49, 1001 Cantrell, Christopher A Atmospheric Chemistry Division/NESL/NCAR HO2 and HO2+RO2 from PeRCIMS at Manitou Experimental Forest BEACHON-RoMBAS 1,1 2011, 07, 28, 2011, 11, 19 0 Start_MST, seconds, number_of_seconds_from_0000_MST 6 1,1,1,1,1,1 -99999,-99999,-99999,-99999,-99999,-99999 Stop_MST, seconds, number_of_seconds_from_0000_MST Mid_MST, seconds, number_of_seconds_from_0000_MST HO2, pptv, HO2_mixing_ratio HO2_uncertainty, pptv, HO2_2_sigma_uncertainty HO2+RO2, pptv, HO2+RO2_mixing_ratio HO2+RO2_uncertainty, pptv, HO2+RO2_2_sigma_uncertainty 5 These data are reduced using four factors determined in the laboratory and in the field: F_lo and F_hi are the radical sensitivities in the HO2+RO2 and HO2 modes, respectively (units pptv/ion ratio). Alpha_lo and alpha_hi are the ratios of RO2 to HO2 sensitivity in the HO2+RO2 and HO2 modes, respectively. HO2+RO2 concentrations are then S_lo*F_lo-(S_lo*F_lo - S_hi*F_hi)*(alpha_lo - 1)/(alpha_lo - alpha_hi) . HO2 concentrations are S_lo*F_lo-(S_lo*F_lo - S_hi*F_hi)*(alpha_lo)/(alpha_lo - alpha_hi) . S_lo is the background corrected ion ratio in the HO2+RO2 mode, and S_hi is the background corrected ion ratio in the HO2 mode. The ion ratios are mass 97 signal count rate minus background count rate divided by mass 62 count rate. 24 PI_CONTACT_INFO: 303-497-1479, NCAR, 3090 Center Green Dr., Boulder, CO 80301, cantrell@ucar.edu PLATFORM: Seacontainer #1 LOCATION: Manitou Experimental Forest, Woodland Park, Colorado, USA ASSOCIATED_DATA: N/A INSTRUMENT_INFO: These data were collected using a CIMS based instrument. An inlet collects ambient air from the free air stream and adds reagents, includling O2 or N2 diluents, and NO and SO2 reagent gases. This method, called oxygen dilution modulation leads to nearly 100% measurement of HO2 and RO2 in the O2 dilution/low reagent concentration mode, whereas RO2 is measured with less than 15% efficiency in the N2 dilution/higher reagent concentration mode. This is because the chemistry converts peroxy radicals to H2SO4 efficiently in the O2 mode, but RO2 radicals are converted to RONO in the N2 mode. The H2SO4 thus produced is ionized by reaction with NO3- ions. The reagent and product ions are detected by mass spectrometry using quadrupole mass filtering and counting by a channel electron multiplier operating in the negative ion mode. DATA_INFO: Signal data for HO2+RO2 are collected during the 0-7 second time interval, and for HO2 in 30-37 second time interval. UNCERTAINTY: approximately 35% (2 sigma) for values well above 2 pptv; estimates are listed for each data point (2 sigma) ULOD_FLAG: -7777 ULOD_VALUE: N/A LLOD_FLAG: -8888 LLOD_VALUE: N/A DM_CONTACT_INFO: N/A PROJECT_INFO: BEACHON-RoMBAS, 20-Jul-2011 to 30-Aug-2011 STIPULATIONS_ON_USE: contact PI BEFORE use/presentation/publication OTHER_COMMENTS: REVISION: R1; R0 R1: final data R0: preliminary data Start_MST,Stop_MST,Mid_MST,HO2,HO2_uncertainty,HO2+RO2,HO2+RO2_uncertainty 0,59,30,0.20,4.00,11.20,4.70 60,119,90,0.50,4.00,11.30,4.70 