49, 1001 Cantrell, Christopher A Atmospheric Chemistry Division/NESL/NCAR HO2 and HO2+RO2 from PeRCIMS at Manitou Experimental Forest BEACHON-RoMBAS 1,1 2011, 08, 13, 2011, 11, 24 0 Start_MST, seconds, number_of_seconds_from_0000_MST 6 1,1,1,1,1,1 -99999,-99999,-99999,-99999,-99999,-99999 Stop_MST, seconds, number_of_seconds_from_0000_MST Mid_MST, seconds, number_of_seconds_from_0000_MST HO2, pptv, HO2_mixing_ratio HO2_uncertainty, pptv, HO2_2_sigma_uncertainty HO2+RO2, pptv, HO2+RO2_mixing_ratio HO2+RO2_uncertainty, pptv, HO2+RO2_2_sigma_uncertainty 5 These data are reduced using four factors determined in the laboratory and in the field: F_lo and F_hi are the radical sensitivities in the HO2+RO2 and HO2 modes, respectively (units pptv/ion ratio). Alpha_lo and alpha_hi are the ratios of RO2 to HO2 sensitivity in the HO2+RO2 and HO2 modes, respectively. HO2+RO2 concentrations are then S_lo*F_lo-(S_lo*F_lo - S_hi*F_hi)*(alpha_lo - 1)/(alpha_lo - alpha_hi) . HO2 concentrations are S_lo*F_lo-(S_lo*F_lo - S_hi*F_hi)*(alpha_lo)/(alpha_lo - alpha_hi) . S_lo is the background corrected ion ratio in the HO2+RO2 mode, and S_hi is the background corrected ion ratio in the HO2 mode. The ion ratios are mass 97 signal count rate minus background count rate divided by mass 62 count rate. 24 PI_CONTACT_INFO: 303-497-1479, NCAR, 3090 Center Green Dr., Boulder, CO 80301, cantrell@ucar.edu PLATFORM: Seacontainer #1 LOCATION: Manitou Experimental Forest, Woodland Park, Colorado, USA ASSOCIATED_DATA: N/A INSTRUMENT_INFO: These data were collected using a CIMS based instrument. An inlet collects ambient air from the free air stream and adds reagents, includling O2 or N2 diluents, and NO and SO2 reagent gases. This method, called oxygen dilution modulation leads to nearly 100% measurement of HO2 and RO2 in the O2 dilution/low reagent concentration mode, whereas RO2 is measured with less than 15% efficiency in the N2 dilution/higher reagent concentration mode. This is because the chemistry converts peroxy radicals to H2SO4 efficiently in the O2 mode, but RO2 radicals are converted to RONO in the N2 mode. The H2SO4 thus produced is ionized by reaction with NO3- ions. The reagent and product ions are detected by mass spectrometry using quadrupole mass filtering and counting by a channel electron multiplier operating in the negative ion mode. DATA_INFO: Signal data for HO2+RO2 are collected during the 0-7 second time interval, and for HO2 in 30-37 second time interval. UNCERTAINTY: approximately 35% (2 sigma) for values well above 2 pptv; estimates are listed for each data point (2 sigma) ULOD_FLAG: -7777 ULOD_VALUE: N/A LLOD_FLAG: -8888 LLOD_VALUE: N/A DM_CONTACT_INFO: N/A PROJECT_INFO: BEACHON-RoMBAS, 20-Jul-2011 to 30-Aug-2011 STIPULATIONS_ON_USE: contact