtering and counting by a channel electron multiplier operating in the negative ion mode. DATA_INFO: Signal data for HO2+RO2 are collected during the 0-7 second time interval, and for HO2 in 30-37 second time interval. UNCERTAINTY: approximately 35% (2 sigma) for values well above 2 pptv; estimates are listed for each data point (2 sigma) ULOD_FLAG: -7777 ULOD_VALUE: N/A LLOD_FLAG: -8888 LLOD_VALUE: N/A DM_CONTACT_INFO: N/A PROJECT_INFO: BEACHON-RoMBAS, 20-Jul-2011 to 30-Aug-2011 STIPULATIONS_ON_USE: contact PI BEFORE use/presentation/publication OTHER_COMMENTS: REVISION: R1; R0 R1: final data R0: preliminary data Start_MST,Stop_MST,Mid_MST,HO2,HO2_uncertainty,HO2+RO2,HO2+RO2_uncertainty 0,59,30,3.80,4.10,14.60,5.10 60,119,90,4.20,4.10,13.80,5.00 120,179,150,4.90,4.10,12.70,4.90 180,239,210,4.80,4.10,11.70,4.80 240,299,270,4.10,4.10,12.70,4.90 300,359,330,3.80,4.10,13.10,4.90 360,419,390,3.40,4.10,12.70,4.90 420,479,450,4.90,4.10,13.40,5.00 480,539,510,4.90,4.10,15.20,5.20 540,599,570,5.40,4.20,16.10,5.30 600,659,630,4.60,4.10,15.70,5.30 660,719,690,4.60,4.10,14.90,5.20 720,779,750,4.90,4.10,15.10,5.20 780,839,810,4.90,4.10,13.50,5.00 840,899,870,4.90,4.10,13.20,4.90 900,959,930,4.80,4.10,12.70,4.90 960,1019,990,4.80,4.10,13.40,5.00 1020,1079,1050,4.20,4.10,12.90,4.90 1080,1139,1110,5.20,4.20,15.30,5.20 1140,1199,1170,4.80,4.10,16.40,5.40 1200,1259,1230,5.70,4.20,16.50,5.40 1260,1319,1290,4.50,4.10,14.20,5.10 1320,1379,1350,5.70,4.20,13.30,5.00 1380,1439,1410,5.70,4.20,14.00,5.00 1440,1499,1470,5.50,4.20,13.00,4.90 1500,1559,1530,5.40,4.20,12.70,4.90 1560,1619,1590,5.40,4.20,11.60,4.80 1620,1679,1650,6.40,4.20,12.90,4.90 1680,1739,1710,6.40,4.20,14.00,5.10 1740,1799,1770,6.10,4.20,14.10,5.10 1800,1859,1830,5.90,4.20,14.00,5.10 1860,1919,1890,6.00,4.20,12.70,4.90 1920,1979,1950,6.30,4.20,12.40,4.80 1980,2039,2010,5.90,4.20,12.00,4.80 2040,2099,2070,4.50,4.10,11.00,4.70 2100,2159,2130,4.60,4.10,11.90,4.80 2160,2219,2190,4.60,4.10,10.90,4.70 2220,2279,2250,4.80,4.10,11.00,4.70 2280,2339,2310,4.40,4.10,11.20,4.70 2340,2399,2370,4.50,4.10,12.50,4.90 2400,2459,2430,4.80,4.10,12.40,4.80 2460,2519,2490,4.80,4.10,12.90,4.90 2520,2579,2550,4.30,4.10,12.70,4.90 2580,2639,2610,3.90,4.10,13.20,4.90 2640,2699,2670,3.20,4.10,11.10,4.70 2700,2759,2730,3.90,4.10,12.20,4.80 2760,2819,2790,4.10,4.10,13.50,5.00 2820,2879,2850,4.70,4.10,13.60,5.00 2880,2939,2910,4.10,4.10,12.00,4.80 2940,2999,2970,3.90,4.10,10.30,4.60 3000,3059,3030,3.60,4.10,11.00,4.70 