120,179,150,0.70,4.00,8.60,4.40 180,239,210,2.90,4.10,9.40,4.50 240,299,270,3.60,4.10,8.40,4.40 300,359,330,4.30,4.10,10.40,4.60 360,419,390,3.10,4.10,9.90,4.60 420,479,450,3.10,4.10,10.60,4.60 480,539,510,3.10,4.10,11.90,4.80 540,599,570,2.20,4.00,10.50,4.60 600,659,630,1.40,4.00,10.90,4.70 660,719,690,1.10,4.00,8.40,4.40 720,779,750,2.10,4.00,7.60,4.30 780,839,810,3.60,4.10,6.40,4.20 840,899,870,3.30,4.10,7.30,4.30 900,959,930,3.10,4.10,8.40,4.40 960,1019,990,1.90,4.00,9.90,4.60 1020,1079,1050,1.70,4.00,9.00,4.50 1080,1139,1110,2.40,4.00,11.70,4.80 1140,1199,1170,1.90,4.00,10.90,4.70 1200,1259,1230,2.60,4.00,12.70,4.90 1260,1319,1290,1.50,4.00,9.50,4.50 1320,1379,1350,3.20,4.10,9.70,4.50 1380,1439,1410,3.70,4.10,10.00,4.60 1440,1499,1470,5.80,4.20,13.30,4.90 1500,1559,1530,5.50,4.20,11.00,4.70 1560,1619,1590,5.60,4.20,11.40,4.70 1620,1679,1650,3.80,4.10,8.30,4.40 1680,1739,1710,3.50,4.10,11.10,4.70 1740,1799,1770,3.10,4.10,11.30,4.70 1800,1859,1830,3.50,4.10,10.90,4.70 1860,1919,1890,3.80,4.10,9.70,4.50 1920,1979,1950,3.30,4.10,8.20,4.40 1980,2039,2010,1.30,4.00,7.00,4.30 2040,2099,2070,1.00,4.00,9.20,4.50 2100,2159,2130,2.00,4.00,10.60,4.60 2160,2219,2190,4.60,4.10,13.30,5.00 2220,2279,2250,5.10,4.20,12.60,4.90 2280,2339,2310,4.10,4.10,11.40,4.70 2340,2399,2370,3.70,4.10,11.20,4.70 2400,2459,2430,4.00,4.10,10.30,4.60 2460,2519,2490,3.60,4.10,9.70,4.50 2520,2579,2550,3.60,4.10,8.10,4.40 2580,2639,2610,3.40,4.10,9.30,4.50 2640,2699,2670,4.70,4.10,11.30,4.70 2700,2759,2730,4.80,4.10,13.50,5.00 2760,2819,2790,4.60,4.10,12.60,4.90 2820,2879,2850,4.60,4.10,11.70,4.80 2880,2939,2910,5.00,4.10,10.60,4.60 2940,2999,2970,5.40,4.20,10.10,4.60 3000,3059,3030,3.60,4.10,11.00,4.70 3060,3119,3090,2.10,4.00,12.20,4.80 3120,3179,3150,1.50,4.00,13.40,5.00 3180,3239,3210,3.30,4.10,11.80,4.80 3240,3299,3270,4.00,4.10,12.30,4.80 3300,3359,3330,3.20,4.10,9.30,4.50 3360,3419,3390,2.30,4.00,10.40,4.60 3420,3479,3450,2.30,4.00,7.90,4.40 3480,3539,3510,3.80,4.10,11.70,4.80 3540,3599,3570,5.30,4.20,10.40,4.60 3600,3659,3630,5.10,4.20,9.70,4.50 3660,3719,3690,4.80,4.10,6.40,4.20 3720,3779,3750,3.30,4.10,6.50,4.20 3780,3839,3810,2.00,4.00,7.70,4.30 3840,3899,3870,1.00,4.00,9.30,4.50 3900,3959,3930,1.10,4.00,10.10,4.60 3960,4019,3990,2.10,4.00,10.30,4.60 4020,4079,4050,2.40,4.00,9.60,4.50 4080,4139,4110,2.30,4.00,9.00,4.50 4140,4199,4170,2.40,4.00,8.80,4.40 4200,4259,4230,2.20,4.00,8.80,4.40 4260,4319,4290,1.50,4.00,8.80,4.40 4320,4379,4350,0.70,4.00,8.50,4.40 4380,4439,4410,0.30,4.00,7.80,4.40 4440,4499,4470,0.70,4.00,7.60,4.30 4500,4559,4530,1.10,4.00,8.10,4.40 4560,4619,4590,1.20,4.00,9.40,4.50 4620,4679,4650,1.30,4.00,10.40,4.60 4680,4739,4710,1.50,4.00,10.90,4.70 4740,4799,4770,1.80,4.00,11.90,4.80 4800,4859,4830,1.90,4.00,11.20,4.70 4860,4919,4890,1.50,4.00,11.00,4.70 4920,4979,4950,1.40,4.00,9.10,4.50 4980,5039,5010,1.00,4.00,10.60,4.60 5040,5099,5070,2.00,4.00,8.20,4.40 5100,5159,5130,2.00,4.00,7.10,4.30 5160,5219,5190,2.70,4.00,5.10,4.20 5220,5279,5250,2.40,4.00,7.00,4.30 5280,5339,5310,3.60,4.10,10.00,4.60 