PI BEFORE use/presentation/publication OTHER_COMMENTS: REVISION: R1; R0 R1: final data R0: preliminary data Start_MST,Stop_MST,Mid_MST,HO2,HO2_uncertainty,HO2+RO2,HO2+RO2_uncertainty 0,59,30,3.60,4.10,13.70,5.00 60,119,90,3.80,4.10,13.60,5.00 120,179,150,4.30,4.10,14.10,5.10 180,239,210,4.10,4.10,12.70,4.90 240,299,270,3.60,4.10,11.90,4.80 300,359,330,3.40,4.10,12.30,4.80 360,419,390,3.80,4.10,14.20,5.10 420,479,450,4.70,4.10,16.00,5.30 480,539,510,3.40,4.10,14.30,5.10 540,599,570,4.00,4.10,15.50,5.30 600,659,630,3.70,4.10,13.70,5.00 660,719,690,4.50,4.10,12.70,4.90 720,779,750,5.30,4.20,10.80,4.60 780,839,810,5.10,4.20,10.70,4.60 840,899,870,5.70,4.20,11.80,4.80 900,959,930,3.90,4.10,11.30,4.70 960,1019,990,4.10,4.10,11.00,4.70 1020,1079,1050,3.70,4.10,10.90,4.70 1080,1139,1110,3.70,4.10,9.50,4.50 1140,1199,1170,4.30,4.10,12.40,4.80 1200,1259,1230,3.70,4.10,11.50,4.70 1260,1319,1290,3.90,4.10,13.00,4.90 1320,1379,1350,4.00,4.10,13.10,4.90 1380,1439,1410,4.10,4.10,13.50,5.00 1440,1499,1470,4.80,4.10,12.40,4.80 1500,1559,1530,4.70,4.10,10.40,4.60 1560,1619,1590,6.30,4.20,13.70,5.00 1620,1679,1650,5.80,4.20,14.10,5.10 1680,1739,1710,4.60,4.10,14.10,5.10 1740,1799,1770,3.70,4.10,11.90,4.80 1800,1859,1830,3.60,4.10,12.60,4.90 1860,1919,1890,4.10,4.10,12.80,4.90 1920,1979,1950,3.50,4.10,12.50,4.90 1980,2039,2010,3.60,4.10,12.80,4.90 2040,2099,2070,5.10,4.20,15.00,5.20 2100,2159,2130,5.10,4.20,15.00,5.20 2160,2219,2190,5.10,4.20,14.90,5.20 2220,2279,2250,2.90,4.10,10.70,4.60 2280,2339,2310,3.60,4.10,8.60,4.40 2340,2399,2370,2.50,4.00,8.90,4.50 2400,2459,2430,2.50,4.00,11.20,4.70 2460,2519,2490,1.60,4.00,14.30,5.10 2520,2579,2550,2.30,4.00,13.10,4.90 2580,2639,2610,1.90,4.00,11.30,4.70 2640,2699,2670,2.10,4.00,9.10,4.50 2700,2759,2730,1.90,4.00,8.70,4.40 2760,2819,2790,2.90,4.10,9.40,4.50 2820,2879,2850,3.00,4.10,10.90,4.70 2880,2939,2910,3.60,4.10,11.00,4.70 2940,2999,2970,4.10,4.10,9.40,4.50 3000,3059,3030,4.70,4.10,11.80,4.80 3060,3119,3090,3.70,4.10,10.70,4.60 3120,3179,3150,2.20,4.00,12.40,4.80 3180,3239,3210,1.10,4.00,8.80,4.40 3240,3299,3270,1.60,4.00,10.40,4.60 3300,3359,3330,3.50,4.10,10.70,4.60 3360,3419,3390,3.10,4.10,11.40,4.70 3420,3479,3450,2.90,4.10,9.80,4.50 3480,3539,3510,1.60,4.00,9.20,4.50 3540,3599,3570,2.20,4.00,7.00,4.30 3600,3659,3630,4.10,4.10,7.90,4.40 3660,3719,3690,6.00,4.20,8.80,4.40 3720,3779,3750,7.40,4.30,11.50,4.70 3780,3839,3810,6.20,4.20,12.50,4.90 3840,3899,3870,5.10,4.20,10.50,4.60 3900,3959,3930,4.90,4.10,11.40,4.70 3960,4019,3990,4.70,4.10,8.00,4.40 4020,4079,4050,5.00,4.10,11.00,4.70 4080,4139,4110,3.80,4.10,7.50,4.30 4140,4199,4170,3.50,4.10,10.00,4.60 4200,4259,4230,3.40,4.10,10.20,4.60 4260,4319,4290,3.40,4.10,11.30,4.70 4320,4379,4350,2.80,4.00,10.10,4.60 4380,4439,4410,2.50,4.00,6.20,4.20 