49, 1001 Cantrell, Christopher A Atmospheric Chemistry Division/NESL/NCAR HO2 and HO2+RO2 from PeRCIMS at Manitou Experimental Forest BEACHON-RoMBAS 1,1 2011, 08, 07, 2011, 11, 22 0 Start_MST, seconds, number_of_seconds_from_0000_MST 6 1,1,1,1,1,1 -99999,-99999,-99999,-99999,-99999,-99999 Stop_MST, seconds, number_of_seconds_from_0000_MST Mid_MST, seconds, number_of_seconds_from_0000_MST HO2, pptv, HO2_mixing_ratio HO2_uncertainty, pptv, HO2_2_sigma_uncertainty HO2+RO2, pptv, HO2+RO2_mixing_ratio HO2+RO2_uncertainty, pptv, HO2+RO2_2_sigma_uncertainty 5 These data are reduced using four factors determined in the laboratory and in the field: F_lo and F_hi are the radical sensitivities in the HO2+RO2 and HO2 modes, respectively (units pptv/ion ratio). Alpha_lo and alpha_hi are the ratios of RO2 to HO2 sensitivity in the HO2+RO2 and HO2 modes, respectively. HO2+RO2 concentrations are then S_lo*F_lo-(S_lo*F_lo - S_hi*F_hi)*(alpha_lo - 1)/(alpha_lo - alpha_hi) . HO2 concentrations are S_lo*F_lo-(S_lo*F_lo - S_hi*F_hi)*(alpha_lo)/(alpha_lo - alpha_hi) . S_lo is the background corrected ion ratio in the HO2+RO2 mode, and S_hi is the background corrected ion ratio in the HO2 mode. The ion ratios are mass 97 signal count rate minus background count rate divided by mass 62 count rate. 24 PI_CONTACT_INFO: 303-497-1479, NCAR, 3090 Center Green Dr., Boulder, CO 80301, cantrell@ucar.edu PLATFORM: Seacontainer #1 LOCATION: Manitou Experimental Forest, Woodland Park, Colorado, USA ASSOCIATED_DATA: N/A INSTRUMENT_INFO: These data were collected using a CIMS based instrument. An inlet collects ambient air from the free air stream and adds reagents, includling O2 or N2 diluents, and NO and SO2 reagent gases. This method, called oxygen dilution modulation leads to nearly 100% measurement of HO2 and RO2 in the O2 dilution/low reagent concentration mode, whereas RO2 is measured with less than 15% efficiency in the N2 dilution/higher reagent concentration mode. This is because the chemistry converts peroxy radicals to H2SO4 efficiently in the O2 mode, but RO2 radicals are converted to RONO in the N2 mode. The H2SO4 thus produced is ionized by reaction with NO3- ions. The reagent and product ions are detected by mass spectrometry using quadrupole mass filtering and counting by a channel electron multiplier operating in the negative ion mode. DATA_INFO: Signal data for HO2+RO2 are collected during the 0-7 second time interval, and for HO2 in 30-37 second time interval. UNCERTAINTY: approximately 35% (2 sigma) for values well above 2 pptv; estimates are listed for each data point (2 sigma) ULOD_FLAG: -7777 ULOD_VALUE: N/A LLOD_FLAG: -8888 LLOD_VALUE: N/A DM_CONTACT_INFO: N/A PROJECT_INFO: BEACHON-RoMBAS, 20-Jul-2011 to 30-Aug-2011 