3060,3119,3090,3.50,4.10,11.60,4.70 3120,3179,3150,3.90,4.10,12.60,4.90 3180,3239,3210,4.10,4.10,11.20,4.70 3240,3299,3270,3.70,4.10,10.10,4.60 3300,3359,3330,3.50,4.10,10.00,4.60 3360,3419,3390,3.00,4.10,11.90,4.80 3420,3479,3450,3.70,4.10,12.80,4.90 3480,3539,3510,4.00,4.10,12.90,4.90 3540,3599,3570,4.60,4.10,12.40,4.80 3600,3659,3630,4.60,4.10,13.00,4.90 3660,3719,3690,3.80,4.10,12.50,4.90 3720,3779,3750,3.10,4.10,12.20,4.80 3780,3839,3810,2.60,4.00,12.00,4.80 3840,3899,3870,2.90,4.10,12.00,4.80 3900,3959,3930,3.00,4.10,11.70,4.80 3960,4019,3990,3.70,4.10,11.10,4.70 4020,4079,4050,3.70,4.10,11.70,4.80 4080,4139,4110,3.60,4.10,12.50,4.90 4140,4199,4170,3.00,4.10,12.90,4.90 4200,4259,4230,3.20,4.10,13.00,4.90 4260,4319,4290,3.50,4.10,11.10,4.70 4320,4379,4350,4.10,4.10,12.30,4.80 4380,4439,4410,4.10,4.10,11.80,4.80 4440,4499,4470,4.00,4.10,12.90,4.90 4500,4559,4530,4.10,4.10,11.60,4.70 4560,4619,4590,3.90,4.10,11.70,4.80 4620,4679,4650,4.40,4.10,11.90,4.80 4680,4739,4710,3.90,4.10,12.40,4.80 4740,4799,4770,4.20,4.10,12.30,4.80 4800,4859,4830,4.10,4.10,12.30,4.80 4860,4919,4890,4.30,4.10,11.30,4.70 4920,4979,4950,4.00,4.10,11.00,4.70 4980,5039,5010,3.60,4.10,10.20,4.60 5040,5099,5070,3.40,4.10,9.90,4.60 5100,5159,5130,4.00,4.10,9.80,4.50 5160,5219,5190,4.20,4.10,10.50,4.60 5220,5279,5250,3.70,4.10,10.90,4.70 5280,5339,5310,3.40,4.10,10.10,4.60 5340,5399,5370,4.30,4.10,9.50,4.50 5400,5459,5430,5.60,4.20,10.00,4.60 5460,5519,5490,5.90,4.20,11.70,4.80 5520,5579,5550,5.40,4.20,12.10,4.80 5580,5639,5610,4.80,4.10,12.20,4.80 5640,5699,5670,4.40,4.10,11.70,4.80 5700,5759,5730,3.80,4.10,11.50,4.70 5760,5819,5790,4.10,4.10,11.00,4.70 5820,5879,5850,4.40,4.10,10.80,4.60 5880,5939,5910,4.70,4.10,10.70,4.60 5940,5999,5970,5.00,4.20,12.00,4.80 6000,6059,6030,4.40,4.10,10.80,4.60 6060,6119,6090,4.20,4.10,9.50,4.50 6120,6179,6150,3.20,4.10,8.60,4.40 6180,6239,6210,3.30,4.10,9.90,4.60 6240,6299,6270,3.10,4.10,11.30,4.70 6300,6359,6330,3.00,4.10,10.80,4.60 6360,6419,6390,3.00,4.10,9.50,4.50 6420,6479,6450,3.90,4.10,8.10,4.40 6480,6539,6510,4.90,4.10,8.80,4.40 6540,6599,6570,4.70,4.10,9.10,4.50 6600,6659,6630,4.00,4.10,9.80,4.50 6660,6719,6690,3.10,4.10,9.00,4.50 6720,6779,6750,2.90,4.10,9.50,4.50 6780,6839,6810,2.60,4.00,8.90,4.50 6840,6899,6870,2.50,4.00,8.30,4.40 6900,6959,6930,2.60,4.00,8.40,4.40 6960,7019,6990,2.50,4.00,9.10,4.50 7020,7079,7050,3.10,4.10,10.80,4.60 7080,7139,7110,2.60,4.00,9.60,4.50 7140,7199,7170,3.20,4.10,10.60,4.60 7200,7259,7230,3.00,4.10,9.70,4.50 