4440,4499,4470,3.50,4.10,8.90,4.40 4500,4559,4530,1.70,4.00,8.10,4.40 4560,4619,4590,1.60,4.00,11.40,4.70 4620,4679,4650,1.10,4.00,9.40,4.50 4680,4739,4710,4.10,4.10,11.10,4.70 4740,4799,4770,3.80,4.10,11.30,4.70 4800,4859,4830,3.30,4.10,11.80,4.80 4860,4919,4890,2.20,4.00,10.90,4.70 4920,4979,4950,1.30,4.00,6.30,4.20 4980,5039,5010,1.80,4.00,5.90,4.20 5040,5099,5070,1.90,4.00,7.30,4.30 5100,5159,5130,2.30,4.00,9.10,4.50 5160,5219,5190,1.30,4.00,9.30,4.50 5220,5279,5250,1.00,4.00,10.00,4.60 5280,5339,5310,2.20,4.00,11.30,4.70 5340,5399,5370,3.20,4.10,11.70,4.80 5400,5459,5430,4.40,4.10,10.90,4.70 5460,5519,5490,3.90,4.10,11.10,4.70 5520,5579,5550,3.20,4.10,10.20,4.60 5580,5639,5610,1.90,4.00,11.50,4.70 5640,5699,5670,3.10,4.10,10.70,4.60 5700,5759,5730,6.10,4.20,11.80,4.80 5760,5819,5790,6.80,4.30,11.90,4.80 5820,5879,5850,5.60,4.20,12.80,4.90 5880,5939,5910,2.60,4.00,12.30,4.80 5940,5999,5970,3.00,4.10,12.80,4.90 6000,6059,6030,3.90,4.10,11.60,4.70 6060,6119,6090,4.80,4.10,9.90,4.60 6120,6179,6150,4.00,4.10,8.30,4.40 6180,6239,6210,2.80,4.00,10.40,4.60 6240,6299,6270,1.60,4.00,12.10,4.80 6300,6359,6330,2.10,4.00,12.40,4.80 6360,6419,6390,3.70,4.10,11.80,4.80 6420,6479,6450,4.10,4.10,13.90,5.00 6480,6539,6510,3.80,4.10,15.40,5.20 6540,6599,6570,1.60,4.00,14.20,5.10 6600,6659,6630,3.00,4.10,13.70,5.00 6660,6719,6690,3.50,4.10,12.30,4.80 6720,6779,6750,5.00,4.20,11.30,4.70 6780,6839,6810,4.00,4.10,8.80,4.40 6840,6899,6870,2.80,4.00,8.20,4.40 6900,6959,6930,2.90,4.00,10.70,4.60 6960,7019,6990,2.60,4.00,12.00,4.80 7020,7079,7050,3.20,4.10,13.30,5.00 7080,7139,7110,2.70,4.00,12.00,4.80 7140,7199,7170,3.30,4.10,12.00,4.80 7200,7259,7230,3.40,4.10,11.30,4.70 7260,7319,7290,3.40,4.10,11.90,4.80 7320,7379,7350,3.70,4.10,11.30,4.70 7380,7439,7410,3.20,4.10,12.00,4.80 7440,7499,7470,3.20,4.10,10.00,4.60 7500,7559,7530,2.70,4.00,9.40,4.50 7560,7619,7590,3.50,4.10,8.50,4.40 7620,7679,7650,3.60,4.10,10.70,4.60 7680,7739,7710,3.40,4.10,13.20,4.90 7740,7799,7770,3.10,4.10,12.70,4.90 7800,7859,7830,2.30,4.00,12.90,4.90 7860,7919,7890,2.50,4.00,11.30,4.70 7920,7979,7950,1.80,4.00,11.60,4.70 7980,8039,8010,2.80,4.00,10.40,4.60 8040,8099,8070,3.00,4.10,10.20,4.60 8100,8159,8130,4.20,4.10,10.90,4.70 8160,8219,8190,3.00,4.10,11.10,4.70 8220,8279,8250,3.40,4.10,9.60,4.50 8280,8339,8310,3.60,4.10,9.20,4.50 8340,8399,8370,4.10,4.10,12.30,4.80 8400,8459,8430,1.50,4.00,13.80,5.00 8460,8519,8490,0.10,4.00,13.30,5.00 8520,8579,8550,-0.10,4.00,9.60,4.50 8580,8639,8610,1.20,4.00,10.70,4.60 8640,8699,8670,1.10,4.00,11.10,4.70 8700,8759,8730,1.20,4.00,11.00,4.70 8760,8819,8790,1.20,4.00,9.50,4.50 8820,8879,8850,1.60,4.00,9.60,4.50 8880,8939,8910,1.20,4.00,10.80,4.70 8940,8999,8970,1.50,4.00,8.60,4.40 9000,9059,9030,2.30,4.00,9.00,4.50 9060,9119,9090,3.40,4.10,8.50,4.40 