STIPULATIONS_ON_USE: contact PI BEFORE use/presentation/publication OTHER_COMMENTS: REVISION: R1; R0 R1: final data R0: preliminary data Start_MST,Stop_MST,Mid_MST,HO2,HO2_uncertainty,HO2+RO2,HO2+RO2_uncertainty 0,59,30,1.00,4.00,8.90,4.50 60,119,90,1.10,4.00,10.10,4.60 120,179,150,1.70,4.00,12.90,4.90 180,239,210,3.70,4.10,14.50,5.10 240,299,270,6.10,4.20,14.30,5.10 300,359,330,6.80,4.30,13.80,5.00 360,419,390,8.40,4.40,18.20,5.70 420,479,450,7.10,4.30,20.10,6.00 480,539,510,6.10,4.20,19.30,5.80 540,599,570,3.20,4.10,14.30,5.10 600,659,630,5.90,4.20,14.90,5.20 660,719,690,8.30,4.40,17.20,5.50 720,779,750,10.10,4.60,19.60,5.90 780,839,810,8.90,4.40,17.60,5.60 840,899,870,6.80,4.30,14.70,5.10 900,959,930,6.40,4.20,14.90,5.20 960,1019,990,4.30,4.10,13.90,5.00 1020,1079,1050,5.60,4.20,16.90,5.50 1080,1139,1110,5.10,4.20,15.60,5.30 1140,1199,1170,4.70,4.10,17.80,5.60 1200,1259,1230,3.50,4.10,16.60,5.40 1260,1319,1290,3.10,4.10,17.60,5.60 1320,1379,1350,3.50,4.10,18.40,5.70 1380,1439,1410,4.40,4.10,18.30,5.70 1440,1499,1470,4.10,4.10,19.10,5.80 1500,1559,1530,4.60,4.10,18.90,5.80 1560,1619,1590,3.90,4.10,18.00,5.60 1620,1679,1650,5.20,4.20,17.10,5.50 1680,1739,1710,6.30,4.20,23.80,6.60 1740,1799,1770,5.00,4.10,22.10,6.30 1800,1859,1830,3.20,4.10,19.70,5.90 1860,1919,1890,2.70,4.00,14.90,5.20 1920,1979,1950,4.10,4.10,18.60,5.70 1980,2039,2010,2.40,4.00,23.90,6.60 2040,2099,2070,2.50,4.00,22.00,6.30 2100,2159,2130,1.70,4.00,21.60,6.20 2160,2219,2190,5.70,4.20,21.70,6.20 2220,2279,2250,6.30,4.20,20.60,6.00 2280,2339,2310,6.30,4.20,20.20,6.00 2340,2399,2370,4.50,4.10,17.10,5.50 2400,2459,2430,3.00,4.10,18.00,5.60 2460,2519,2490,3.30,4.10,18.60,5.70 2520,2579,2550,3.70,4.10,18.30,5.70 2580,2639,2610,5.20,4.20,15.60,5.30 2640,2699,2670,6.10,4.20,14.40,5.10 2700,2759,2730,9.80,4.50,13.10,4.90 2760,2819,2790,9.10,4.50,14.20,5.10 2820,2879,2850,9.70,4.50,15.00,5.20 2880,2939,2910,6.10,4.20,16.00,5.30 2940,2999,2970,4.10,4.10,21.00,6.10 3000,3059,3030,3.10,4.10,20.00,5.90 3060,3119,3090,3.30,4.10,19.60,5.90 3120,3179,3150,5.10,4.20,15.20,5.20 3180,3239,3210,4.90,4.10,15.90,5.30 3240,3299,3270,4.70,4.10,13.20,4.90 3300,3359,3330,5.20,4.20,14.00,5.00 3360,3419,3390,6.60,4.30,14.80,5.20 3420,3479,3450,2.20,4.00,16.20,5.40 3480,3539,3510,0.60,4.00,21.50,6.20 3540,3599,3570,0.40,4.00,20.70,6.10 3600,3659,3630,5.80,4.20,21.40,6.20 3660,3719,3690,7.20,4.30,14.40,5.10 3720,3779,3750,6.70,4.30,12.70,4.90 3780,3839,3810,5.40,4.20,12.70,4.90 3840,3899,3870,5.80,4.20,17.40,5.50 3900,3959,3930,1.80,4.00,18.30,5.70 3960,4019,3990,3.10,4.10,20.00,5.90 4020,4079,4050,2.00,4.00,17.60,5.60 4080,4139,4110,5.90,4.20,17.00,5.50 4140,4199,4170,7.40,4.30,18.10,5.60 4200,4259,4230,8.80,4.40,19.10,5.80 4260,4319,4290,8.10,4.40,18.50,5.70 4320,4379,4350,6.40,4.20,17.40,5.50 