5340,5399,5370,3.90,4.10,11.90,4.80 5400,5459,5430,3.30,4.10,12.10,4.80 5460,5519,5490,2.80,4.00,10.00,4.60 5520,5579,5550,3.30,4.10,8.40,4.40 5580,5639,5610,4.50,4.10,10.10,4.60 5640,5699,5670,4.50,4.10,10.50,4.60 5700,5759,5730,3.40,4.10,12.20,4.80 5760,5819,5790,2.60,4.00,10.30,4.60 5820,5879,5850,2.80,4.00,10.90,4.70 5880,5939,5910,4.20,4.10,11.80,4.80 5940,5999,5970,3.50,4.10,11.60,4.70 6000,6059,6030,2.00,4.00,11.10,4.70 6060,6119,6090,1.30,4.00,8.10,4.40 6120,6179,6150,1.70,4.00,7.70,4.30 6180,6239,6210,3.30,4.10,7.40,4.30 6240,6299,6270,2.60,4.00,8.90,4.50 6300,6359,6330,2.70,4.00,9.70,4.50 6360,6419,6390,2.80,4.00,8.70,4.40 6420,6479,6450,4.10,4.10,9.80,4.50 6480,6539,6510,4.40,4.10,9.00,4.50 6540,6599,6570,3.50,4.10,11.10,4.70 6600,6659,6630,2.50,4.00,8.50,4.40 6660,6719,6690,2.60,4.00,9.90,4.60 6720,6779,6750,2.70,4.00,9.30,4.50 6780,6839,6810,2.50,4.00,9.90,4.60 6840,6899,6870,1.90,4.00,8.40,4.40 6900,6959,6930,2.20,4.00,9.20,4.50 6960,7019,6990,2.00,4.00,6.50,4.30 7020,7079,7050,2.00,4.00,6.30,4.20 7080,7139,7110,0.70,4.00,3.70,4.10 7140,7199,7170,0.50,4.00,4.40,4.10 7200,7259,7230,0.20,4.00,5.20,4.20 7260,7319,7290,0.70,4.00,4.40,4.10 7320,7379,7350,1.30,4.00,5.70,4.20 7380,7439,7410,1.20,4.00,5.00,4.10 7440,7499,7470,2.00,4.00,7.70,4.30 7500,7559,7530,2.40,4.00,9.40,4.50 7560,7619,7590,3.10,4.10,8.70,4.40 7620,7679,7650,3.00,4.10,7.50,4.30 7680,7739,7710,3.40,4.10,5.20,4.20 7740,7799,7770,3.70,4.10,5.40,4.20 7800,7859,7830,2.90,4.00,5.50,4.20 7860,7919,7890,2.60,4.00,5.80,4.20 7920,7979,7950,2.80,4.00,5.30,4.20 7980,8039,8010,3.30,4.10,5.50,4.20 8040,8099,8070,2.90,4.10,5.80,4.20 8100,8159,8130,2.50,4.00,7.60,4.30 8160,8219,8190,2.10,4.00,4.20,4.10 8220,8279,8250,2.50,4.00,5.70,4.20 8280,8339,8310,3.50,4.10,7.40,4.30 8340,8399,8370,3.90,4.10,10.60,4.60 8400,8459,8430,2.80,4.00,6.90,4.30 8460,8519,8490,0.90,4.00,6.20,4.20 8520,8579,8550,0.60,4.00,3.70,4.10 8580,8639,8610,0.90,4.00,8.10,4.40 8640,8699,8670,2.50,4.00,5.40,4.20 8700,8759,8730,4.40,4.10,5.80,4.20 8760,8819,8790,4.20,4.10,5.80,4.20 8820,8879,8850,0.80,4.00,4.00,4.10 8880,8939,8910,1.20,4.00,5.50,4.20 8940,8999,8970,3.00,4.10,4.00,4.10 9000,9059,9030,3.90,4.10,4.30,4.10 9060,9119,9090,0.80,4.00,3.30,4.10 9120,9179,9150,0.80,4.00,3.40,4.10 9180,9239,9210,2.80,4.00,5.60,4.20 9240,9299,9270,3.90,4.10,6.30,4.20 9300,9359,9330,1.60,4.00,2.60,4.00 9360,9419,9390,0.80,4.00,2.50,4.00 9420,9479,9450,0.30,4.00,1.50,4.00 9480,9539,9510,3.00,4.10,5.50,4.20 9540,9599,9570,4.20,4.10,4.10,4.10 9600,9659,9630,3.50,4.10,5.60,4.20 9660,9719,9690,1.60,4.00,4.10,4.10 9720,9779,9750,-0.10,4.00,8.40,4.40 9780,9839,9810,1.00,4.00,9.50,4.50 9840,9899,9870,1.30,4.00,9.50,4.50 9900,9959,9930,1.70,4.00,5.30,4.20 9960,10019,9990,1.10,4.00,4.00,4.10 10020,10079,10050,0.60,4.00,4.80,4.10 10080,10139,10110,0.00,4.00,5.80,4.20 10140,10199,10170,2.90,4.10,5.90,4.20 10200,10259,10230,2.10,4.00,3.90,4.10 10260,10319,10290,1.60,4.00,5.00,4.10 10320,10379,10350,1.00,4.00,9.60,4.50 10380,10439,10410,1.50,4.00,12.20,4.80 10440,10499,10470,3.00,4.10,11.10,4.70 