9120,9179,9150,4.00,4.10,11.60,4.70 9180,9239,9210,3.80,4.10,11.50,4.70 9240,9299,9270,2.90,4.10,11.50,4.70 9300,9359,9330,2.50,4.00,10.60,4.60 9360,9419,9390,2.50,4.00,9.30,4.50 9420,9479,9450,2.80,4.00,7.80,4.40 9480,9539,9510,2.80,4.00,8.50,4.40 9540,9599,9570,2.30,4.00,9.90,4.60 9600,9659,9630,2.10,4.00,12.90,4.90 9660,9719,9690,1.30,4.00,10.90,4.70 9720,9779,9750,1.20,4.00,10.20,4.60 9780,9839,9810,1.90,4.00,8.50,4.40 9840,9899,9870,2.80,4.00,8.80,4.40 9900,9959,9930,3.60,4.10,7.70,4.30 9960,10019,9990,3.50,4.10,8.80,4.40 10020,10079,10050,4.30,4.10,9.10,4.50 10080,10139,10110,5.00,4.10,10.60,4.60 10140,10199,10170,3.80,4.10,10.20,4.60 10200,10259,10230,2.10,4.00,11.30,4.70 10260,10319,10290,1.90,4.00,11.10,4.70 10320,10379,10350,3.50,4.10,9.70,4.50 10380,10439,10410,4.90,4.10,9.50,4.50 10440,10499,10470,4.20,4.10,10.80,4.70 10500,10559,10530,3.40,4.10,12.70,4.90 10560,10619,10590,2.40,4.00,12.90,4.90 10620,10679,10650,1.50,4.00,11.20,4.70 10680,10739,10710,0.50,4.00,10.60,4.60 10740,10799,10770,1.40,4.00,9.90,4.60 10800,10859,10830,2.10,4.00,11.50,4.70 10860,10919,10890,1.00,4.00,9.40,4.50 10920,10979,10950,1.00,4.00,7.80,4.30 10980,11039,11010,2.80,4.00,6.20,4.20 11040,11099,11070,5.40,4.20,8.30,4.40 11100,11159,11130,4.10,4.10,10.60,4.60 11160,11219,11190,2.20,4.00,10.70,4.60 11220,11279,11250,1.60,4.00,7.90,4.40 11280,11339,11310,2.90,4.00,6.80,4.30 11340,11399,11370,3.10,4.10,7.20,4.30 11400,11459,11430,1.80,4.00,7.50,4.30 11460,11519,11490,1.80,4.00,8.10,4.40 11520,11579,11550,1.60,4.00,7.60,4.30 11580,11639,11610,2.80,4.00,9.40,4.50 11640,11699,11670,2.50,4.00,9.00,4.50 11700,11759,11730,2.70,4.00,8.90,4.50 11760,11819,11790,2.50,4.00,8.80,4.40 11820,11879,11850,1.80,4.00,10.00,4.60 11880,11939,11910,1.00,4.00,11.40,4.70 11940,11999,11970,0.90,4.00,9.20,4.50 12000,12059,12030,0.80,4.00,7.30,4.30 12060,12119,12090,1.00,4.00,4.10,4.10 12120,12179,12150,1.70,4.00,6.70,4.30 12180,12239,12210,2.90,4.10,8.80,4.40 12240,12299,12270,3.30,4.10,8.90,4.50 12300,12359,12330,2.30,4.00,10.00,4.60 12360,12419,12390,0.90,4.00,7.20,4.30 12420,12479,12450,1.20,4.00,7.20,4.30 12480,12539,12510,2.90,4.10,5.90,4.20 12540,12599,12570,4.40,4.10,7.30,4.30 12600,12659,12630,4.10,4.10,8.90,4.50 12660,12719,12690,2.70,4.00,9.80,4.50 12720,12779,12750,1.40,4.00,9.20,4.50 12780,12839,12810,1.70,4.00,9.80,4.50 12840,12899,12870,2.40,4.00,8.90,4.50 12900,12959,12930,2.40,4.00,7.30,4.30 12960,13019,12990,3.60,4.10,7.50,4.30 13020,13079,13050,4.10,4.10,7.10,4.30 13080,13139,13110,4.80,4.10,8.00,4.40 13140,13199,13170,3.70,4.10,6.20,4.20 13200,13259,13230,3.50,4.10,7.00,4.30 13260,13319,13290,2.20,4.00,6.40,4.20 13320,13379,13350,2.00,4.00,6.60,4.30 13380,13439,13410,1.30,4.00,6.20,4.20 13440,13499,13470,2.10,4.00,8.30,4.40 13500,13559,13530,1.60,4.00,7.00,4.30 