4380,4439,4410,5.50,4.20,14.30,5.10 4440,4499,4470,4.70,4.10,12.90,4.90 4500,4559,4530,3.10,4.10,10.50,4.60 4560,4619,4590,2.50,4.00,10.00,4.60 4620,4679,4650,4.40,4.10,13.60,5.00 4680,4739,4710,3.80,4.10,12.10,4.80 4740,4799,4770,4.20,4.10,15.40,5.20 4800,4859,4830,2.40,4.00,12.70,4.90 4860,4919,4890,2.80,4.00,11.30,4.70 4920,4979,4950,3.90,4.10,8.20,4.40 4980,5039,5010,3.90,4.10,9.40,4.50 5040,5099,5070,5.70,4.20,15.60,5.30 5100,5159,5130,3.70,4.10,14.60,5.10 5160,5219,5190,4.50,4.10,14.10,5.10 5220,5279,5250,4.00,4.10,14.30,5.10 5280,5339,5310,4.80,4.10,16.90,5.50 5340,5399,5370,5.00,4.10,18.10,5.70 5400,5459,5430,4.20,4.10,17.60,5.60 5460,5519,5490,4.50,4.10,18.10,5.70 5520,5579,5550,5.00,4.10,16.90,5.50 5580,5639,5610,5.00,4.10,13.90,5.00 5640,5699,5670,5.40,4.20,11.90,4.80 5700,5759,5730,3.50,4.10,11.60,4.70 5760,5819,5790,2.70,4.00,12.70,4.90 5820,5879,5850,1.50,4.00,10.70,4.60 5880,5939,5910,2.30,4.00,11.90,4.80 5940,5999,5970,2.60,4.00,11.80,4.80 6000,6059,6030,3.30,4.10,15.20,5.20 6060,6119,6090,3.40,4.10,17.90,5.60 6120,6179,6150,2.50,4.00,20.20,6.00 6180,6239,6210,0.50,4.00,18.10,5.60 6240,6299,6270,0.50,4.00,15.90,5.30 6300,6359,6330,3.30,4.10,14.50,5.10 6360,6419,6390,5.90,4.20,17.20,5.50 6420,6479,6450,6.40,4.20,14.30,5.10 6480,6539,6510,6.80,4.30,16.40,5.40 6540,6599,6570,5.20,4.20,15.80,5.30 6600,6659,6630,4.90,4.10,18.40,5.70 6660,6719,6690,3.60,4.10,15.50,5.20 6720,6779,6750,3.40,4.10,14.00,5.10 6780,6839,6810,4.10,4.10,12.30,4.80 6840,6899,6870,3.80,4.10,13.80,5.00 6900,6959,6930,5.70,4.20,18.40,5.70 6960,7019,6990,3.90,4.10,22.10,6.30 7020,7079,7050,3.40,4.10,19.80,5.90 7080,7139,7110,2.30,4.00,18.40,5.70 7140,7199,7170,2.10,4.00,14.90,5.20 7200,7259,7230,2.10,4.00,16.80,5.40 7260,7319,7290,1.90,4.00,15.90,5.30 7320,7379,7350,2.20,4.00,15.30,5.20 7380,7439,7410,3.80,4.10,14.10,5.10 7440,7499,7470,2.70,4.00,10.90,4.70 7500,7559,7530,4.50,4.10,14.60,5.10 7560,7619,7590,3.40,4.10,15.60,5.30 7620,7679,7650,5.10,4.20,17.20,5.50 7680,7739,7710,3.90,4.10,15.00,5.20 7740,7799,7770,4.40,4.10,18.20,5.70 7800,7859,7830,2.70,4.00,15.70,5.30 7860,7919,7890,5.60,4.20,18.40,5.70 7920,7979,7950,5.00,4.10,13.70,5.00 7980,8039,8010,6.00,4.20,17.60,5.60 8040,8099,8070,4.10,4.10,19.00,5.80 8100,8159,8130,4.10,4.10,19.90,5.90 8160,8219,8190,4.10,4.10,19.80,5.90 8220,8279,8250,3.80,4.10,14.10,5.10 8280,8339,8310,5.00,4.10,13.40,5.00 8340,8399,8370,4.90,4.10,12.90,4.90 8400,8459,8430,4.20,4.10,15.80,5.30 8460,8519,8490,0.80,4.00,17.20,5.50 8520,8579,8550,1.60,4.00,16.30,5.40 8580,8639,8610,0.60,4.00,13.10,4.90 8640,8699,8670,3.20,4.10,11.60,4.70 8700,8759,8730,2.80,4.00,10.80,4.70 8760,8819,8790,3.80,4.10,10.40,4.60 8820,8879,8850,4.10,4.10,9.30,4.50 8880,8939,8910,4.80,4.10,9.70,4.50 8940,8999,8970,7.30,4.30,15.30,5.20 