49, 1001 Cantrell, Christopher A Atmospheric Chemistry Division/NESL/NCAR HO2 and HO2+RO2 from PeRCIMS at Manitou Experimental Forest BEACHON-RoMBAS 1,1 2011, 08, 01, 2011, 11, 19 0 Start_MST, seconds, number_of_seconds_from_0000_MST 6 1,1,1,1,1,1 -99999,-99999,-99999,-99999,-99999,-99999 Stop_MST, seconds, number_of_seconds_from_0000_MST Mid_MST, seconds, number_of_seconds_from_0000_MST HO2, pptv, HO2_mixing_ratio HO2_uncertainty, pptv, HO2_2_sigma_uncertainty HO2+RO2, pptv, HO2+RO2_mixing_ratio HO2+RO2_uncertainty, pptv, HO2+RO2_2_sigma_uncertainty 5 These data are reduced using four factors determined in the laboratory and in the field: F_lo and F_hi are the radical sensitivities in the HO2+RO2 and HO2 modes, respectively (units pptv/ion ratio). Alpha_lo and alpha_hi are the ratios of RO2 to HO2 sensitivity in the HO2+RO2 and HO2 modes, respectively. HO2+RO2 concentrations are then S_lo*F_lo-(S_lo*F_lo - S_hi*F_hi)*(alpha_lo - 1)/(alpha_lo - alpha_hi) . HO2 concentrations are S_lo*F_lo-(S_lo*F_lo - S_hi*F_hi)*(alpha_lo)/(alpha_lo - alpha_hi) . S_lo is the background corrected ion ratio in the HO2+RO2 mode, and S_hi is the background corrected ion ratio in the HO2 mode. The ion ratios are mass 97 signal count rate minus background count rate divided by mass 62 count rate. 24 PI_CONTACT_INFO: 303-497-1479, NCAR, 3090 Center Green Dr., Boulder, CO 80301, cantrell@ucar.edu PLATFORM: Seacontainer #1 LOCATION: Manitou Experimental Forest, Woodland Park, Colorado, USA ASSOCIATED_DATA: N/A INSTRUMENT_INFO: These data were collected using a CIMS based instrument. An inlet collects ambient air from the free air stream and adds reagents, includling O2 or N2 diluents, and NO and SO2 reagent gases. This method, called oxygen dilution modulation leads to nearly 100% measurement of HO2 and RO2 in the O2 dilution/low reagent concentration mode, whereas RO2 is measured with less than 15% efficiency in the N2 dilution/higher reagent concentration mode. This is because the chemistry converts peroxy radicals to H2SO4 efficiently in the O2 mode, but RO2 radicals are converted to RONO in the N2 mode. The H2SO4 thus produced is ionized by reaction with NO3- ions. The reagent and product ions are detected by mass spectrometry using quadrupole mass filtering and counting by a channel electron multiplier operating in the negative ion mode. DATA_INFO: Signal data for HO2+RO2 are collected during the 0-7 second time interval, and for HO2 in 30-37 second time interval. UNCERTAINTY: approximately 35% (2 sigma) for values well above 2 pptv; estimates are listed for each data point (2 sigma) ULOD_FLAG: -7777 ULOD_VALUE: N/A LLOD_FLAG: -8888 LLOD_VALUE: N/A DM_CONTACT_INFO: N/A PROJECT_INFO: BEACHON-RoMBAS, 20-Jul-2011 to 30-Aug-2011 STIPULATIONS_ON_USE: contact PI BEFORE use/presentation/publication OTHER_COMMENTS: REVISION: R1; R0 R1: final data R0: preliminary data Start_MST,Stop_MST,Mid_MST,HO2,HO2_uncertainty,HO2+RO2,HO2+RO2_uncertainty 0,59,30,6.60,4.30,11.50,4.70 60,119,90,6.80,4.30,12.50,4.80 120,179,150,7.40,4.30,15.70,5.30 180,239,210,6.60,4.30,18.70,5.70 240,299,270,4.90,4.10,21.30,6.20 300,359,330,4.10,4.10,14.20,5.10 360,419,390,4.30,4.10,10.30,4.60 420,479,450,4.80,4.10,8.00,4.40 480,539,510,3.60,4.10,15.60,5.30 540,599,570,5.90,4.20,20.70,6.10 600,659,630,7.90,4.40,19.20,5.80 660,719,690,8.90,4.50,15.90,5.30 720,779,750,7.10,4.30,12.70,4.90 780,839,810,6.10,4.20,13.80,5.00 840,899,870,6.00,4.20,15.70,5.30 900,959,930,5.50,4.20,14.70,5.10 960,1019,990,4.80,4.10,12.60,4.90 1020,1079,1050,3.50,4.10,8.40,4.40 1080,1139,1110,2.80,4.00,7.00,4.30 1140,1199,1170,3.70,4.10,9.60,4.50 1200,1259,1230,5.00,4.10,12.70,4.90 1260,1319,1290,5.40,4.20,15.20,5.20 1320,1379,1350,4.90,4.10,15.10,5.20 1380,1439,1410,5.20,4.20,15.90,5.30 1440,1499,1470,6.30,4.20,18.40,5.70 1500,1559,1530,6.90,4.30,19.80,5.90 1560,1619,1590,7.30,4.30,20.10,6.00 1620,1679,1650,7.30,4.30,18.60,5.70 1680,1739,1710,7.00,4.30,16.80,5.40 1740,1799,1770,6.20,4.20,16.30,5.40 1800,1859,1830,4.90,4.10,15.20,5.20 1860,1919,1890,4.30,4.10,15.40,5.20 1920,1979,1950,4.50,4.10,15.60,5.30 1980,2039,2010,5.20,4.20,16.90,5.50 2040,2099,2070,6.20,4.20,17.00,5.50 2100,2159,2130,6.30,4.20,16.60,5.40 2160,2219,2190,5.60,4.20,14.10,5.10 2220,2279,2250,5.60,4.20,15.10,5.20 2280,2339,2310,4.70,4.10,14.40,5.10 2340,2399,2370,4.50,4.10,16.10,5.30 2400,2459,2430,3.50,4.10,15.50,5.30 2460,2519,2490,3.70,4.10,16.00,5.30 2520,2579,2550,3.60,4.10,15.60,5.30 2580,2639,2610,4.30,4.10,13.70,5.00 2640,2699,2670,5.00,4.20,12.70,4.90 2700,2759,2730,5.00,4.10,13.30,5.00 2760,2819,2790,4.10,4.10,14.50,5.10 2820,2879,2850,4.10,4.10,15.30,5.20 2880,2939,2910,4.10,4.10,14.60,5.10 2940,2999,2970,2.90,4.10,12.20,4.80 3000,3059,3030,2.20,4.00,11.50,4.70 3060,3119,3090,1.90,4.00,11.90,4.80 3120,3179,3150,2.20,4.00,14.10,5.10 3180,3239,3210,2.60,4.00,12.70,4.90 3240,3299,3270,4.00,4.10,12.60,4.90 3300,3359,3330,4.80,4.10,10.50,4.60 3360,3419,3390,5.80,4.20,12.60,4.90 3420,3479,3450,4.70,4.10,10.50,4.60 3480,3539,3510,4.70,4.10,11.40,4.70 3540,3599,3570,4.00,4.10,13.50,5.00 3600,3659,3630,4.10,4.10,13.60,5.00 3660,3719,3690,5.50,4.20,16.20,5.40 3720,3779,3750,4.40,4.10,14.60,5.10 3780,3839,3810,5.50,4.20,17.30,5.50 3840,3899,3870,4.90,4.10,14.90,5.20 3900,3959,3930,4.50,4.10,12.70,4.90 3960,4019,3990,3.80,4.10,12.20,4.80 4020,4079,4050,4.00,4.10,12.70,4.90 4080,4139,4110,6.50,4.20,15.00,5.20 4140,4199,4170,5.70,4.20,11.90,4.80 4200,4259,4230,5.00,4.20,10.50,4.60 4260,4319,4290,4.00,4.10,8.40,4.40 4320,4379,4350,4.90,4.10,10.50,4.60 4380,4439,4410,4.90,4.10,11.70,4.80 4440,4499,4470,3.40,4.10,9.00,4.50 4500,4559,4530,8.10,4.40,14.00,5.00 4560,4619,4590,9.30,4.50,15.40,5.20 4620,4679,4650,10.90,4.70,18.00,5.60 4680,4739,4710,6.00,4.20,12.30,4.80 