13560,13619,13590,1.40,4.00,4.60,4.10 13620,13679,13650,1.20,4.00,3.30,4.10 13680,13739,13710,1.60,4.00,3.90,4.10 13740,13799,13770,1.70,4.00,4.50,4.10 13800,13859,13830,1.50,4.00,3.90,4.10 13860,13919,13890,0.60,4.00,4.30,4.10 13920,13979,13950,0.40,4.00,5.20,4.20 13980,14039,14010,0.90,4.00,6.20,4.20 14040,14099,14070,1.90,4.00,6.20,4.20 14100,14159,14130,1.80,4.00,5.80,4.20 14160,14219,14190,0.60,4.00,4.50,4.10 14220,14279,14250,-0.20,4.00,3.80,4.10 14280,14339,14310,0.70,4.00,3.20,4.10 14340,14399,14370,2.30,4.00,3.20,4.10 14400,14459,14430,2.50,4.00,5.10,4.20 14460,14519,14490,2.00,4.00,6.70,4.30 14520,14579,14550,1.50,4.00,7.80,4.40 14580,14639,14610,1.80,4.00,7.50,4.30 14640,14699,14670,2.80,4.00,7.90,4.40 14700,14759,14730,4.10,4.10,9.10,4.50 14760,14819,14790,5.00,4.10,8.90,4.50 14820,14879,14850,4.90,4.10,9.80,4.50 14880,14939,14910,3.90,4.10,9.60,4.50 14940,14999,14970,3.20,4.10,10.10,4.60 15000,15059,15030,1.00,4.00,9.20,4.50 15060,15119,15090,0.30,4.00,8.60,4.40 15120,15179,15150,0.80,4.00,8.40,4.40 15180,15239,15210,1.80,4.00,8.00,4.40 15240,15299,15270,1.80,4.00,10.40,4.60 15300,15359,15330,1.20,4.00,8.00,4.40 15360,15419,15390,1.00,4.00,6.90,4.30 15420,15479,15450,1.60,4.00,3.30,4.10 15480,15539,15510,2.50,4.00,4.30,4.10 15540,15599,15570,2.50,4.00,3.50,4.10 15600,15659,15630,2.40,4.00,3.30,4.10 15660,15719,15690,1.70,4.00,3.50,4.10 15720,15779,15750,2.60,4.00,4.60,4.10 15780,15839,15810,3.00,4.10,7.70,4.30 15840,15899,15870,4.10,4.10,8.70,4.40 15900,15959,15930,5.40,4.20,8.30,4.40 15960,16019,15990,6.10,4.20,7.70,4.30 16020,16079,16050,5.60,4.20,7.80,4.40 16080,16139,16110,4.10,4.10,8.70,4.40 16140,16199,16170,2.70,4.00,7.70,4.30 16200,16259,16230,2.10,4.00,5.90,4.20 16260,16319,16290,2.30,4.00,3.30,4.10 16320,16379,16350,2.10,4.00,1.70,4.00 16380,16439,16410,2.20,4.00,2.50,4.00 16440,16499,16470,1.20,4.00,4.00,4.10 16500,16559,16530,2.00,4.00,5.80,4.20 16560,16619,16590,1.90,4.00,6.40,4.20 16620,16679,16650,2.90,4.00,8.30,4.40 16680,16739,16710,2.90,4.10,7.50,4.30 16740,16799,16770,2.90,4.10,5.40,4.20 16800,16859,16830,2.80,4.00,3.90,4.10 16860,16919,16890,2.60,4.00,4.80,4.10 16920,16979,16950,2.50,4.00,6.50,4.20 16980,17039,17010,2.30,4.00,7.00,4.30 17040,17099,17070,2.10,4.00,5.60,4.20 17100,17159,17130,1.70,4.00,4.50,4.10 17160,17219,17190,2.60,4.00,5.00,4.10 17220,17279,17250,2.40,4.00,5.50,4.20 17280,17339,17310,2.90,4.10,7.60,4.30 17340,17399,17370,2.30,4.00,7.60,4.30 17400,17459,17430,2.80,4.00,7.70,4.30 17460,17519,17490,3.00,4.10,6.60,4.30 17520,17579,17550,3.00,4.10,6.00,4.20 17580,17639,17610,3.00,4.10,5.10,4.20 17640,17699,17670,2.00,4.00,5.10,4.20 17700,17759,17730,1.30,4.00,7.20,4.30 17760,17819,17790,0.60,4.00,7.60,4.30 17820,17879,17850,1.40,4.00,7.00,4.30 17880,17939,17910,2.10,4.00,4.80,4.10 