9000,9059,9030,8.70,4.40,16.60,5.40 9060,9119,9090,7.20,4.30,17.40,5.50 9120,9179,9150,5.90,4.20,17.60,5.60 9180,9239,9210,4.60,4.10,17.70,5.60 9240,9299,9270,4.90,4.10,19.60,5.90 9300,9359,9330,3.10,4.10,18.70,5.70 9360,9419,9390,2.80,4.00,19.80,5.90 9420,9479,9450,4.40,4.10,17.90,5.60 9480,9539,9510,6.50,4.20,16.20,5.40 9540,9599,9570,7.00,4.30,16.40,5.40 9600,9659,9630,6.40,4.20,13.60,5.00 9660,9719,9690,5.30,4.20,16.60,5.40 9720,9779,9750,4.00,4.10,13.80,5.00 9780,9839,9810,3.50,4.10,18.60,5.70 9840,9899,9870,3.10,4.10,13.60,5.00 9900,9959,9930,3.40,4.10,14.80,5.20 9960,10019,9990,3.50,4.10,13.40,5.00 10020,10079,10050,5.00,4.10,13.90,5.00 10080,10139,10110,5.30,4.20,17.90,5.60 10140,10199,10170,6.50,4.20,17.30,5.50 10200,10259,10230,4.80,4.10,20.10,6.00 10260,10319,10290,3.90,4.10,18.30,5.70 10320,10379,10350,3.10,4.10,17.90,5.60 10380,10439,10410,5.10,4.20,17.30,5.50 10440,10499,10470,6.70,4.30,17.40,5.50 10500,10559,10530,5.60,4.20,17.10,5.50 10560,10619,10590,3.00,4.10,15.80,5.30 10620,10679,10650,1.10,4.00,12.10,4.80 10680,10739,10710,1.10,4.00,11.70,4.80 10740,10799,10770,1.50,4.00,10.70,4.60 10800,10859,10830,2.10,4.00,10.00,4.60 10860,10919,10890,2.90,4.00,9.10,4.50 10920,10979,10950,3.70,4.10,8.80,4.40 10980,11039,11010,3.90,4.10,10.60,4.60 11040,11099,11070,3.60,4.10,12.00,4.80 11100,11159,11130,2.90,4.00,13.20,4.90 11160,11219,11190,1.70,4.00,10.70,4.60 11220,11279,11250,3.60,4.10,11.00,4.70 11280,11339,11310,3.90,4.10,10.50,4.60 11340,11399,11370,5.80,4.20,15.40,5.20 11400,11459,11430,3.50,4.10,11.60,4.70 11460,11519,11490,4.20,4.10,12.40,4.80 11520,11579,11550,3.70,4.10,7.30,4.30 11580,11639,11610,4.40,4.10,11.40,4.70 11640,11699,11670,3.10,4.10,9.00,4.50 11700,11759,11730,2.50,4.00,10.00,4.60 11760,11819,11790,2.20,4.00,11.30,4.70 11820,11879,11850,2.60,4.00,14.70,5.10 11880,11939,11910,3.20,4.10,17.30,5.50 11940,11999,11970,3.70,4.10,15.70,5.30 12000,12059,12030,4.90,4.10,14.60,5.10 12060,12119,12090,5.90,4.20,13.40,5.00 12120,12179,12150,6.40,4.20,12.20,4.80 12180,12239,12210,6.00,4.20,11.70,4.80 12240,12299,12270,5.00,4.10,11.10,4.70 12300,12359,12330,3.70,4.10,6.50,4.30 12360,12419,12390,2.10,4.00,2.80,4.00 12420,12479,12450,1.00,4.00,0.30,4.00 12480,12539,12510,2.40,4.00,6.00,4.20 12540,12599,12570,3.30,4.10,8.80,4.40 12600,12659,12630,3.30,4.10,10.80,4.70 12660,12719,12690,1.80,4.00,9.90,4.60 12720,12779,12750,1.70,4.00,11.60,4.70 12780,12839,12810,2.10,4.00,10.20,4.60 12840,12899,12870,1.50,4.00,9.30,4.50 12900,12959,12930,2.00,4.00,10.40,4.60 12960,13019,12990,1.00,4.00,12.50,4.90 13020,13079,13050,1.20,4.00,11.80,4.80 13080,13139,13110,0.10,4.00,7.70,4.30 13140,13199,13170,0.60,4.00,8.70,4.40 13200,13259,13230,1.80,4.00,9.00,4.50 13260,13319,13290,3.90,4.10,10.70,4.60 