7260,7319,7290,2.40,4.00,11.00,4.70 7320,7379,7350,2.40,4.00,10.40,4.60 7380,7439,7410,2.00,4.00,9.90,4.60 7440,7499,7470,2.60,4.00,7.30,4.30 7500,7559,7530,2.70,4.00,7.20,4.30 7560,7619,7590,2.50,4.00,6.10,4.20 7620,7679,7650,3.30,4.10,8.70,4.40 7680,7739,7710,2.80,4.00,8.00,4.40 7740,7799,7770,2.90,4.00,9.00,4.50 7800,7859,7830,2.50,4.00,8.70,4.40 7860,7919,7890,3.10,4.10,10.90,4.70 7920,7979,7950,4.10,4.10,11.60,4.70 7980,8039,8010,4.90,4.10,12.50,4.90 8040,8099,8070,4.90,4.10,11.60,4.70 8100,8159,8130,4.50,4.10,11.70,4.80 8160,8219,8190,4.30,4.10,11.00,4.70 8220,8279,8250,4.30,4.10,10.90,4.70 8280,8339,8310,4.10,4.10,11.20,4.70 8340,8399,8370,3.70,4.10,11.90,4.80 8400,8459,8430,3.30,4.10,12.60,4.90 8460,8519,8490,3.30,4.10,11.30,4.70 8520,8579,8550,3.60,4.10,10.80,4.70 8580,8639,8610,4.40,4.10,9.90,4.60 8640,8699,8670,4.70,4.10,10.30,4.60 8700,8759,8730,5.10,4.20,10.70,4.60 8760,8819,8790,5.10,4.20,11.20,4.70 8820,8879,8850,5.60,4.20,12.10,4.80 8880,8939,8910,5.40,4.20,11.70,4.80 8940,8999,8970,4.90,4.10,12.80,4.90 9000,9059,9030,4.40,4.10,13.60,5.00 9060,9119,9090,4.80,4.10,14.30,5.10 9120,9179,9150,5.50,4.20,13.30,5.00 9180,9239,9210,5.50,4.20,14.00,5.00 9240,9299,9270,5.20,4.20,12.70,4.90 9300,9359,9330,4.50,4.10,13.00,4.90 9360,9419,9390,4.10,4.10,12.40,4.80 9420,9479,9450,4.10,4.10,12.30,4.80 9480,9539,9510,5.10,4.20,12.00,4.80 9540,9599,9570,5.80,4.20,10.80,4.70 9600,9659,9630,6.40,4.20,13.20,4.90 9660,9719,9690,5.30,4.20,12.30,4.80 9720,9779,9750,5.10,4.20,13.20,4.90 9780,9839,9810,4.90,4.10,10.90,4.70 9840,9899,9870,5.20,4.20,12.20,4.80 9900,9959,9930,4.80,4.10,11.70,4.80 9960,10019,9990,4.20,4.10,11.90,4.80 10020,10079,10050,3.80,4.10,11.70,4.80 10080,10139,10110,3.20,4.10,11.40,4.70 10140,10199,10170,3.80,4.10,11.90,4.80 10200,10259,10230,4.10,4.10,12.70,4.90 10260,10319,10290,4.40,4.10,11.70,4.80 10320,10379,10350,4.30,4.10,11.30,4.70 10380,10439,10410,4.60,4.10,9.00,4.50 10440,10499,10470,6.10,4.20,11.50,4.70 10500,10559,10530,5.60,4.20,10.90,4.70 10560,10619,10590,4.90,4.10,10.30,4.60 10620,10679,10650,4.20,4.10,9.10,4.50 10680,10739,10710,5.10,4.20,9.50,4.50 10740,10799,10770,5.80,4.20,12.10,4.80 10800,10859,10830,5.40,4.20,11.40,4.70 10860,10919,10890,5.00,4.10,12.50,4.80 10920,10979,10950,3.80,4.10,11.10,4.70 10980,11039,11010,3.50,4.10,11.30,4.70 11040,11099,11070,3.60,4.10,10.30,4.60 11100,11159,11130,5.50,4.20,10.80,4.70 11160,11219,11190,7.40,4.30,12.60,4.90 11220,11279,11250,6.20,4.20,13.60,5.00 11280,11339,11310,5.10,4.20,14.00,5.00 