10500,10559,10530,1.60,4.00,8.10,4.40 10560,10619,10590,0.80,4.00,4.90,4.10 10620,10679,10650,0.50,4.00,3.10,4.10 10680,10739,10710,1.20,4.00,0.00,4.00 10740,10799,10770,3.60,4.10,3.30,4.10 10800,10859,10830,3.40,4.10,2.90,4.10 10860,10919,10890,1.90,4.00,1.20,4.00 10920,10979,10950,1.80,4.00,-1.60,4.00 10980,11039,11010,2.80,4.00,0.30,4.00 11040,11099,11070,3.50,4.10,4.10,4.10 11100,11159,11130,2.30,4.00,7.50,4.30 11160,11219,11190,1.50,4.00,9.40,4.50 11220,11279,11250,0.40,4.00,10.40,4.60 11280,11339,11310,-0.50,4.00,9.80,4.50 11340,11399,11370,0.20,4.00,3.90,4.10 11400,11459,11430,2.80,4.00,3.00,4.10 11460,11519,11490,3.60,4.10,0.50,4.00 11520,11579,11550,4.50,4.10,6.50,4.20 11580,11639,11610,1.70,4.00,4.70,4.10 11640,11699,11670,1.30,4.00,7.20,4.30 11700,11759,11730,-0.10,4.00,6.00,4.20 11760,11819,11790,1.30,4.00,6.00,4.20 11820,11879,11850,2.50,4.00,5.90,4.20 11880,11939,11910,2.30,4.00,6.40,4.20 11940,11999,11970,1.90,4.00,8.10,4.40 12000,12059,12030,1.40,4.00,5.50,4.20 12060,12119,12090,1.90,4.00,4.00,4.10 12120,12179,12150,3.00,4.10,4.50,4.10 12180,12239,12210,2.50,4.00,5.20,4.20 12240,12299,12270,2.30,4.00,5.60,4.20 12300,12359,12330,1.50,4.00,5.10,4.20 12360,12419,12390,1.90,4.00,6.10,4.20 12420,12479,12450,1.90,4.00,6.40,4.20 12480,12539,12510,1.60,4.00,5.50,4.20 12540,12599,12570,2.00,4.00,5.90,4.20 12600,12659,12630,1.60,4.00,5.10,4.20 12660,12719,12690,2.20,4.00,6.00,4.20 12720,12779,12750,1.90,4.00,5.20,4.20 12780,12839,12810,1.80,4.00,5.20,4.20 12840,12899,12870,1.40,4.00,4.90,4.10 12900,12959,12930,1.20,4.00,4.30,4.10 12960,13019,12990,1.70,4.00,4.40,4.10 13020,13079,13050,1.60,4.00,4.10,4.10 13080,13139,13110,1.40,4.00,5.10,4.20 13140,13199,13170,1.10,4.00,5.70,4.20 13200,13259,13230,1.20,4.00,6.90,4.30 13260,13319,13290,0.30,4.00,7.20,4.30 13320,13379,13350,0.10,4.00,6.80,4.30 13380,13439,13410,0.30,4.00,6.50,4.20 13440,13499,13470,0.90,4.00,6.60,4.30 13500,13559,13530,1.90,4.00,5.70,4.20 13560,13619,13590,0.40,4.00,4.50,4.10 13620,13679,13650,0.80,4.00,3.30,4.10 13680,13739,13710,0.20,4.00,4.60,4.10 13740,13799,13770,1.10,4.00,3.40,4.10 13800,13859,13830,1.00,4.00,2.60,4.00 13860,13919,13890,0.30,4.00,0.60,4.00 13920,13979,13950,0.60,4.00,1.10,4.00 13980,14039,14010,0.70,4.00,2.60,4.00 14040,14099,14070,1.70,4.00,3.90,4.10 14100,14159,14130,1.70,4.00,4.30,4.10 14160,14219,14190,1.70,4.00,3.50,4.10 14220,14279,14250,2.10,4.00,3.20,4.10 14280,14339,14310,2.20,4.00,4.00,4.10 14340,14399,14370,2.10,4.00,5.60,4.20 14400,14459,14430,1.50,4.00,7.20,4.30 14460,14519,14490,1.80,4.00,7.50,4.30 14520,14579,14550,3.20,4.10,6.60,4.30 14580,14639,14610,3.60,4.10,6.80,4.30 14640,14699,14670,3.30,4.10,8.10,4.40 14700,14759,14730,2.40,4.00,7.30,4.30 14760,14819,14790,2.10,4.00,6.60,4.30 14820,14879,14850,2.60,4.00,6.20,4.20 14880,14939,14910,1.50,4.00,5.20,4.20 14940,14999,14970,1.00,4.00,3.90,4.10 15000,15059,15030,0.50,4.00,2.60,4.00 15060,15119,15090,1.50,4.00,3.90,4.10 15120,15179,15150,2.00,4.00,4.50,4.10 15180,15239,15210,1.10,4.00,4.70,4.10 15240,15299,15270,0.20,4.00,3.40,4.10 