4740,4799,4770,5.90,4.20,10.10,4.60 4800,4859,4830,5.00,4.10,8.20,4.40 4860,4919,4890,5.00,4.20,10.40,4.60 4920,4979,4950,4.80,4.10,12.30,4.80 4980,5039,5010,5.20,4.20,14.80,5.20 5040,5099,5070,4.50,4.10,12.80,4.90 5100,5159,5130,3.00,4.10,12.30,4.80 5160,5219,5190,3.30,4.10,13.00,4.90 5220,5279,5250,4.30,4.10,12.60,4.90 5280,5339,5310,5.10,4.20,12.70,4.90 5340,5399,5370,4.90,4.10,13.50,5.00 5400,5459,5430,5.60,4.20,13.60,5.00 5460,5519,5490,7.00,4.30,13.60,5.00 5520,5579,5550,6.70,4.30,10.40,4.60 5580,5639,5610,6.00,4.20,12.80,4.90 5640,5699,5670,5.00,4.20,12.40,4.80 5700,5759,5730,5.00,4.10,14.90,5.20 5760,5819,5790,4.80,4.10,15.40,5.20 5820,5879,5850,4.50,4.10,16.60,5.40 5880,5939,5910,4.50,4.10,15.40,5.20 5940,5999,5970,4.80,4.10,15.10,5.20 6000,6059,6030,5.50,4.20,14.60,5.10 6060,6119,6090,6.20,4.20,13.40,5.00 6120,6179,6150,4.80,4.10,13.70,5.00 6180,6239,6210,4.20,4.10,12.50,4.90 6240,6299,6270,5.70,4.20,10.70,4.60 6300,6359,6330,7.50,4.30,10.90,4.70 6360,6419,6390,8.10,4.40,11.60,4.70 6420,6479,6450,5.90,4.20,18.80,5.70 6480,6539,6510,5.20,4.20,19.20,5.80 6540,6599,6570,4.70,4.10,19.60,5.90 6600,6659,6630,5.50,4.20,17.20,5.50 6660,6719,6690,5.00,4.10,15.00,5.20 6720,6779,6750,4.20,4.10,15.00,5.20 6780,6839,6810,3.30,4.10,13.70,5.00 6840,6899,6870,3.60,4.10,13.40,5.00 6900,6959,6930,4.60,4.10,13.80,5.00 6960,7019,6990,4.60,4.10,15.40,5.20 7020,7079,7050,4.50,4.10,17.10,5.50 7080,7139,7110,4.60,4.10,14.70,5.20 7140,7199,7170,5.80,4.20,11.90,4.80 7200,7259,7230,6.60,4.30,9.90,4.60 7260,7319,7290,6.60,4.30,11.20,4.70 7320,7379,7350,6.40,4.20,12.40,4.80 7380,7439,7410,5.50,4.20,12.60,4.90 7440,7499,7470,5.30,4.20,10.60,4.60 7500,7559,7530,4.70,4.10,10.40,4.60 7560,7619,7590,4.70,4.10,13.30,5.00 7620,7679,7650,4.40,4.10,15.30,5.20 7680,7739,7710,4.00,4.10,16.50,5.40 7740,7799,7770,4.30,4.10,14.30,5.10 7800,7859,7830,5.70,4.20,15.90,5.30 7860,7919,7890,6.90,4.30,13.30,5.00 7920,7979,7950,7.90,4.40,14.30,5.10 7980,8039,8010,5.40,4.20,13.50,5.00 8040,8099,8070,3.90,4.10,15.40,5.20 8100,8159,8130,2.30,4.00,14.70,5.10 8160,8219,8190,3.30,4.10,14.80,5.20 8220,8279,8250,3.00,4.10,14.90,5.20 8280,8339,8310,3.30,4.10,15.30,5.20 8340,8399,8370,3.60,4.10,15.40,5.20 8400,8459,8430,3.50,4.10,13.90,5.00 8460,8519,8490,3.40,4.10,13.10,4.90 8520,8579,8550,3.30,4.10,12.50,4.80 8580,8639,8610,3.90,4.10,15.00,5.20 8640,8699,8670,4.20,4.10,14.40,5.10 8700,8759,8730,5.00,4.10,14.20,5.10 8760,8819,8790,5.40,4.20,12.40,4.80 8820,8879,8850,5.30,4.20,12.70,4.90 8880,8939,8910,4.40,4.10,12.30,4.80 8940,8999,8970,4.50,4.10,11.70,4.80 9000,9059,9030,4.60,4.10,11.60,4.80 9060,9119,9090,4.10,4.10,11.90,4.80 9120,9179,9150,4.10,4.10,12.60,4.90 9180,9239,9210,4.50,4.10,13.70,5.00 9240,9299,9270,4.70,4.10,13.80,5.00 9300,9359,9330,4.60,4.10,15.40,5.20 9360,9419,9390,3.90,4.10,15.80,5.30 9420,9479,9450,3.90,4.10,16.10,5.30 9480,9539,9510,4.80,4.10,12.80,4.90 