49, 1001 Cantrell, Christopher A Atmospheric Chemistry Division/NESL/NCAR HO2 and HO2+RO2 from PeRCIMS at Manitou Experimental Forest BEACHON-RoMBAS 1,1 2011, 07, 21, 2011, 11, 17 0 Start_MST, seconds, number_of_seconds_from_0000_MST 6 1,1,1,1,1,1 -99999,-99999,-99999,-99999,-99999,-99999 Stop_MST, seconds, number_of_seconds_from_0000_MST Mid_MST, seconds, number_of_seconds_from_0000_MST HO2, pptv, HO2_mixing_ratio HO2_uncertainty, pptv, HO2_2_sigma_uncertainty HO2+RO2, pptv, HO2+RO2_mixing_ratio HO2+RO2_uncertainty, pptv, HO2+RO2_2_sigma_uncertainty 5 These data are reduced using four factors determined in the laboratory and in the field: F_lo and F_hi are the radical sensitivities in the HO2+RO2 and HO2 modes, respectively (units pptv/ion ratio). Alpha_lo and alpha_hi are the ratios of RO2 to HO2 sensitivity in the HO2+RO2 and HO2 modes, respectively. HO2+RO2 concentrations are then S_lo*F_lo-(S_lo*F_lo - S_hi*F_hi)*(alpha_lo - 1)/(alpha_lo - alpha_hi) . HO2 concentrations are S_lo*F_lo-(S_lo*F_lo - S_hi*F_hi)*(alpha_lo)/(alpha_lo - alpha_hi) . S_lo is the background corrected ion ratio in the HO2+RO2 mode, and S_hi is the background corrected ion ratio in the HO2 mode. The ion ratios are mass 97 signal count rate minus background count rate divided by mass 62 count rate. 24 PI_CONTACT_INFO: 303-497-1479, NCAR, 3090 Center Green Dr., Boulder, CO 80301, cantrell@ucar.edu PLATFORM: Seacontainer #1 LOCATION: Manitou Experimental Forest, Woodland Park, Colorado, USA ASSOCIATED_DATA: N/A INSTRUMENT_INFO: These data were collected using a CIMS based instrument. An inlet collects ambient air from the free air stream and adds reagents, includling O2 or N2 diluents, and NO and SO2 reagent gases. This method, called oxygen dilution modulation leads to nearly 100% measurement of HO2 and RO2 in the O2 dilution/low reagent concentration mode, whereas RO2 is measured with less than 15% efficiency in the N2 dilution/higher reagent concentration mode. This is because the chemistry converts peroxy radicals to H2SO4 efficiently in the O2 mode, but RO2 radicals are converted to RONO in the N2 mode. The H2SO4 thus produced is ionized by reaction with NO3- ions. The reagent and product ions are detected by mass spectrometry using quadrupole mass filtering and counting by a channel electron multiplier operating in the negative ion mode. DATA_INFO: Signal data for HO2+RO2 are collected during the 0-7 second time interval, and for HO2 in 30-37 second time interval. UNCERTAINTY: approximately 35% (2 sigma) for HO2 & HO2+RO2 values well above 2 pptv; estimates are listed for each data point (2 sigma) ULOD_FLAG: -7777 ULOD_VALUE: N/A LLOD_FLAG: -8888 LLOD_VALUE: N/A DM_CONTACT_INFO: N/A PROJECT_INFO: BEACHON-RoMBAS, 20-Jul-2011 to 30-Aug-2011 STIPULATIONS_ON_USE: contact PI BEFORE use/presentation/publication OTHER_COMMENTS: REVISION: R1; R0 R1: final data R0: preliminary data Start_MST,Stop_MST,Mid_MST,HO2,HO2_uncertainty,HO2+RO2,HO2+RO2_uncertainty 0,59,30,-1.00,4.00,8.10,4.40 60,119,90,-0.30,4.00,7.30,4.30 