15300,15359,15330,-0.20,4.00,3.00,4.10 15360,15419,15390,0.60,4.00,2.60,4.00 15420,15479,15450,2.20,4.00,3.30,4.10 15480,15539,15510,2.50,4.00,2.80,4.00 15540,15599,15570,3.10,4.10,4.30,4.10 15600,15659,15630,1.40,4.00,4.30,4.10 15660,15719,15690,1.20,4.00,4.90,4.10 15720,15779,15750,0.90,4.00,4.20,4.10 15780,15839,15810,1.10,4.00,5.40,4.20 15840,15899,15870,0.70,4.00,5.80,4.20 15900,15959,15930,-0.10,4.00,4.30,4.10 15960,16019,15990,0.30,4.00,3.40,4.10 16020,16079,16050,0.50,4.00,4.30,4.10 16080,16139,16110,0.70,4.00,6.20,4.20 16140,16199,16170,-0.60,4.00,6.90,4.30 16200,16259,16230,-0.90,4.00,6.00,4.20 16260,16319,16290,-0.90,4.00,4.40,4.10 16320,16379,16350,0.80,4.00,3.00,4.10 16380,16439,16410,1.70,4.00,3.40,4.10 16440,16499,16470,2.20,4.00,3.20,4.10 16500,16559,16530,2.40,4.00,3.60,4.10 16560,16619,16590,0.80,4.00,0.60,4.00 16620,16679,16650,1.20,4.00,1.80,4.00 16680,16739,16710,1.30,4.00,2.60,4.00 16740,16799,16770,2.30,4.00,5.00,4.10 16800,16859,16830,0.90,4.00,3.20,4.10 16860,16919,16890,-0.20,4.00,3.60,4.10 16920,16979,16950,-0.80,4.00,4.30,4.10 16980,17039,17010,-0.60,4.00,6.00,4.20 17040,17099,17070,-1.00,4.00,5.20,4.20 17100,17159,17130,0.40,4.00,5.60,4.20 17160,17219,17190,1.30,4.00,5.90,4.20 17220,17279,17250,2.10,4.00,6.80,4.30 17280,17339,17310,0.80,4.00,6.10,4.20 17340,17399,17370,0.90,4.00,5.50,4.20 17400,17459,17430,1.40,4.00,6.20,4.20 17460,17519,17490,1.40,4.00,6.20,4.20 17520,17579,17550,0.60,4.00,5.80,4.20 17580,17639,17610,0.10,4.00,3.80,4.10 17640,17699,17670,0.40,4.00,3.20,4.10 17700,17759,17730,0.50,4.00,3.10,4.10 17760,17819,17790,0.90,4.00,3.70,4.10 17820,17879,17850,1.60,4.00,4.20,4.10 17880,17939,17910,2.40,4.00,4.50,4.10 17940,17999,17970,1.30,4.00,5.50,4.20 18000,18059,18030,0.50,4.00,4.50,4.10 18060,18119,18090,-0.20,4.00,5.40,4.20 18120,18179,18150,-0.20,4.00,2.40,4.00 18180,18239,18210,0.10,4.00,2.20,4.00 18240,18299,18270,1.00,4.00,-0.40,4.00 18300,18359,18330,3.30,4.10,2.00,4.00 18360,18419,18390,4.40,4.10,3.50,4.10 18420,18479,18450,4.70,4.10,5.60,4.20 18480,18539,18510,4.50,4.10,6.40,4.20 18540,18599,18570,3.40,4.10,4.70,4.10 18600,18659,18630,2.00,4.00,3.30,4.10 18660,18719,18690,1.30,4.00,3.10,4.10 18720,18779,18750,0.10,4.00,4.50,4.10 18780,18839,18810,0.60,4.00,4.60,4.10 18840,18899,18870,0.50,4.00,2.00,4.00 18900,18959,18930,3.60,4.10,2.40,4.00 18960,19019,18990,3.00,4.10,3.90,4.10 19020,19079,19050,2.20,4.00,5.70,4.20 19080,19139,19110,0.80,4.00,6.60,4.30 19140,19199,19170,1.30,4.00,5.80,4.20 19200,19259,19230,2.30,4.00,5.30,4.20 19260,19319,19290,2.90,4.10,4.60,4.10 19320,19379,19350,2.60,4.00,6.20,4.20 19380,19439,19410,1.90,4.00,6.10,4.20 19440,19499,19470,1.00,4.00,6.30,4.20 19500,19559,19530,1.40,4.00,4.20,4.10 19560,19619,19590,2.10,4.00,5.80,4.20 19620,19679,19650,1.40,4.00,6.60,4.30 19680,19739,19710,1.10,4.00,8.00,4.40 19740,19799,19770,0.10,4.00,7.20,4.30 19800,19859,19830,0.30,4.00,5.80,4.20 19860,19919,19890,0.70,4.00,5.10,4.20 19920,19979,19950,1.30,4.00,5.10,4.20 19980,20039,20010,1.70,4.00,5.40,4.20 