9540,9599,9570,5.40,4.20,11.00,4.70 9600,9659,9630,6.50,4.20,13.50,5.00 9660,9719,9690,5.70,4.20,16.00,5.30 9720,9779,9750,5.30,4.20,17.10,5.50 9780,9839,9810,4.10,4.10,14.40,5.10 9840,9899,9870,2.90,4.00,12.70,4.90 9900,9959,9930,2.00,4.00,12.30,4.80 9960,10019,9990,3.00,4.10,13.70,5.00 10020,10079,10050,4.30,4.10,16.00,5.30 10080,10139,10110,4.50,4.10,16.90,5.50 10140,10199,10170,3.40,4.10,16.90,5.50 10200,10259,10230,4.40,4.10,13.90,5.00 10260,10319,10290,7.00,4.30,15.40,5.20 10320,10379,10350,8.10,4.40,15.40,5.20 10380,10439,10410,6.60,4.30,16.00,5.30 10440,10499,10470,4.40,4.10,13.50,5.00 10500,10559,10530,3.50,4.10,13.30,5.00 10560,10619,10590,3.90,4.10,15.70,5.30 10620,10679,10650,4.70,4.10,14.70,5.10 10680,10739,10710,4.50,4.10,15.70,5.30 10740,10799,10770,5.60,4.20,9.30,4.50 10800,10859,10830,4.50,4.10,9.30,4.50 10860,10919,10890,5.40,4.20,7.10,4.30 10920,10979,10950,7.20,4.30,10.80,4.60 10980,11039,11010,8.80,4.40,11.60,4.70 11040,11099,11070,9.40,4.50,12.30,4.80 11100,11159,11130,8.10,4.40,16.20,5.40 11160,11219,11190,6.90,4.30,16.40,5.40 11220,11279,11250,5.60,4.20,15.60,5.30 11280,11339,11310,3.90,4.10,11.50,4.70 11340,11399,11370,4.70,4.10,10.00,4.60 11400,11459,11430,4.70,4.10,9.60,4.50 11460,11519,11490,5.70,4.20,8.90,4.40 11520,11579,11550,5.40,4.20,8.30,4.40 11580,11639,11610,7.50,4.30,9.50,4.50 11640,11699,11670,7.50,4.30,11.10,4.70 11700,11759,11730,7.80,4.40,12.90,4.90 11760,11819,11790,6.00,4.20,13.10,4.90 11820,11879,11850,4.50,4.10,13.90,5.00 11880,11939,11910,4.10,4.10,13.40,5.00 11940,11999,11970,4.20,4.10,11.80,4.80 12000,12059,12030,3.70,4.10,10.90,4.70 12060,12119,12090,3.50,4.10,10.50,4.60 12120,12179,12150,3.30,4.10,12.00,4.80 12180,12239,12210,3.70,4.10,11.50,4.70 12240,12299,12270,6.20,4.20,13.40,5.00 12300,12359,12330,6.80,4.30,12.40,4.80 12360,12419,12390,8.00,4.40,14.90,5.20 12420,12479,12450,6.30,4.20,17.10,5.50 12480,12539,12510,6.70,4.30,23.10,6.50 12540,12599,12570,6.50,4.20,21.80,6.20 12600,12659,12630,9.60,4.50,19.40,5.80 12660,12719,12690,9.60,4.50,15.60,5.30 12720,12779,12750,8.60,4.40,14.40,5.10 12780,12839,12810,5.20,4.20,14.10,5.10 12840,12899,12870,9.20,4.50,11.90,4.80 12900,12959,12930,12.10,4.80,13.10,4.90 12960,13019,12990,11.60,4.70,11.30,4.70 13020,13079,13050,7.50,4.30,10.60,4.60 13080,13139,13110,7.10,4.30,11.90,4.80 13140,13199,13170,7.00,4.30,13.70,5.00 13200,13259,13230,6.10,4.20,10.90,4.70 13260,13319,13290,7.70,4.30,5.70,4.20 13320,13379,13350,7.30,4.30,6.60,4.30 13380,13439,13410,7.10,4.30,10.10,4.60 13440,13499,13470,3.30,4.10,16.60,5.40 13500,13559,13530,4.80,4.10,15.00,5.20 13560,13619,13590,5.50,4.20,15.60,5.30 13620,13679,13650,6.40,4.20,14.00,5.00 13680,13739,13710,6.00,4.20,11.30,4.70 13740,13799,13770,4.90,4.10,10.20,4.60 13800,13859,13830,3.20,4.10,10.60,4.60 13860,13919,13890,1.80,4.00,14.60,5.10 13920,13979,13950,2.00,4.00,15.00,5.20 13980,14039,14010,1.60,4.00,14.20,5.10 