13320,13379,13350,5.40,4.20,10.10,4.60 13380,13439,13410,4.40,4.10,11.20,4.70 13440,13499,13470,1.60,4.00,8.20,4.40 13500,13559,13530,0.90,4.00,9.00,4.50 13560,13619,13590,1.50,4.00,7.20,4.30 13620,13679,13650,3.10,4.10,9.30,4.50 13680,13739,13710,1.50,4.00,7.20,4.30 13740,13799,13770,-0.40,4.00,9.30,4.50 13800,13859,13830,-2.70,4.00,9.40,4.50 13860,13919,13890,-2.90,4.10,10.40,4.60 13920,13979,13950,-3.00,4.10,7.10,4.30 13980,14039,14010,-1.30,4.00,7.20,4.30 14040,14099,14070,0.40,4.00,7.80,4.40 14100,14159,14130,2.30,4.00,9.90,4.60 14160,14219,14190,1.70,4.00,9.90,4.60 14220,14279,14250,1.60,4.00,9.70,4.50 14280,14339,14310,1.70,4.00,10.90,4.70 14340,14399,14370,2.80,4.00,10.50,4.60 14400,14459,14430,3.90,4.10,9.00,4.50 14460,14519,14490,5.30,4.20,9.50,4.50 14520,14579,14550,5.40,4.20,9.50,4.50 14580,14639,14610,4.90,4.10,9.50,4.50 14640,14699,14670,4.10,4.10,10.50,4.60 14700,14759,14730,4.40,4.10,11.60,4.70 14760,14819,14790,4.40,4.10,10.40,4.60 14820,14879,14850,4.80,4.10,7.30,4.30 14880,14939,14910,3.00,4.10,5.30,4.20 14940,14999,14970,3.30,4.10,6.10,4.20 15000,15059,15030,2.40,4.00,7.30,4.30 15060,15119,15090,3.80,4.10,10.10,4.60 15120,15179,15150,1.80,4.00,9.50,4.50 15180,15239,15210,1.70,4.00,9.10,4.50 15240,15299,15270,1.40,4.00,6.50,4.20 15300,15359,15330,3.80,4.10,5.60,4.20 15360,15419,15390,4.90,4.10,8.10,4.40 15420,15479,15450,4.20,4.10,9.00,4.50 15480,15539,15510,2.80,4.00,13.50,5.00 15540,15599,15570,3.00,4.10,10.90,4.70 15600,15659,15630,4.90,4.10,11.90,4.80 15660,15719,15690,4.60,4.10,8.70,4.40 15720,15779,15750,3.10,4.10,9.10,4.50 15780,15839,15810,2.10,4.00,10.20,4.60 15840,15899,15870,0.80,4.00,9.70,4.50 15900,15959,15930,0.50,4.00,8.40,4.40 15960,16019,15990,0.60,4.00,5.10,4.20 16020,16079,16050,2.10,4.00,7.10,4.30 16080,16139,16110,2.30,4.00,11.70,4.80 16140,16199,16170,1.70,4.00,15.90,5.30 16200,16259,16230,1.60,4.00,17.20,5.50 16260,16319,16290,3.20,4.10,15.10,5.20 16320,16379,16350,3.20,4.10,10.30,4.60 16380,16439,16410,4.00,4.10,8.30,4.40 16440,16499,16470,2.40,4.00,7.50,4.30 16500,16559,16530,1.30,4.00,11.70,4.80 16560,16619,16590,0.40,4.00,15.00,5.20 16620,16679,16650,-1.00,4.00,14.50,5.10 16680,16739,16710,0.20,4.00,10.80,4.70 16740,16799,16770,2.60,4.00,8.60,4.40 16800,16859,16830,6.40,4.20,12.80,4.90 16860,16919,16890,7.70,4.30,16.80,5.40 16920,16979,16950,6.80,4.30,14.40,5.10 16980,17039,17010,6.10,4.20,9.80,4.50 17040,17099,17070,10.10,4.60,9.20,4.50 17100,17159,17130,8.00,4.40,10.80,4.60 17160,17219,17190,5.70,4.20,8.30,4.40 17220,17279,17250,1.00,4.00,6.60,4.30 17280,17339,17310,2.20,4.00,4.50,4.10 17340,17399,17370,3.40,4.10,4.00,4.10 17400,17459,17430,4.20,4.10,3.30,4.10 17460,17519,17490,3.00,4.10,1.30,4.00 17520,17579,17550,3.20,4.10,4.80,4.10 17580,17639,17610,1.40,4.00,3.40,4.10 