20040,20099,20070,1.30,4.00,6.70,4.30 20100,20159,20130,1.30,4.00,6.20,4.20 20160,20219,20190,1.00,4.00,6.00,4.20 20220,20279,20250,0.70,4.00,4.80,4.10 20280,20339,20310,0.50,4.00,4.70,4.10 20340,20399,20370,1.20,4.00,5.00,4.10 20400,20459,20430,2.10,4.00,6.20,4.20 20460,20519,20490,1.50,4.00,6.30,4.20 20520,20579,20550,0.70,4.00,5.60,4.20 20580,20639,20610,-0.20,4.00,3.70,4.10 20640,20699,20670,0.30,4.00,3.30,4.10 20700,20759,20730,1.30,4.00,1.70,4.00 20760,20819,20790,2.50,4.00,1.50,4.00 20820,20879,20850,3.00,4.10,1.30,4.00 20880,20939,20910,3.30,4.10,2.80,4.00 20940,20999,20970,2.60,4.00,2.60,4.00 21000,21059,21030,1.80,4.00,2.90,4.10 21060,21119,21090,1.20,4.00,3.10,4.10 21120,21179,21150,1.20,4.00,4.20,4.10 21180,21239,21210,0.90,4.00,5.10,4.20 21240,21299,21270,-0.50,4.00,4.70,4.10 21300,21359,21330,-0.60,4.00,4.10,4.10 21360,21419,21390,-0.10,4.00,5.50,4.20 21420,21479,21450,-0.20,4.00,5.70,4.20 21480,21539,21510,-0.50,4.00,5.60,4.20 21540,21599,21570,-0.40,4.00,2.30,4.00 21600,21659,21630,0.80,4.00,1.40,4.00 21660,21719,21690,1.10,4.00,1.40,4.00 21720,21779,21750,0.60,4.00,2.40,4.00 21780,21839,21810,-0.20,4.00,2.80,4.00 21840,21899,21870,-0.80,4.00,3.30,4.10 21900,21959,21930,-1.00,4.00,4.00,4.10 21960,22019,21990,0.00,4.00,5.30,4.20 22020,22079,22050,1.20,4.00,6.00,4.20 22080,22139,22110,2.30,4.00,6.20,4.20 22140,22199,22170,2.60,4.00,6.20,4.20 22200,22259,22230,2.00,4.00,6.90,4.30 22260,22319,22290,1.00,4.00,8.00,4.40 22320,22379,22350,0.70,4.00,6.00,4.20 22380,22439,22410,2.20,4.00,5.40,4.20 22440,22499,22470,3.60,4.10,4.70,4.10 22500,22559,22530,4.10,4.10,8.00,4.40 22560,22619,22590,1.60,4.00,7.30,4.30 22620,22679,22650,0.70,4.00,7.60,4.30 22680,22739,22710,0.20,4.00,5.90,4.20 22740,22799,22770,2.30,4.00,6.50,4.20 22800,22859,22830,2.30,4.00,4.90,4.10 22860,22919,22890,1.40,4.00,4.50,4.10 22920,22979,22950,0.80,4.00,5.00,4.10 22980,23039,23010,1.20,4.00,4.80,4.10 23040,23099,23070,2.40,4.00,6.00,4.20 23100,23159,23130,2.00,4.00,7.10,4.30 23160,23219,23190,2.10,4.00,7.40,4.30 23220,23279,23250,2.40,4.00,8.10,4.40 23280,23339,23310,2.40,4.00,7.50,4.30 23340,23399,23370,1.80,4.00,8.10,4.40 23400,23459,23430,1.20,4.00,7.70,4.30 23460,23519,23490,1.80,4.00,8.50,4.40 23520,23579,23550,1.70,4.00,9.40,4.50 23580,23639,23610,2.00,4.00,8.10,4.40 23640,23699,23670,2.00,4.00,6.40,4.20 23700,23759,23730,3.10,4.10,5.90,4.20 23760,23819,23790,3.10,4.10,6.60,4.30 23820,23879,23850,3.30,4.10,5.60,4.20 23880,23939,23910,1.50,4.00,4.30,4.10 23940,23999,23970,1.20,4.00,9.40,4.50 24000,24059,24030,-0.20,4.00,9.90,4.60 24060,24119,24090,1.50,4.00,10.80,4.70 24120,24179,24150,2.10,4.00,7.50,4.30 24180,24239,24210,3.10,4.10,9.20,4.50 24240,24299,24270,3.70,4.10,8.60,4.40 24300,24359,24330,3.60,4.10,6.80,4.30 24360,24419,24390,3.80,4.10,6.60,4.30 24420,24479,24450,3.00,4.10,7.30,4.30 24480,24539,24510,2.40,4.00,6.60,4.30 24540,24599,24570,2.70,4.00,6.00,4.20 24600,24659,24630,2.60,4.00,6.60,4.30 24660,24719,24690,2.80,4.00,9.60,4.50 24720,24779,24750,1.60,4.00,9.20,4.50 24780,24839,24810,0.90,4.00,8.30,4.40 