14040,14099,14070,2.60,4.00,12.70,4.90 14100,14159,14130,3.10,4.10,14.30,5.10 14160,14219,14190,3.80,4.10,13.00,4.90 14220,14279,14250,4.20,4.10,13.80,5.00 14280,14339,14310,4.20,4.10,12.90,4.90 14340,14399,14370,3.90,4.10,11.00,4.70 14400,14459,14430,5.60,4.20,9.10,4.50 14460,14519,14490,10.60,4.60,10.70,4.60 14520,14579,14550,15.00,5.20,14.60,5.10 14580,14639,14610,15.20,5.20,18.30,5.70 14640,14699,14670,10.90,4.70,13.40,5.00 14700,14759,14730,8.10,4.40,13.40,5.00 14760,14819,14790,7.50,4.30,7.40,4.30 14820,14879,14850,5.70,4.20,9.40,4.50 14880,14939,14910,5.40,4.20,8.20,4.40 14940,14999,14970,2.90,4.10,14.40,5.10 15000,15059,15030,3.20,4.10,17.10,5.50 15060,15119,15090,3.10,4.10,18.20,5.70 15120,15179,15150,4.60,4.10,17.10,5.50 15180,15239,15210,3.90,4.10,16.50,5.40 15240,15299,15270,4.90,4.10,17.10,5.50 15300,15359,15330,3.90,4.10,17.10,5.50 15360,15419,15390,4.50,4.10,16.40,5.40 15420,15479,15450,2.90,4.10,13.50,5.00 15480,15539,15510,3.60,4.10,12.00,4.80 15540,15599,15570,3.20,4.10,11.70,4.80 15600,15659,15630,3.00,4.10,13.20,4.90 15660,15719,15690,2.30,4.00,14.90,5.20 15720,15779,15750,1.70,4.00,13.90,5.00 15780,15839,15810,2.30,4.00,13.30,5.00 15840,15899,15870,3.50,4.10,12.30,4.80 15900,15959,15930,5.30,4.20,13.60,5.00 15960,16019,15990,4.60,4.10,15.00,5.20 16020,16079,16050,3.40,4.10,12.80,4.90 16080,16139,16110,2.40,4.00,12.00,4.80 16140,16199,16170,2.80,4.00,11.10,4.70 16200,16259,16230,4.60,4.10,12.10,4.80 16260,16319,16290,6.00,4.20,14.80,5.20 16320,16379,16350,4.40,4.10,13.60,5.00 16380,16439,16410,2.90,4.10,16.10,5.30 16440,16499,16470,0.90,4.00,13.60,5.00 16500,16559,16530,2.60,4.00,15.40,5.20 16560,16619,16590,2.40,4.00,13.30,5.00 16620,16679,16650,2.30,4.00,13.30,5.00 16680,16739,16710,1.80,4.00,16.70,5.40 16740,16799,16770,2.20,4.00,19.10,5.80 16800,16859,16830,3.80,4.10,19.20,5.80 16860,16919,16890,5.30,4.20,14.40,5.10 16920,16979,16950,5.90,4.20,11.90,4.80 16980,17039,17010,5.60,4.20,11.10,4.70 17040,17099,17070,5.80,4.20,11.90,4.80 17100,17159,17130,7.50,4.30,15.00,5.20 17160,17219,17190,9.20,4.50,17.20,5.50 17220,17279,17250,4.20,4.10,15.30,5.20 17280,17339,17310,2.40,4.00,7.80,4.40 17340,17399,17370,1.60,4.00,7.90,4.40 17400,17459,17430,12.60,4.90,9.10,4.50 17460,17519,17490,12.90,4.90,13.90,5.00 17520,17579,17550,12.10,4.80,13.10,4.90 17580,17639,17610,4.90,4.10,13.30,5.00 17640,17699,17670,4.00,4.10,13.80,5.00 17700,17759,17730,3.30,4.10,14.60,5.10 17760,17819,17790,2.70,4.00,15.40,5.20 17820,17879,17850,2.30,4.00,14.70,5.10 17880,17939,17910,3.00,4.10,14.30,5.10 17940,17999,17970,2.80,4.00,11.60,4.70 18000,18059,18030,3.20,4.10,10.20,4.60 18060,18119,18090,3.50,4.10,9.60,4.50 18120,18179,18150,4.00,4.10,11.30,4.70 18180,18239,18210,3.90,4.10,13.00,4.90 18240,18299,18270,3.30,4.10,12.60,4.90 18300,18359,18330,3.60,4.10,11.80,4.80 18360,18419,18390,4.50,4.10,10.30,4.60 18420,18479,18450,7.40,4.30,12.50,4.90 