17940,17999,17970,2.60,4.00,5.20,4.20 18000,18059,18030,2.80,4.00,6.70,4.30 18060,18119,18090,2.30,4.00,5.20,4.20 18120,18179,18150,4.20,4.10,6.90,4.30 18180,18239,18210,4.40,4.10,6.00,4.20 18240,18299,18270,4.80,4.10,6.40,4.20 18300,18359,18330,3.60,4.10,4.50,4.10 18360,18419,18390,2.80,4.00,4.00,4.10 18420,18479,18450,3.10,4.10,4.80,4.10 18480,18539,18510,3.00,4.10,4.70,4.10 18540,18599,18570,4.40,4.10,6.30,4.20 18600,18659,18630,4.00,4.10,6.50,4.20 18660,18719,18690,4.00,4.10,6.10,4.20 18720,18779,18750,2.40,4.00,4.50,4.10 18780,18839,18810,2.60,4.00,4.90,4.10 18840,18899,18870,1.00,4.00,4.40,4.10 18900,18959,18930,0.70,4.00,4.20,4.10 18960,19019,18990,0.20,4.00,4.80,4.10 19020,19079,19050,0.40,4.00,5.30,4.20 19080,19139,19110,1.30,4.00,6.40,4.20 19140,19199,19170,1.30,4.00,5.00,4.10 19200,19259,19230,1.30,4.00,5.40,4.20 19260,19319,19290,0.90,4.00,4.50,4.10 19320,19379,19350,0.90,4.00,6.80,4.30 19380,19439,19410,1.30,4.00,8.00,4.40 19440,19499,19470,0.90,4.00,9.70,4.50 19500,19559,19530,0.40,4.00,9.00,4.50 19560,19619,19590,0.30,4.00,7.70,4.30 19620,19679,19650,1.00,4.00,5.50,4.20 19680,19739,19710,2.00,4.00,4.40,4.10 19740,19799,19770,2.10,4.00,4.00,4.10 19800,19859,19830,2.20,4.00,6.70,4.30 19860,19919,19890,1.80,4.00,7.90,4.40 19920,19979,19950,1.20,4.00,8.40,4.40 19980,20039,20010,0.90,4.00,7.30,4.30 20040,20099,20070,0.10,4.00,6.90,4.30 20100,20159,20130,0.00,4.00,7.50,4.30 20160,20219,20190,-0.30,4.00,8.00,4.40 20220,20279,20250,1.00,4.00,6.90,4.30 20280,20339,20310,2.30,4.00,5.60,4.20 20340,20399,20370,3.50,4.10,6.60,4.30 20400,20459,20430,2.90,4.00,7.20,4.30 20460,20519,20490,2.10,4.00,7.40,4.30 20520,20579,20550,0.90,4.00,5.90,4.20 20580,20639,20610,1.20,4.00,7.20,4.30 20640,20699,20670,1.60,4.00,8.10,4.40 20700,20759,20730,1.00,4.00,8.30,4.40 20760,20819,20790,0.20,4.00,6.70,4.30 20820,20879,20850,0.40,4.00,6.40,4.20 20880,20939,20910,0.30,4.00,6.00,4.20 20940,20999,20970,1.80,4.00,8.00,4.40 21000,21059,21030,2.10,4.00,8.60,4.40 21060,21119,21090,3.50,4.10,8.50,4.40 21120,21179,21150,2.80,4.00,4.30,4.10 21180,21239,21210,3.50,4.10,2.60,4.00 21240,21299,21270,3.40,4.10,1.80,4.00 21300,21359,21330,2.10,4.00,2.70,4.00 21360,21419,21390,0.70,4.00,3.20,4.10 21420,21479,21450,0.20,4.00,5.00,4.10 21480,21539,21510,0.60,4.00,6.20,4.20 21540,21599,21570,0.30,4.00,6.10,4.20 21600,21659,21630,0.50,4.00,6.60,4.30 21660,21719,21690,0.20,4.00,5.10,4.20 21720,21779,21750,0.60,4.00,6.10,4.20 21780,21839,21810,0.70,4.00,4.60,4.10 21840,21899,21870,3.50,4.10,6.50,4.30 21900,21959,21930,3.70,4.10,6.20,4.20 21960,22019,21990,3.70,4.10,6.80,4.30 22020,22079,22050,1.80,4.00,7.40,4.30 22080,22139,22110,1.60,4.00,7.10,4.30 22140,22199,22170,1.10,4.00,5.10,4.20 22200,22259,22230,1.40,4.00,4.70,4.10 22260,22319,22290,1.80,4.00,5.80,4.20 