17640,17699,17670,1.70,4.00,6.80,4.30 17700,17759,17730,-0.40,4.00,6.90,4.30 17760,17819,17790,2.00,4.00,10.50,4.60 17820,17879,17850,0.30,4.00,8.90,4.50 17880,17939,17910,0.60,4.00,7.10,4.30 17940,17999,17970,-1.60,4.00,4.80,4.10 18000,18059,18030,-1.00,4.00,4.50,4.10 18060,18119,18090,0.20,4.00,5.00,4.10 18120,18179,18150,-0.20,4.00,3.50,4.10 18180,18239,18210,0.50,4.00,3.20,4.10 18240,18299,18270,-0.50,4.00,1.50,4.00 18300,18359,18330,0.30,4.00,0.10,4.00 18360,18419,18390,2.20,4.00,-0.40,4.00 18420,18479,18450,3.60,4.10,0.30,4.00 18480,18539,18510,3.00,4.10,2.00,4.00 18540,18599,18570,1.70,4.00,6.10,4.20 18600,18659,18630,-0.20,4.00,6.20,4.20 18660,18719,18690,2.30,4.00,9.00,4.50 18720,18779,18750,3.20,4.10,9.70,4.50 18780,18839,18810,5.80,4.20,13.60,5.00 18840,18899,18870,3.50,4.10,14.30,5.10 18900,18959,18930,2.30,4.00,9.90,4.60 18960,19019,18990,1.70,4.00,8.30,4.40 19020,19079,19050,1.50,4.00,4.30,4.10 19080,19139,19110,2.90,4.10,6.10,4.20 19140,19199,19170,2.00,4.00,3.90,4.10 19200,19259,19230,2.90,4.00,4.20,4.10 19260,19319,19290,2.60,4.00,4.50,4.10 19320,19379,19350,3.80,4.10,6.00,4.20 19380,19439,19410,3.00,4.10,6.60,4.30 19440,19499,19470,2.40,4.00,8.20,4.40 19500,19559,19530,1.00,4.00,6.50,4.20 19560,19619,19590,3.40,4.10,7.90,4.40 19620,19679,19650,3.40,4.10,4.60,4.10 19680,19739,19710,3.20,4.10,7.10,4.30 19740,19799,19770,0.40,4.00,5.40,4.20 19800,19859,19830,-0.20,4.00,11.00,4.70 19860,19919,19890,-0.40,4.00,10.60,4.60 19920,19979,19950,-2.30,4.00,9.30,4.50 19980,20039,20010,-2.30,4.00,6.10,4.20 20040,20099,20070,-2.30,4.00,5.50,4.20 20100,20159,20130,-0.30,4.00,5.80,4.20 20160,20219,20190,0.10,4.00,6.50,4.20 20220,20279,20250,1.70,4.00,3.90,4.10 20280,20339,20310,1.70,4.00,5.90,4.20 20340,20399,20370,1.40,4.00,8.30,4.40 20400,20459,20430,0.40,4.00,11.50,4.70 20460,20519,20490,0.00,4.00,12.30,4.80 20520,20579,20550,-0.40,4.00,10.00,4.60 20580,20639,20610,0.50,4.00,10.40,4.60 20640,20699,20670,1.50,4.00,13.30,5.00 20700,20759,20730,3.50,4.10,15.10,5.20 20760,20819,20790,4.80,4.10,14.30,5.10 20820,20879,20850,6.30,4.20,9.20,4.50 20880,20939,20910,5.20,4.20,8.10,4.40 20940,20999,20970,4.30,4.10,6.70,4.30 21000,21059,21030,4.10,4.10,8.20,4.40 21060,21119,21090,5.90,4.20,6.20,4.20 21120,21179,21150,7.30,4.30,8.30,4.40 21180,21239,21210,7.00,4.30,11.10,4.70 21240,21299,21270,5.20,4.20,12.30,4.80 21300,21359,21330,3.10,4.10,11.60,4.70 21360,21419,21390,1.30,4.00,8.70,4.40 21420,21479,21450,1.20,4.00,11.30,4.70 21480,21539,21510,1.20,4.00,10.40,4.60 21540,21599,21570,2.60,4.00,8.80,4.40 21600,21659,21630,3.90,4.10,3.70,4.10 21660,21719,21690,3.80,4.10,4.40,4.10 21720,21779,21750,3.90,4.10,6.50,4.20 21780,21839,21810,3.10,4.10,10.40,4.60 21840,21899,21870,2.80,4.00,11.40,4.70 21900,21959,21930,1.00,4.00,12.50,4.80 