11340,11399,11370,3.50,4.10,12.70,4.90 11400,11459,11430,4.80,4.10,13.10,4.90 11460,11519,11490,4.50,4.10,13.30,5.00 11520,11579,11550,3.90,4.10,12.60,4.90 11580,11639,11610,3.70,4.10,12.90,4.90 11640,11699,11670,3.30,4.10,11.70,4.80 11700,11759,11730,3.60,4.10,11.80,4.80 11760,11819,11790,3.60,4.10,10.20,4.60 11820,11879,11850,4.50,4.10,11.60,4.70 11880,11939,11910,4.40,4.10,12.10,4.80 11940,11999,11970,4.00,4.10,11.10,4.70 12000,12059,12030,3.50,4.10,9.90,4.50 12060,12119,12090,3.30,4.10,9.70,4.50 12120,12179,12150,3.10,4.10,11.20,4.70 12180,12239,12210,3.20,4.10,10.90,4.70 12240,12299,12270,4.30,4.10,10.30,4.60 12300,12359,12330,4.20,4.10,8.70,4.40 12360,12419,12390,3.90,4.10,8.50,4.40 12420,12479,12450,2.60,4.00,8.60,4.40 12480,12539,12510,2.90,4.00,8.30,4.40 12540,12599,12570,2.90,4.10,8.90,4.40 12600,12659,12630,3.60,4.10,8.80,4.40 12660,12719,12690,3.70,4.10,9.30,4.50 12720,12779,12750,3.60,4.10,8.30,4.40 12780,12839,12810,4.00,4.10,8.20,4.40 12840,12899,12870,4.40,4.10,8.40,4.40 12900,12959,12930,5.20,4.20,9.20,4.50 12960,13019,12990,4.70,4.10,9.40,4.50 13020,13079,13050,4.20,4.10,9.60,4.50 13080,13139,13110,3.70,4.10,9.90,4.60 13140,13199,13170,3.20,4.10,9.70,4.50 13200,13259,13230,3.80,4.10,9.30,4.50 13260,13319,13290,4.50,4.10,9.30,4.50 13320,13379,13350,4.70,4.10,10.60,4.60 13380,13439,13410,3.50,4.10,10.60,4.60 13440,13499,13470,3.60,4.10,11.60,4.70 13500,13559,13530,3.10,4.10,9.30,4.50 13560,13619,13590,4.00,4.10,10.60,4.60 13620,13679,13650,3.00,4.10,10.30,4.60 13680,13739,13710,3.50,4.10,11.20,4.70 13740,13799,13770,3.40,4.10,9.40,4.50 13800,13859,13830,4.00,4.10,7.30,4.30 13860,13919,13890,4.30,4.10,7.60,4.30 13920,13979,13950,3.90,4.10,7.30,4.30 13980,14039,14010,3.80,4.10,7.80,4.40 14040,14099,14070,3.50,4.10,6.90,4.30 14100,14159,14130,4.00,4.10,8.80,4.40 14160,14219,14190,3.60,4.10,10.10,4.60 14220,14279,14250,3.90,4.10,11.50,4.70 14280,14339,14310,3.90,4.10,11.80,4.80 14340,14399,14370,3.20,4.10,11.00,4.70 14400,14459,14430,2.60,4.00,9.80,4.50 14460,14519,14490,2.20,4.00,7.90,4.40 14520,14579,14550,3.00,4.10,8.70,4.40 14580,14639,14610,2.90,4.00,9.70,4.50 14640,14699,14670,2.80,4.00,9.90,4.60 14700,14759,14730,3.10,4.10,8.30,4.40 14760,14819,14790,4.00,4.10,6.80,4.30 14820,14879,14850,3.70,4.10,7.00,4.30 14880,14939,14910,3.20,4.10,7.90,4.40 14940,14999,14970,2.10,4.00,9.10,4.50 15000,15059,15030,2.30,4.00,9.20,4.50 15060,15119,15090,2.80,4.00,8.90,4.50 15120,15179,15150,4.00,4.10,8.40,4.40 15180,15239,15210,4.10,4.10,9.30,4.50 