18480,18539,18510,7.90,4.40,14.20,5.10 18540,18599,18570,5.90,4.20,12.80,4.90 18600,18659,18630,4.40,4.10,12.00,4.80 18660,18719,18690,3.60,4.10,11.70,4.80 18720,18779,18750,5.10,4.20,14.30,5.10 18780,18839,18810,4.30,4.10,13.60,5.00 18840,18899,18870,3.80,4.10,12.70,4.90 18900,18959,18930,4.20,4.10,16.40,5.40 18960,19019,18990,3.50,4.10,17.10,5.50 19020,19079,19050,5.10,4.20,19.40,5.80 19080,19139,19110,4.60,4.10,14.40,5.10 19140,19199,19170,6.70,4.30,10.50,4.60 19200,19259,19230,8.10,4.40,12.00,4.80 19260,19319,19290,7.80,4.40,12.30,4.80 19320,19379,19350,7.30,4.30,15.10,5.20 19380,19439,19410,7.00,4.30,17.10,5.50 19440,19499,19470,7.40,4.30,17.70,5.60 19500,19559,19530,4.70,4.10,16.40,5.40 19560,19619,19590,2.10,4.00,12.20,4.80 19620,19679,19650,2.00,4.00,18.80,5.80 19680,19739,19710,3.70,4.10,20.50,6.00 19740,19799,19770,3.30,4.10,19.60,5.90 19800,19859,19830,2.50,4.00,11.90,4.80 19860,19919,19890,1.30,4.00,9.70,4.50 19920,19979,19950,3.00,4.10,11.20,4.70 19980,20039,20010,1.70,4.00,14.10,5.10 20040,20099,20070,1.50,4.00,18.30,5.70 20100,20159,20130,1.60,4.00,21.40,6.20 20160,20219,20190,3.70,4.10,21.10,6.10 20220,20279,20250,4.30,4.10,18.10,5.70 20280,20339,20310,5.20,4.20,16.60,5.40 20340,20399,20370,5.50,4.20,16.50,5.40 20400,20459,20430,4.90,4.10,16.00,5.30 20460,20519,20490,3.30,4.10,13.50,5.00 20520,20579,20550,3.60,4.10,10.80,4.70 20580,20639,20610,5.80,4.20,16.10,5.30 20640,20699,20670,5.90,4.20,14.80,5.20 20700,20759,20730,5.90,4.20,15.60,5.30 20760,20819,20790,4.90,4.10,11.00,4.70 20820,20879,20850,3.60,4.10,16.00,5.30 20880,20939,20910,2.90,4.10,19.50,5.90 20940,20999,20970,3.20,4.10,21.70,6.20 21000,21059,21030,4.20,4.10,18.00,5.60 21060,21119,21090,4.00,4.10,17.50,5.60 21120,21179,21150,2.40,4.00,16.80,5.50 21180,21239,21210,2.50,4.00,16.70,5.40 21240,21299,21270,2.60,4.00,15.30,5.20 21300,21359,21330,3.40,4.10,14.00,5.00 21360,21419,21390,3.40,4.10,14.20,5.10 21420,21479,21450,5.70,4.20,15.30,5.20 21480,21539,21510,6.20,4.20,16.90,5.50 21540,21599,21570,6.30,4.20,16.00,5.30 21600,21659,21630,4.40,4.10,22.10,6.30 21660,21719,21690,4.50,4.10,22.00,6.30 21720,21779,21750,5.00,4.10,24.00,6.60 21780,21839,21810,5.70,4.20,18.70,5.70 21840,21899,21870,6.00,4.20,18.30,5.70 21900,21959,21930,6.00,4.20,17.40,5.50 21960,22019,21990,5.10,4.20,15.60,5.30 22020,22079,22050,4.90,4.10,17.20,5.50 22080,22139,22110,4.40,4.10,17.40,5.50 22140,22199,22170,4.50,4.10,16.40,5.40 22200,22259,22230,3.90,4.10,16.40,5.40 22260,22319,22290,4.10,4.10,15.10,5.20 22320,22379,22350,5.50,4.20,17.50,5.50 22380,22439,22410,5.90,4.20,17.00,5.50 22440,22499,22470,5.50,4.20,17.90,5.60 22500,22559,22530,4.90,4.10,17.90,5.60 22560,22619,22590,5.10,4.20,20.70,6.10 22620,22679,22650,4.60,4.10,19.60,5.90 22680,22739,22710,4.20,4.10,21.90,6.30 22740,22799,22770,3.80,4.10,21.30,6.20 22800,22859,22830,4.70,4.10,23.60,6.50 