21960,22019,21990,0.30,4.00,10.70,4.60 22020,22079,22050,0.60,4.00,10.80,4.70 22080,22139,22110,1.10,4.00,9.40,4.50 22140,22199,22170,0.60,4.00,7.50,4.30 22200,22259,22230,1.00,4.00,7.20,4.30 22260,22319,22290,2.20,4.00,7.20,4.30 22320,22379,22350,2.20,4.00,9.00,4.50 22380,22439,22410,1.10,4.00,11.90,4.80 22440,22499,22470,-0.50,4.00,10.20,4.60 22500,22559,22530,-1.20,4.00,13.30,5.00 22560,22619,22590,0.60,4.00,12.60,4.90 22620,22679,22650,2.30,4.00,15.00,5.20 22680,22739,22710,2.00,4.00,14.00,5.10 22740,22799,22770,0.10,4.00,14.10,5.10 22800,22859,22830,-1.00,4.00,15.80,5.30 22860,22919,22890,0.30,4.00,16.00,5.30 22920,22979,22950,1.00,4.00,17.10,5.50 22980,23039,23010,2.00,4.00,15.20,5.20 23040,23099,23070,1.20,4.00,13.60,5.00 23100,23159,23130,3.50,4.10,10.70,4.60 23160,23219,23190,1.90,4.00,11.50,4.70 23220,23279,23250,3.30,4.10,13.70,5.00 23280,23339,23310,1.50,4.00,19.80,5.90 23340,23399,23370,3.30,4.10,16.00,5.30 23400,23459,23430,3.90,4.10,13.10,4.90 23460,23519,23490,4.80,4.10,11.50,4.70 23520,23579,23550,3.60,4.10,15.90,5.30 23580,23639,23610,3.90,4.10,17.40,5.50 23640,23699,23670,3.60,4.10,14.90,5.20 23700,23759,23730,2.10,4.00,16.20,5.40 23760,23819,23790,1.20,4.00,11.80,4.80 23820,23879,23850,-0.20,4.00,12.60,4.90 23880,23939,23910,2.00,4.00,14.60,5.10 23940,23999,23970,1.20,4.00,17.30,5.50 24000,24059,24030,3.40,4.10,15.70,5.30 24060,24119,24090,4.60,4.10,11.90,4.80 24120,24179,24150,6.00,4.20,15.70,5.30 24180,24239,24210,5.50,4.20,16.30,5.40 24240,24299,24270,6.30,4.20,19.70,5.90 24300,24359,24330,5.90,4.20,15.00,5.20 24360,24419,24390,4.20,4.10,14.60,5.10 24420,24479,24450,4.10,4.10,14.00,5.00 24480,24539,24510,5.30,4.20,13.30,5.00 24540,24599,24570,7.80,4.40,15.90,5.30 24600,24659,24630,5.60,4.20,12.80,4.90 24660,24719,24690,6.30,4.20,16.60,5.40 24720,24779,24750,5.30,4.20,15.00,5.20 24780,24839,24810,5.10,4.20,17.50,5.50 24840,24899,24870,1.70,4.00,18.10,5.60 24900,24959,24930,0.60,4.00,16.90,5.50 24960,25019,24990,0.10,4.00,12.20,4.80 25020,25079,25050,3.10,4.10,13.80,5.00 25080,25139,25110,3.60,4.10,14.30,5.10 25140,25199,25170,4.40,4.10,17.60,5.60 25200,25259,25230,4.50,4.10,16.60,5.40 25260,25319,25290,5.30,4.20,15.50,5.30 25320,25379,25350,8.50,4.40,18.80,5.70 25380,25439,25410,6.60,4.30,18.60,5.70 25440,25499,25470,6.50,4.20,20.40,6.00 25500,25559,25530,4.80,4.10,17.30,5.50 25560,25619,25590,6.30,4.20,16.00,5.30 25620,25679,25650,7.60,4.30,15.00,5.20 25680,25739,25710,8.50,4.40,18.00,5.60 25740,25799,25770,7.00,4.30,17.30,5.50 25800,25859,25830,5.10,4.20,17.60,5.60 25860,25919,25890,3.70,4.10,15.60,5.30 25920,25979,25950,4.40,4.10,17.10,5.50 25980,26039,26010,5.30,4.20,16.40,5.40 26040,26099,26070,5.10,4.20,14.90,5.20 26100,26159,26130,5.20,4.20,13.30,5.00 26160,26219,26190,6.30,4.20,14.20,5.10 