24840,24899,24870,0.20,4.00,5.50,4.20 24900,24959,24930,1.00,4.00,5.90,4.20 24960,25019,24990,2.30,4.00,8.20,4.40 25020,25079,25050,2.50,4.00,9.10,4.50 25080,25139,25110,2.50,4.00,8.40,4.40 25140,25199,25170,0.80,4.00,6.40,4.20 25200,25259,25230,-0.10,4.00,5.60,4.20 25260,25319,25290,-0.20,4.00,8.80,4.40 25320,25379,25350,0.20,4.00,9.50,4.50 25380,25439,25410,-0.30,4.00,10.20,4.60 25440,25499,25470,-0.10,4.00,7.60,4.30 25500,25559,25530,1.60,4.00,7.10,4.30 25560,25619,25590,3.10,4.10,6.20,4.20 25620,25679,25650,2.40,4.00,6.50,4.20 25680,25739,25710,1.30,4.00,6.20,4.20 25740,25799,25770,1.40,4.00,7.50,4.30 25800,25859,25830,2.00,4.00,8.60,4.40 25860,25919,25890,1.70,4.00,10.20,4.60 25920,25979,25950,1.60,4.00,12.20,4.80 25980,26039,26010,0.90,4.00,11.40,4.70 26040,26099,26070,1.70,4.00,10.80,4.70 26100,26159,26130,2.10,4.00,9.00,4.50 26160,26219,26190,2.90,4.10,9.00,4.50 26220,26279,26250,2.10,4.00,9.00,4.50 26280,26339,26310,0.80,4.00,6.90,4.30 26340,26399,26370,0.10,4.00,7.30,4.30 26400,26459,26430,0.00,4.00,7.70,4.30 26460,26519,26490,0.20,4.00,9.40,4.50 26520,26579,26550,1.30,4.00,9.00,4.50 26580,26639,26610,1.80,4.00,6.20,4.20 26640,26699,26670,2.40,4.00,7.10,4.30 26700,26759,26730,2.30,4.00,8.80,4.40 26760,26819,26790,1.70,4.00,11.50,4.70 26820,26879,26850,2.40,4.00,13.20,4.90 26880,26939,26910,2.30,4.00,13.70,5.00 26940,26999,26970,2.60,4.00,15.90,5.30 27000,27059,27030,3.90,4.10,15.40,5.20 27060,27119,27090,5.20,4.20,15.30,5.20 27120,27179,27150,5.80,4.20,13.60,5.00 27180,27239,27210,4.60,4.10,14.50,5.10 27240,27299,27270,2.50,4.00,12.90,4.90 27300,27359,27330,3.70,4.10,13.50,5.00 27360,27419,27390,4.00,4.10,10.40,4.60 27420,27479,27450,5.00,4.10,10.30,4.60 27480,27539,27510,3.90,4.10,9.30,4.50 27540,27599,27570,3.70,4.10,10.80,4.70 27600,27659,27630,3.60,4.10,11.50,4.70 27660,27719,27690,3.40,4.10,13.80,5.00 27720,27779,27750,2.10,4.00,13.70,5.00 27780,27839,27810,2.20,4.00,13.00,4.90 27840,27899,27870,0.90,4.00,11.20,4.70 27900,27959,27930,2.20,4.00,12.10,4.80 27960,28019,27990,1.40,4.00,12.80,4.90 28020,28079,28050,2.10,4.00,12.80,4.90 28080,28139,28110,1.50,4.00,12.20,4.80 28140,28199,28170,1.80,4.00,12.70,4.90 28200,28259,28230,2.60,4.00,12.20,4.80 28260,28319,28290,3.20,4.10,13.30,5.00 28320,28379,28350,3.50,4.10,14.30,5.10 28380,28439,28410,2.80,4.00,15.10,5.20 28440,28499,28470,2.70,4.00,16.10,5.30 28500,28559,28530,1.60,4.00,15.80,5.30 28560,28619,28590,3.30,4.10,17.00,5.50 28620,28679,28650,4.30,4.10,16.60,5.40 28680,28739,28710,6.20,4.20,18.10,5.60 28740,28799,28770,5.60,4.20,18.90,5.80 28800,28859,28830,5.30,4.20,19.60,5.90 28860,28919,28890,5.30,4.20,20.10,6.00 28920,28979,28950,5.60,4.20,20.20,6.00 28980,29039,29010,6.80,4.30,21.10,6.10 29040,29099,29070,7.10,4.30,20.10,6.00 29100,29159,29130,7.50,4.30,20.60,6.00 29160,29219,29190,5.80,4.20,18.50,5.70 29220,29279,29250,6.70,4.30,19.70,5.90 29280,29339,29310,8.60,4.40,19.20,5.80 29340,29399,29370,10.70,4.60,20.20,6.00 29400,29459,29430,10.00,4.60,18.30,5.70 29460,29519,29490,8.20,4.40,18.90,5.80 