15240,15299,15270,3.60,4.10,10.40,4.60 15300,15359,15330,3.60,4.10,9.70,4.50 15360,15419,15390,3.80,4.10,8.70,4.40 15420,15479,15450,3.80,4.10,7.50,4.30 15480,15539,15510,3.70,4.10,9.70,4.50 15540,15599,15570,3.10,4.10,10.00,4.60 15600,15659,15630,3.50,4.10,11.30,4.70 15660,15719,15690,2.80,4.00,9.40,4.50 15720,15779,15750,3.00,4.10,10.00,4.60 15780,15839,15810,2.40,4.00,8.20,4.40 15840,15899,15870,2.70,4.00,9.10,4.50 15900,15959,15930,2.90,4.10,8.70,4.40 15960,16019,15990,2.80,4.00,8.20,4.40 16020,16079,16050,2.90,4.10,7.00,4.30 16080,16139,16110,2.70,4.00,7.10,4.30 16140,16199,16170,3.10,4.10,9.20,4.50 16200,16259,16230,3.00,4.10,9.40,4.50 16260,16319,16290,3.10,4.10,9.10,4.50 16320,16379,16350,2.90,4.10,8.40,4.40 16380,16439,16410,2.80,4.00,8.00,4.40 16440,16499,16470,2.30,4.00,5.90,4.20 16500,16559,16530,2.90,4.10,6.90,4.30 16560,16619,16590,3.40,4.10,8.30,4.40 16620,16679,16650,3.70,4.10,11.00,4.70 16680,16739,16710,4.10,4.10,9.20,4.50 16740,16799,16770,4.00,4.10,8.80,4.40 16800,16859,16830,4.30,4.10,8.70,4.40 16860,16919,16890,4.00,4.10,10.00,4.60 16920,16979,16950,3.80,4.10,11.60,4.70 16980,17039,17010,2.60,4.00,10.40,4.60 17040,17099,17070,2.60,4.00,9.90,4.60 17100,17159,17130,2.30,4.00,8.50,4.40 17160,17219,17190,3.90,4.10,9.40,4.50 17220,17279,17250,3.90,4.10,9.70,4.50 17280,17339,17310,4.30,4.10,9.60,4.50 17340,17399,17370,3.50,4.10,8.30,4.40 17400,17459,17430,2.80,4.00,8.00,4.40 17460,17519,17490,3.00,4.10,7.20,4.30 17520,17579,17550,3.10,4.10,8.90,4.50 17580,17639,17610,3.10,4.10,11.10,4.70 17640,17699,17670,3.10,4.10,13.80,5.00 17700,17759,17730,1.80,4.00,12.30,4.80 17760,17819,17790,1.70,4.00,10.80,4.70 17820,17879,17850,1.30,4.00,7.80,4.40 17880,17939,17910,2.40,4.00,7.80,4.40 17940,17999,17970,2.50,4.00,7.50,4.30 18000,18059,18030,2.60,4.00,8.20,4.40 18060,18119,18090,3.10,4.10,8.40,4.40 18120,18179,18150,3.70,4.10,9.00,4.50 18180,18239,18210,3.70,4.10,9.70,4.50 18240,18299,18270,3.90,4.10,10.40,4.60 18300,18359,18330,3.70,4.10,10.30,4.60 18360,18419,18390,3.50,4.10,10.40,4.60 18420,18479,18450,3.00,4.10,11.20,4.70 18480,18539,18510,2.70,4.00,10.60,4.60 18540,18599,18570,2.30,4.00,9.80,4.50 18600,18659,18630,1.70,4.00,8.60,4.40 18660,18719,18690,1.50,4.00,8.30,4.40 18720,18779,18750,1.80,4.00,8.50,4.40 18780,18839,18810,2.70,4.00,8.10,4.40 18840,18899,18870,3.10,4.10,8.50,4.40 18900,18959,18930,3.20,4.10,8.00,4.40 18960,19019,18990,2.70,4.00,7.00,4.30 19020,19079,19050,3.00,4.10,6.40,4.20 19080,19139,19110,2.90,4.10,6.80,4.30 