26220,26279,26250,5.80,4.20,11.50,4.70 26280,26339,26310,6.50,4.20,13.20,4.90 26340,26399,26370,6.70,4.30,13.80,5.00 26400,26459,26430,8.50,4.40,16.90,5.50 26460,26519,26490,9.00,4.50,23.90,6.60 26520,26579,26550,4.40,4.10,23.30,6.50 26580,26639,26610,1.90,4.00,25.70,6.90 26640,26699,26670,1.40,4.00,23.50,6.50 26700,26759,26730,4.70,4.10,24.70,6.80 26760,26819,26790,9.50,4.50,24.20,6.70 26820,26879,26850,10.70,4.60,22.40,6.30 26880,26939,26910,12.50,4.90,28.30,7.40 26940,26999,26970,8.80,4.40,29.40,7.60 27000,27059,27030,7.00,4.30,30.40,7.80 27060,27119,27090,6.90,4.30,24.90,6.80 27120,27179,27150,9.70,4.50,24.70,6.80 27180,27239,27210,9.60,4.50,21.90,6.30 27240,27299,27270,8.00,4.40,29.90,7.70 27300,27359,27330,6.90,4.30,39.60,9.60 27360,27419,27390,7.60,4.30,40.50,9.80 27420,27479,27450,9.00,4.50,32.40,8.20 27480,27539,27510,7.80,4.30,24.00,6.60 27540,27599,27570,6.40,4.20,25.40,6.90 27600,27659,27630,6.00,4.20,28.20,7.40 27660,27719,27690,7.20,4.30,34.20,8.50 27720,27779,27750,9.40,4.50,32.50,8.20 27780,27839,27810,10.70,4.60,32.90,8.30 27840,27899,27870,11.40,4.70,28.20,7.40 27900,27959,27930,10.30,4.60,29.60,7.70 27960,28019,27990,8.60,4.40,27.40,7.20 28020,28079,28050,7.70,4.30,24.00,6.60 28080,28139,28110,8.00,4.40,24.00,6.60 28140,28199,28170,8.60,4.40,29.60,7.60 28200,28259,28230,7.00,4.30,31.50,8.00 28260,28319,28290,5.20,4.20,30.10,7.70 28320,28379,28350,5.80,4.20,27.00,7.20 28380,28439,28410,7.60,4.30,28.60,7.40 28440,28499,28470,9.50,4.50,30.60,7.80 28500,28559,28530,7.40,4.30,29.80,7.70 28560,28619,28590,8.10,4.40,32.40,8.20 28620,28679,28650,8.20,4.40,34.80,8.60 28680,28739,28710,10.60,4.60,34.80,8.60 28740,28799,28770,9.50,4.50,32.70,8.20 28800,28859,28830,9.50,4.50,30.90,7.90 28860,28919,28890,8.80,4.40,31.90,8.10 28920,28979,28950,9.40,4.50,33.10,8.30 28980,29039,29010,10.30,4.60,35.30,8.70 29040,29099,29070,10.80,4.60,34.50,8.60 29100,29159,29130,11.40,4.70,37.60,9.20 29160,29219,29190,12.50,4.90,47.90,11.30 29220,29279,29250,14.70,5.10,57.50,13.30 29280,29339,29310,17.00,5.50,65.70,15.00 29340,29399,29370,15.30,5.20,58.80,13.50 29400,29459,29430,15.00,5.20,62.90,14.40 29460,29519,29490,14.50,5.10,60.70,14.00 29520,29579,29550,15.40,5.20,62.10,14.20 29580,29639,29610,16.20,5.40,58.90,13.60 29640,29699,29670,16.30,5.40,57.80,13.30 29700,29759,29730,18.50,5.70,56.50,13.10 29760,29819,29790,20.60,6.00,59.00,13.60 29820,29879,29850,23.60,6.60,57.80,13.30 29880,29939,29910,26.10,7.00,60.70,13.90 29940,29999,29970,26.90,7.10,57.80,13.30 30000,30059,30030,25.70,6.90,58.30,13.40 30060,30119,30090,21.90,6.30,68.10,15.50 30120,30179,30150,19.50,5.90,76.30,17.30 30180,30239,30210,19.50,5.90,83.50,18.80 30240,30299,30270,23.70,6.60,80.20,18.10 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