22860,22919,22890,5.40,4.20,23.40,6.50 22920,22979,22950,5.30,4.20,23.50,6.50 22980,23039,23010,4.60,4.10,26.40,7.10 23040,23099,23070,4.40,4.10,26.30,7.00 23100,23159,23130,5.80,4.20,28.30,7.40 23160,23219,23190,6.90,4.30,30.50,7.80 23220,23279,23250,6.70,4.30,35.00,8.70 23280,23339,23310,6.40,4.20,32.50,8.20 23340,23399,23370,6.30,4.20,29.70,7.70 23400,23459,23430,6.10,4.20,27.20,7.20 23460,23519,23490,4.90,4.10,31.40,8.00 23520,23579,23550,4.30,4.10,36.20,8.90 23580,23639,23610,5.30,4.20,35.30,8.70 23640,23699,23670,5.30,4.20,39.60,9.60 23700,23759,23730,7.40,4.30,34.10,8.50 23760,23819,23790,7.50,4.30,33.20,8.30 23820,23879,23850,8.70,4.40,27.10,7.20 23880,23939,23910,6.20,4.20,24.50,6.70 23940,23999,23970,4.80,4.10,24.60,6.70 24000,24059,24030,3.70,4.10,23.10,6.50 24060,24119,24090,3.40,4.10,22.70,6.40 24120,24179,24150,4.50,4.10,24.60,6.70 24180,24239,24210,5.20,4.20,22.70,6.40 24240,24299,24270,6.30,4.20,29.90,7.70 24300,24359,24330,7.10,4.30,33.00,8.30 24360,24419,24390,7.20,4.30,35.40,8.80 24420,24479,24450,8.10,4.40,31.60,8.00 24480,24539,24510,7.20,4.30,28.30,7.40 24540,24599,24570,6.80,4.30,28.50,7.40 24600,24659,24630,6.10,4.20,30.70,7.90 24660,24719,24690,6.40,4.20,27.00,7.20 24720,24779,24750,8.40,4.40,26.90,7.10 24780,24839,24810,9.80,4.50,25.00,6.80 24840,24899,24870,10.00,4.60,26.70,7.10 24900,24959,24930,8.20,4.40,24.40,6.70 24960,25019,24990,7.70,4.30,29.20,7.60 25020,25079,25050,6.60,4.30,32.50,8.20 25080,25139,25110,7.30,4.30,33.40,8.40 25140,25199,25170,6.80,4.30,31.30,8.00 25200,25259,25230,7.00,4.30,26.30,7.00 25260,25319,25290,7.80,4.40,26.20,7.00 25320,25379,25350,7.80,4.40,26.40,7.10 25380,25439,25410,8.20,4.40,33.60,8.40 25440,25499,25470,6.60,4.30,41.90,10.00 25500,25559,25530,7.40,4.30,43.70,10.40 25560,25619,25590,8.30,4.40,42.60,10.20 25620,25679,25650,9.60,4.50,37.70,9.20 25680,25739,25710,8.80,4.40,39.00,9.50 25740,25799,25770,8.10,4.40,37.80,9.20 25800,25859,25830,8.60,4.40,33.70,8.40 25860,25919,25890,9.70,4.50,32.50,8.20 25920,25979,25950,10.60,4.60,36.90,9.00 25980,26039,26010,10.10,4.60,43.50,10.40 26040,26099,26070,9.90,4.60,40.30,9.70 26100,26159,26130,9.80,4.50,33.40,8.40 26160,26219,26190,9.90,4.60,28.30,7.40 26220,26279,26250,9.70,4.50,24.10,6.60 26280,26339,26310,10.20,4.60,27.30,7.20 26340,26399,26370,14.10,5.10,34.90,8.70 26400,26459,26430,12.70,4.90,40.40,9.80 26460,26519,26490,12.90,4.90,41.20,9.90 26520,26579,26550,10.30,4.60,37.10,9.10 26580,26639,26610,11.60,4.70,36.70,9.00 26640,26699,26670,11.80,4.80,31.60,8.00 26700,26759,26730,11.20,4.70,29.70,7.70 26760,26819,26790,11.60,4.70,33.10,8.30 26820,26879,26850,11.00,4.70,39.90,9.60 26880,26939,26910,9.30,4.50,43.00,10.30 26940,26999,26970,9.60,4.50,41.20,9.90 27000,27059,27030,9.90,4.60,35.70,8.80 27060,27119,27090,13.20,4.90,37.70,9.20 27120,27179,27150,12.00,4.80,35.70,8.80 27180,27239,27210,12.80,4.90,39.70,9.60 27240,27299,27270,11.10,4.70,38.90,9.50 