19140,19199,19170,3.70,4.10,9.30,4.50 19200,19259,19230,3.00,4.10,8.90,4.50 19260,19319,19290,2.40,4.00,8.30,4.40 19320,19379,19350,1.80,4.00,8.00,4.40 19380,19439,19410,2.10,4.00,7.40,4.30 19440,19499,19470,3.30,4.10,8.50,4.40 19500,19559,19530,3.40,4.10,7.60,4.30 19560,19619,19590,3.80,4.10,9.20,4.50 19620,19679,19650,3.80,4.10,9.00,4.50 19680,19739,19710,4.30,4.10,9.30,4.50 19740,19799,19770,3.70,4.10,7.90,4.40 19800,19859,19830,3.30,4.10,7.80,4.40 19860,19919,19890,2.90,4.00,8.50,4.40 19920,19979,19950,2.80,4.00,10.40,4.60 19980,20039,20010,3.50,4.10,9.70,4.50 20040,20099,20070,2.80,4.00,9.30,4.50 20100,20159,20130,2.60,4.00,8.00,4.40 20160,20219,20190,2.30,4.00,8.20,4.40 20220,20279,20250,3.50,4.10,8.40,4.40 20280,20339,20310,4.20,4.10,8.70,4.40 20340,20399,20370,3.70,4.10,8.50,4.40 20400,20459,20430,3.10,4.10,8.20,4.40 20460,20519,20490,3.10,4.10,8.50,4.40 20520,20579,20550,3.30,4.10,8.50,4.40 20580,20639,20610,3.70,4.10,8.80,4.40 20640,20699,20670,2.40,4.00,7.90,4.40 20700,20759,20730,1.80,4.00,9.30,4.50 20760,20819,20790,0.80,4.00,9.90,4.60 20820,20879,20850,1.50,4.00,10.20,4.60 20880,20939,20910,1.90,4.00,10.30,4.60 20940,20999,20970,2.30,4.00,10.10,4.60 21000,21059,21030,2.70,4.00,10.10,4.60 21060,21119,21090,2.40,4.00,9.50,4.50 21120,21179,21150,2.40,4.00,8.70,4.40 21180,21239,21210,3.10,4.10,10.70,4.60 21240,21299,21270,2.70,4.00,9.00,4.50 21300,21359,21330,2.40,4.00,8.30,4.40 21360,21419,21390,2.30,4.00,6.20,4.20 21420,21479,21450,3.10,4.10,7.50,4.30 21480,21539,21510,3.80,4.10,7.60,4.30 21540,21599,21570,3.10,4.10,7.40,4.30 21600,21659,21630,3.20,4.10,7.30,4.30 21660,21719,21690,2.80,4.00,8.50,4.40 21720,21779,21750,3.00,4.10,7.80,4.30 21780,21839,21810,2.70,4.00,7.80,4.30 21840,21899,21870,2.30,4.00,7.10,4.30 21900,21959,21930,2.60,4.00,7.70,4.30 21960,22019,21990,3.00,4.10,7.20,4.30 22020,22079,22050,3.00,4.10,7.40,4.30 22080,22139,22110,2.50,4.00,9.30,4.50 22140,22199,22170,2.20,4.00,11.60,4.70 22200,22259,22230,2.20,4.00,11.80,4.80 22260,22319,22290,2.30,4.00,11.90,4.80 22320,22379,22350,2.60,4.00,9.90,4.60 22380,22439,22410,3.10,4.10,8.40,4.40 22440,22499,22470,4.20,4.10,7.40,4.30 22500,22559,22530,4.80,4.10,7.10,4.30 22560,22619,22590,4.30,4.10,7.40,4.30 22620,22679,22650,3.30,4.10,8.50,4.40 22680,22739,22710,3.10,4.10,8.40,4.40 22740,22799,22770,4.00,4.10,9.80,4.50 22800,22859,22830,4.60,4.10,8.40,4.40 22860,22919,22890,4.40,4.10,9.70,4.50 22920,22979,22950,3.40,4.10,9.20,4.50 22980,23039,23010,2.60,4.00,9.10,4.50 