22320,22379,22350,2.30,4.00,7.40,4.30 22380,22439,22410,2.70,4.00,7.50,4.30 22440,22499,22470,1.30,4.00,6.50,4.20 22500,22559,22530,1.60,4.00,8.40,4.40 22560,22619,22590,1.00,4.00,7.70,4.30 22620,22679,22650,2.70,4.00,8.40,4.40 22680,22739,22710,2.30,4.00,8.60,4.40 22740,22799,22770,1.80,4.00,7.50,4.30 22800,22859,22830,1.90,4.00,7.20,4.30 22860,22919,22890,1.90,4.00,4.90,4.10 22920,22979,22950,2.50,4.00,6.90,4.30 22980,23039,23010,1.30,4.00,6.80,4.30 23040,23099,23070,1.50,4.00,5.00,4.10 23100,23159,23130,3.50,4.10,5.00,4.10 23160,23219,23190,3.50,4.10,4.50,4.10 23220,23279,23250,2.00,4.00,5.80,4.20 23280,23339,23310,-0.30,4.00,5.20,4.20 23340,23399,23370,0.80,4.00,6.60,4.30 23400,23459,23430,2.40,4.00,7.70,4.30 23460,23519,23490,2.90,4.10,7.50,4.30 23520,23579,23550,2.70,4.00,7.00,4.30 23580,23639,23610,1.20,4.00,6.10,4.20 23640,23699,23670,1.10,4.00,5.00,4.10 23700,23759,23730,0.70,4.00,3.60,4.10 23760,23819,23790,2.70,4.00,3.70,4.10 23820,23879,23850,3.40,4.10,4.70,4.10 23880,23939,23910,3.80,4.10,5.00,4.20 23940,23999,23970,3.10,4.10,5.00,4.10 24000,24059,24030,2.10,4.00,4.50,4.10 24060,24119,24090,2.10,4.00,5.10,4.20 24120,24179,24150,1.30,4.00,4.30,4.10 24180,24239,24210,2.20,4.00,5.40,4.20 24240,24299,24270,1.30,4.00,4.30,4.10 24300,24359,24330,1.20,4.00,5.10,4.20 24360,24419,24390,-0.70,4.00,5.10,4.20 24420,24479,24450,-1.00,4.00,6.20,4.20 24480,24539,24510,0.10,4.00,6.50,4.20 24540,24599,24570,2.20,4.00,5.00,4.20 24600,24659,24630,4.10,4.10,6.30,4.20 24660,24719,24690,4.50,4.10,7.10,4.30 24720,24779,24750,4.10,4.10,8.60,4.40 24780,24839,24810,3.30,4.10,7.10,4.30 24840,24899,24870,3.00,4.10,6.10,4.20 24900,24959,24930,2.90,4.10,6.80,4.30 24960,25019,24990,1.00,4.00,6.30,4.20 25020,25079,25050,1.30,4.00,7.50,4.30 25080,25139,25110,0.70,4.00,5.90,4.20 25140,25199,25170,2.60,4.00,6.90,4.30 25200,25259,25230,2.30,4.00,6.30,4.20 25260,25319,25290,2.60,4.00,8.10,4.40 25320,25379,25350,1.90,4.00,8.30,4.40 25380,25439,25410,0.80,4.00,9.30,4.50 25440,25499,25470,0.50,4.00,10.30,4.60 25500,25559,25530,-0.40,4.00,9.30,4.50 25560,25619,25590,-0.20,4.00,7.90,4.40 25620,25679,25650,0.40,4.00,5.40,4.20 25680,25739,25710,3.00,4.10,6.30,4.20 25740,25799,25770,4.20,4.10,8.90,4.50 25800,25859,25830,2.70,4.00,11.50,4.70 25860,25919,25890,2.40,4.00,11.10,4.70 25920,25979,25950,2.50,4.00,7.50,4.30 25980,26039,26010,6.10,4.20,6.70,4.30 26040,26099,26070,5.90,4.20,7.10,4.30 26100,26159,26130,5.60,4.20,9.50,4.50 26160,26219,26190,3.50,4.10,8.40,4.40 26220,26279,26250,3.90,4.10,12.80,4.90 26280,26339,26310,4.70,4.10,12.50,4.80 26340,26399,26370,5.00,4.20,12.80,4.90 26400,26459,26430,4.50,4.10,9.30,4.50 26460,26519,26490,4.30,4.10,11.30,4.70 26520,26579,26550,4.80,4.10,12.60,4.90 26580,26639,26610,4.00,4.10,13.20,4.90 26640,26699,26670,4.00,4.10,12.00,4.80 