27300,27359,27330,14.20,5.10,40.00,9.70 27360,27419,27390,15.10,5.20,36.90,9.10 27420,27479,27450,15.00,5.20,33.70,8.40 27480,27539,27510,14.80,5.20,34.50,8.60 27540,27599,27570,15.90,5.30,40.40,9.80 27600,27659,27630,16.90,5.50,42.80,10.20 27660,27719,27690,14.20,5.10,44.70,10.60 27720,27779,27750,14.10,5.10,40.40,9.70 27780,27839,27810,13.50,5.00,37.30,9.10 27840,27899,27870,17.60,5.60,41.60,10.00 27900,27959,27930,15.30,5.20,44.40,10.60 27960,28019,27990,14.00,5.10,46.90,11.10 28020,28079,28050,12.30,4.80,41.10,9.90 28080,28139,28110,10.60,4.60,37.70,9.20 28140,28199,28170,13.50,5.00,40.10,9.70 28200,28259,28230,14.10,5.10,40.50,9.80 28260,28319,28290,18.60,5.70,45.00,10.70 28320,28379,28350,20.30,6.00,42.50,10.20 28380,28439,28410,21.60,6.20,42.50,10.20 28440,28499,28470,20.00,5.90,40.80,9.80 28500,28559,28530,18.00,5.60,40.40,9.80 28560,28619,28590,17.00,5.50,36.20,8.90 28620,28679,28650,17.60,5.60,37.00,9.10 28680,28739,28710,19.50,5.90,39.50,9.60 28740,28799,28770,16.90,5.50,41.80,10.00 28800,28859,28830,15.80,5.30,39.20,9.50 28860,28919,28890,15.60,5.30,38.90,9.40 28920,28979,28950,20.70,6.10,41.60,10.00 28980,29039,29010,18.90,5.80,45.00,10.70 29040,29099,29070,17.30,5.50,46.00,10.90 29100,29159,29130,14.80,5.20,48.40,11.40 29160,29219,29190,18.10,5.60,48.30,11.40 29220,29279,29250,19.00,5.80,51.30,12.00 29280,29339,29310,19.20,5.80,48.40,11.40 29340,29399,29370,19.60,5.90,52.20,12.20 29400,29459,29430,21.20,6.10,51.00,11.90 29460,29519,29490,22.40,6.30,54.80,12.70 29520,29579,29550,19.90,5.90,52.50,12.20 29580,29639,29610,16.60,5.40,50.80,11.90 29640,29699,29670,15.50,5.30,49.50,11.60 29700,29759,29730,16.00,5.30,48.10,11.30 29760,29819,29790,17.80,5.60,48.50,11.40 29820,29879,29850,18.30,5.70,50.10,11.70 29880,29939,29910,22.40,6.40,45.90,10.90 29940,29999,29970,21.90,6.30,47.30,11.20 30000,30059,30030,23.90,6.60,51.60,12.00 30060,30119,30090,22.10,6.30,59.80,13.70 30120,30179,30150,23.40,6.50,59.80,13.80 30180,30239,30210,22.20,6.30,58.80,13.50 30240,30299,30270,21.90,6.30,62.10,14.20 30300,30359,30330,26.60,7.10,71.70,16.30 30360,30419,30390,29.40,7.60,77.20,17.40 30420,30479,30450,30.70,7.90,76.20,17.20 30480,30539,30510,26.10,7.00,69.10,15.70 30540,30599,30570,23.70,6.60,66.50,15.20 30600,30659,30630,27.30,7.20,62.60,14.30 30660,30719,30690,30.50,7.80,64.20,14.70 30720,30779,30750,34.20,8.50,61.60,14.10 30780,30839,30810,37.80,9.20,65.50,14.90 30840,30899,30870,37.60,9.20,70.00,15.90 30900,30959,30930,37.70,9.20,74.00,16.80 30960,31019,30990,34.70,8.60,78.70,17.80 31020,31079,31050,34.20,8.50,69.90,15.90 31080,31139,31110,37.80,9.20,74.60,16.90 31140,31199,31170,35.50,8.80,75.10,17.00 31200,31259,31230,38.70,9.40,86.20,19.40 31260,31319,31290,36.60,9.00,81.90,18.40 31320,31379,31350,35.60,8.80,78.10,17.60 31380,31439,31410,31.40,8.00,83.00,18.70 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