23040,23099,23070,2.90,4.10,8.80,4.40 23100,23159,23130,2.10,4.00,10.00,4.60 23160,23219,23190,1.90,4.00,12.00,4.80 23220,23279,23250,1.50,4.00,14.10,5.10 23280,23339,23310,2.40,4.00,15.10,5.20 23340,23399,23370,2.70,4.00,15.00,5.20 23400,23459,23430,2.00,4.00,13.40,5.00 23460,23519,23490,1.40,4.00,11.30,4.70 23520,23579,23550,1.60,4.00,9.80,4.50 23580,23639,23610,2.10,4.00,10.20,4.60 23640,23699,23670,3.60,4.10,10.70,4.60 23700,23759,23730,3.50,4.10,10.60,4.60 23760,23819,23790,2.80,4.00,9.60,4.50 23820,23879,23850,2.00,4.00,9.80,4.50 23880,23939,23910,1.70,4.00,9.50,4.50 23940,23999,23970,2.70,4.00,12.70,4.90 24000,24059,24030,2.70,4.00,12.80,4.90 24060,24119,24090,3.40,4.10,13.60,5.00 24120,24179,24150,3.30,4.10,9.90,4.60 24180,24239,24210,2.80,4.00,9.00,4.50 24240,24299,24270,3.10,4.10,9.40,4.50 24300,24359,24330,2.50,4.00,11.30,4.70 24360,24419,24390,2.60,4.00,12.20,4.80 24420,24479,24450,2.40,4.00,13.30,5.00 24480,24539,24510,2.30,4.00,11.80,4.80 24540,24599,24570,3.10,4.10,12.00,4.80 24600,24659,24630,2.90,4.00,12.20,4.80 24660,24719,24690,4.30,4.10,13.20,4.90 24720,24779,24750,4.90,4.10,13.10,4.90 24780,24839,24810,5.70,4.20,11.90,4.80 24840,24899,24870,5.60,4.20,11.80,4.80 24900,24959,24930,5.00,4.10,12.00,4.80 24960,25019,24990,4.50,4.10,13.30,5.00 25020,25079,25050,4.00,4.10,13.50,5.00 25080,25139,25110,4.40,4.10,14.50,5.10 25140,25199,25170,4.40,4.10,15.90,5.30 25200,25259,25230,4.20,4.10,17.30,5.50 25260,25319,25290,4.80,4.10,15.60,5.30 25320,25379,25350,5.50,4.20,14.00,5.00 25380,25439,25410,6.30,4.20,13.30,5.00 25440,25499,25470,5.90,4.20,14.60,5.10 25500,25559,25530,5.60,4.20,14.10,5.10 25560,25619,25590,4.90,4.10,13.10,4.90 25620,25679,25650,4.40,4.10,14.70,5.10 25680,25739,25710,4.30,4.10,19.20,5.80 25740,25799,25770,4.30,4.10,24.20,6.70 25800,25859,25830,4.40,4.10,22.60,6.40 25860,25919,25890,4.00,4.10,21.00,6.10 25920,25979,25950,5.00,4.20,19.40,5.90 25980,26039,26010,5.10,4.20,19.20,5.80 26040,26099,26070,6.00,4.20,20.20,6.00 26100,26159,26130,5.50,4.20,21.50,6.20 26160,26219,26190,5.50,4.20,25.50,6.90 26220,26279,26250,5.00,4.10,26.20,7.00 26280,26339,26310,4.20,4.10,23.00,6.50 26340,26399,26370,4.40,4.10,24.70,6.70 26400,26459,26430,5.20,4.20,21.80,6.20 26460,26519,26490,6.70,4.30,23.10,6.50 26520,26579,26550,7.40,4.30,19.00,5.80 26580,26639,26610,6.70,4.30,20.20,6.00 26640,26699,26670,6.30,4.20,20.10,6.00 26700,26759,26730,6.10,4.20,19.80,5.90 26760,26819,26790,6.10,4.20,20.10,6.00 26820,26879,26850,5.80,4.20,21.00,6.10 