29520,29579,29550,7.00,4.30,20.90,6.10 29580,29639,29610,7.00,4.30,24.50,6.70 29640,29699,29670,6.40,4.20,24.70,6.70 29700,29759,29730,7.80,4.30,24.90,6.80 29760,29819,29790,8.80,4.40,23.60,6.50 29820,29879,29850,11.00,4.70,24.30,6.70 29880,29939,29910,10.20,4.60,23.30,6.50 29940,29999,29970,10.40,4.60,25.20,6.80 30000,30059,30030,10.90,4.70,26.20,7.00 30060,30119,30090,12.50,4.90,27.80,7.30 30120,30179,30150,13.30,5.00,27.50,7.20 30180,30239,30210,12.90,4.90,27.30,7.20 30240,30299,30270,12.50,4.80,27.30,7.20 30300,30359,30330,10.90,4.70,27.20,7.20 30360,30419,30390,11.30,4.70,31.00,7.90 30420,30479,30450,10.70,4.60,32.80,8.20 30480,30539,30510,12.40,4.80,34.70,8.60 30540,30599,30570,13.80,5.00,33.10,8.30 30600,30659,30630,13.60,5.00,31.70,8.00 30660,30719,30690,13.70,5.00,31.70,8.00 30720,30779,30750,13.80,5.00,34.40,8.60 30780,30839,30810,15.40,5.20,37.70,9.20 30840,30899,30870,14.30,5.10,40.10,9.70 30900,30959,30930,13.60,5.00,38.80,9.40 30960,31019,30990,14.30,5.10,41.30,9.90 31020,31079,31050,16.00,5.30,40.30,9.70 31080,31139,31110,16.50,5.40,43.50,10.40 31140,31199,31170,16.40,5.40,41.90,10.00 31200,31259,31230,16.20,5.40,43.00,10.30 31260,31319,31290,16.70,5.40,45.90,10.90 31320,31379,31350,17.30,5.50,46.50,11.00 31380,31439,31410,17.60,5.60,51.50,12.00 31440,31499,31470,17.80,5.60,51.30,12.00 31500,31559,31530,16.40,5.40,53.20,12.40 31560,31619,31590,19.30,5.80,50.00,11.70 31620,31679,31650,21.40,6.20,49.10,11.50 31680,31739,31710,24.40,6.70,49.10,11.50 31740,31799,31770,22.80,6.40,51.20,12.00 31800,31859,31830,21.10,6.10,50.90,11.90 31860,31919,31890,20.50,6.00,51.20,12.00 31920,31979,31950,21.50,6.20,48.80,11.50 31980,32039,32010,22.20,6.30,52.40,12.20 32040,32099,32070,21.90,6.30,56.40,13.00 32100,32159,32130,22.10,6.30,59.50,13.70 32160,32219,32190,23.50,6.50,54.70,12.70 32220,32279,32250,25.50,6.90,53.00,12.30 32280,32339,32310,23.30,6.50,57.10,13.20 32340,32399,32370,21.40,6.20,63.50,14.50 32400,32459,32430,20.00,6.00,62.50,14.30 32460,32519,32490,22.40,6.40,64.00,14.60 32520,32579,32550,23.80,6.60,60.70,13.90 32580,32639,32610,24.60,6.70,62.40,14.30 32640,32699,32670,24.60,6.70,61.10,14.00 32700,32759,32730,25.50,6.90,62.20,14.20 32760,32819,32790,26.70,7.10,70.00,15.90 32820,32879,32850,28.80,7.50,73.10,16.60 32880,32939,32910,29.30,7.60,76.30,17.30 32940,32999,32970,29.30,7.60,69.50,15.80 33000,33059,33030,27.80,7.30,66.20,15.10 33060,33119,33090,26.80,7.10,66.90,15.20 33120,33179,33150,27.00,7.20,66.30,15.10 33180,33239,33210,29.40,7.60,69.50,15.80 33240,33299,33270,31.20,7.90,68.30,15.60 33300,33359,33330,34.30,8.50,69.90,15.90 33360,33419,33390,34.10,8.50,66.40,15.20 33420,33479,33450,36.10,8.90,65.10,14.90 33480,33539,33510,34.30,8.50,66.70,15.20 33540,33599,33570,33.50,8.40,68.00,15.50 33600,33659,33630,32.10,8.10,68.40,15.60 33660,33719,33690,33.80,8.40,75.50,17.10 33720,33779,33750,36.00,8.90,77.90,17.60 33780,33839,33810,37.50,9.20,86.00,19.30 33840,33899,33870,35.50,8.80,81.30,18.30 33900,33959,33930,35.10,8.70,84.80,19.10 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