26700,26759,26730,2.80,4.00,13.30,5.00 26760,26819,26790,4.40,4.10,16.10,5.30 26820,26879,26850,4.60,4.10,18.10,5.60 26880,26939,26910,5.50,4.20,16.60,5.40 26940,26999,26970,5.60,4.20,14.50,5.10 27000,27059,27030,6.50,4.20,16.40,5.40 27060,27119,27090,6.10,4.20,18.00,5.60 27120,27179,27150,6.40,4.20,17.20,5.50 27180,27239,27210,4.60,4.10,12.50,4.90 27240,27299,27270,6.20,4.20,12.80,4.90 27300,27359,27330,5.70,4.20,14.50,5.10 27360,27419,27390,5.30,4.20,14.20,5.10 27420,27479,27450,5.10,4.20,13.30,5.00 27480,27539,27510,5.60,4.20,13.30,5.00 27540,27599,27570,7.20,4.30,18.10,5.60 27600,27659,27630,6.40,4.20,18.90,5.80 27660,27719,27690,5.30,4.20,17.60,5.60 27720,27779,27750,5.70,4.20,16.20,5.40 27780,27839,27810,6.20,4.20,16.30,5.40 27840,27899,27870,7.00,4.30,16.80,5.50 27900,27959,27930,5.70,4.20,15.90,5.30 27960,28019,27990,6.30,4.20,18.10,5.70 28020,28079,28050,5.50,4.20,19.50,5.90 28080,28139,28110,5.20,4.20,22.20,6.30 28140,28199,28170,3.20,4.10,23.30,6.50 28200,28259,28230,4.00,4.10,24.20,6.70 28260,28319,28290,6.80,4.30,23.60,6.60 28320,28379,28350,8.40,4.40,19.90,5.90 28380,28439,28410,8.50,4.40,18.00,5.60 28440,28499,28470,6.70,4.30,16.20,5.40 28500,28559,28530,6.10,4.20,17.10,5.50 28560,28619,28590,7.80,4.40,19.50,5.90 28620,28679,28650,9.60,4.50,20.80,6.10 28680,28739,28710,10.30,4.60,22.30,6.30 28740,28799,28770,9.10,4.50,22.10,6.30 28800,28859,28830,7.90,4.40,23.20,6.50 28860,28919,28890,7.70,4.30,22.90,6.40 28920,28979,28950,8.80,4.40,23.60,6.60 28980,29039,29010,10.60,4.60,23.70,6.60 29040,29099,29070,12.90,4.90,25.00,6.80 29100,29159,29130,11.90,4.80,24.40,6.70 29160,29219,29190,12.10,4.80,24.80,6.80 29220,29279,29250,12.00,4.80,25.10,6.80 29280,29339,29310,13.30,5.00,27.50,7.30 29340,29399,29370,12.20,4.80,30.60,7.80 29400,29459,29430,11.10,4.70,32.00,8.10 29460,29519,29490,11.50,4.70,32.70,8.20 29520,29579,29550,12.60,4.90,31.50,8.00 29580,29639,29610,13.80,5.00,32.00,8.10 29640,29699,29670,12.70,4.90,32.60,8.20 29700,29759,29730,11.80,4.80,33.30,8.30 29760,29819,29790,11.60,4.70,35.50,8.80 29820,29879,29850,12.00,4.80,37.80,9.20 29880,29939,29910,12.60,4.90,38.90,9.40 29940,29999,29970,12.50,4.90,43.40,10.40 30000,30059,30030,11.90,4.80,40.50,9.80 30060,30119,30090,12.50,4.80,40.30,9.70 30120,30179,30150,14.10,5.10,39.50,9.60 30180,30239,30210,16.90,5.50,43.50,10.40 30240,30299,30270,18.50,5.70,45.10,10.70 30300,30359,30330,17.30,5.50,40.40,9.70 30360,30419,30390,15.30,5.20,43.90,10.50 30420,30479,30450,14.60,5.10,47.50,11.20 30480,30539,30510,15.40,5.20,52.60,12.20 30540,30599,30570,17.00,5.50,50.80,11.90 30600,30659,30630,17.20,5.50,49.90,11.70 30660,30719,30690,17.70,5.60,47.70,11.20 30720,30779,30750,18.60,5.70,52.50,12.20 30780,30839,30810,18.00,5.60,52.30,12.20 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