26880,26939,26910,4.80,4.10,20.20,6.00 26940,26999,26970,4.90,4.10,21.30,6.20 27000,27059,27030,5.80,4.20,19.60,5.90 27060,27119,27090,6.40,4.20,24.10,6.60 27120,27179,27150,6.90,4.30,21.20,6.10 27180,27239,27210,6.70,4.30,22.60,6.40 27240,27299,27270,7.30,4.30,18.90,5.80 27300,27359,27330,7.20,4.30,19.40,5.80 27360,27419,27390,7.00,4.30,17.70,5.60 27420,27479,27450,7.00,4.30,18.00,5.60 27480,27539,27510,7.50,4.30,18.00,5.60 27540,27599,27570,7.70,4.30,18.70,5.70 27600,27659,27630,7.50,4.30,18.70,5.70 27660,27719,27690,6.10,4.20,22.30,6.30 27720,27779,27750,6.50,4.20,28.20,7.40 27780,27839,27810,6.00,4.20,26.80,7.10 27840,27899,27870,7.80,4.40,28.70,7.50 27900,27959,27930,7.10,4.30,23.40,6.50 27960,28019,27990,7.10,4.30,24.40,6.70 28020,28079,28050,6.50,4.30,24.30,6.70 28080,28139,28110,7.20,4.30,25.10,6.80 28140,28199,28170,8.40,4.40,25.60,6.90 28200,28259,28230,8.80,4.40,21.70,6.20 28260,28319,28290,7.10,4.30,26.80,7.10 28320,28379,28350,6.40,4.20,31.10,7.90 28380,28439,28410,6.90,4.30,31.60,8.00 28440,28499,28470,8.60,4.40,27.70,7.30 28500,28559,28530,9.00,4.50,25.40,6.90 28560,28619,28590,8.50,4.40,27.20,7.20 28620,28679,28650,8.70,4.40,27.10,7.20 28680,28739,28710,9.20,4.50,27.00,7.20 28740,28799,28770,9.70,4.50,25.30,6.80 28800,28859,28830,9.50,4.50,24.80,6.80 28860,28919,28890,9.40,4.50,24.70,6.70 28920,28979,28950,9.60,4.50,24.10,6.60 28980,29039,29010,9.00,4.50,23.20,6.50 29040,29099,29070,9.10,4.50,23.00,6.50 29100,29159,29130,9.50,4.50,24.10,6.60 29160,29219,29190,10.90,4.70,25.00,6.80 29220,29279,29250,11.80,4.80,25.40,6.90 29280,29339,29310,12.30,4.80,26.60,7.10 29340,29399,29370,11.60,4.70,26.70,7.10 29400,29459,29430,11.20,4.70,31.70,8.00 29460,29519,29490,9.20,4.50,34.30,8.50 29520,29579,29550,9.00,4.50,41.40,10.00 29580,29639,29610,8.70,4.40,41.80,10.00 29640,29699,29670,11.50,4.70,43.90,10.50 29700,29759,29730,12.70,4.90,39.30,9.50 29760,29819,29790,13.40,5.00,37.20,9.10 29820,29879,29850,12.90,4.90,37.50,9.20 29880,29939,29910,13.50,5.00,40.70,9.80 29940,29999,29970,13.60,5.00,42.50,10.20 30000,30059,30030,14.50,5.10,41.90,10.10 30060,30119,30090,15.30,5.20,41.60,10.00 30120,30179,30150,16.00,5.30,39.80,9.60 30180,30239,30210,16.00,5.30,39.30,9.50 30240,30299,30270,16.20,5.40,39.80,9.60 30300,30359,30330,16.50,5.40,41.70,10.00 30360,30419,30390,16.50,5.40,39.70,9.60 30420,30479,30450,14.70,5.10,44.30,10.50 30480,30539,30510,14.30,5.10,52.00,12.10 30540,30599,30570,14.50,5.10,59.30,13.60 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