120,179,150,0.80,4.00,5.50,4.20 180,239,210,3.10,4.10,6.60,4.30 240,299,270,3.40,4.10,5.80,4.20 300,359,330,3.50,4.10,5.90,4.20 360,419,390,1.70,4.00,5.70,4.20 420,479,450,1.40,4.00,7.80,4.30 480,539,510,1.50,4.00,8.60,4.40 540,599,570,2.50,4.00,7.80,4.40 600,659,630,4.40,4.10,7.50,4.30 660,719,690,5.00,4.10,8.70,4.40 720,779,750,4.50,4.10,9.20,4.50 780,839,810,2.30,4.00,8.40,4.40 840,899,870,2.20,4.00,8.80,4.40 900,959,930,2.70,4.00,8.70,4.40 960,1019,990,2.90,4.00,9.60,4.50 1020,1079,1050,1.40,4.00,7.10,4.30 1080,1139,1110,0.80,4.00,5.30,4.20 1140,1199,1170,0.80,4.00,2.80,4.00 1200,1259,1230,1.90,4.00,2.20,4.00 1260,1319,1290,2.70,4.00,2.00,4.00 1320,1379,1350,5.20,4.20,4.10,4.10 1380,1439,1410,4.70,4.10,6.70,4.30 1440,1499,1470,3.70,4.10,8.10,4.40 1500,1559,1530,0.90,4.00,6.50,4.20 1560,1619,1590,1.90,4.00,7.30,4.30 1620,1679,1650,0.70,4.00,5.80,4.20 1680,1739,1710,0.10,4.00,4.40,4.10 1740,1799,1770,0.60,4.00,5.90,4.20 1800,1859,1830,2.40,4.00,6.10,4.20 1860,1919,1890,5.00,4.20,7.80,4.40 1920,1979,1950,4.50,4.10,5.10,4.20 1980,2039,2010,3.80,4.10,5.40,4.20 2040,2099,2070,2.20,4.00,5.30,4.20 2100,2159,2130,1.70,4.00,3.20,4.10 2160,2219,2190,2.20,4.00,4.00,4.10 2220,2279,2250,3.10,4.10,4.40,4.10 2280,2339,2310,2.60,4.00,7.50,4.30 2340,2399,2370,3.20,4.10,7.20,4.30 2400,2459,2430,2.30,4.00,7.20,4.30 2460,2519,2490,3.30,4.10,6.60,4.30 2520,2579,2550,1.90,4.00,5.80,4.20 2580,2639,2610,2.00,4.00,5.10,4.20 2640,2699,2670,1.80,4.00,4.10,4.10 2700,2759,2730,2.30,4.00,4.60,4.10 2760,2819,2790,2.60,4.00,4.40,4.10 2820,2879,2850,3.50,4.10,5.20,4.20 2880,2939,2910,4.20,4.10,5.90,4.20 2940,2999,2970,4.70,4.10,7.30,4.30 3000,3059,3030,3.90,4.10,8.40,4.40 3060,3119,3090,3.00,4.10,7.70,4.30 3120,3179,3150,2.80,4.00,6.20,4.20 3180,3239,3210,2.70,4.00,4.90,4.10 3240,3299,3270,2.80,4.00,6.30,4.20 3300,3359,3330,2.00,4.00,6.90,4.30 3360,3419,3390,1.60,4.00,6.30,4.20 3420,3479,3450,1.10,4.00,5.10,4.20 3480,3539,3510,2.10,4.00,5.10,4.20 3540,3599,3570,1.00,4.00,6.30,4.20 3600,3659,3630,1.20,4.00,4.90,4.10 3660,3719,3690,0.80,4.00,4.10,4.10 3720,3779,3750,1.50,4.00,3.50,4.10 3780,3839,3810,1.30,4.00,2.10,4.00 3840,3899,3870,3.70,4.10,4.40,4.10 3900,3959,3930,2.70,4.00,4.40,4.10 3960,4019,3990,3.70,4.10,8.00,4.40 4020,4079,4050,1.00,4.00,6.40,4.20 4080,4139,4110,1.60,4.00,4.30,4.10 4140,4199,4170,1.30,4.00,2.80,4.00 4200,4259,4230,1.90,4.00,1.60,4.00 4260,4319,4290,4.20,4.10,5.10,4.20 4320,4379,4350,2.70,4.00,4.40,4.10 4380,4439,4410,2.50,4.00,8.50,4.40 4440,4499,4470,1.00,4.00,5.40,4.20 4500,4559,4530,2.00,4.00,7.10,4.30 4560,4619,4590,1.50,4.00,6.40,4.20 4620,4679,4650,0.70,4.00,7.10,4.30 4680,4739,4710,1.50,4.00,7.40,4.30 4740,4799,4770,1.70,4.00,4.50,4.10 4800,4859,4830,1.90,4.00,5.50,4.20 4860,4919,4890,1.30,4.00,5.60,4.20 4920,4979,4950,2.50,4.00,5.20,4.20 4980,5039,5010,4.10,4.10,5.70,4.20 5040,5099,5070,2.90,4.00,4.90,4.10 5100,5159,5130,1.50,4.00,7.70,4.30 5160,5219,5190,0.80,4.00,6.10,4.20 5220,5279,5250,3.20,4.10,9.10,4.50 5280,5339,5310,3.70,4.10,7.80,4.40 5340,5399,5370,3.90,4.10,9.90,4.60 5400,5459,5430,2.50,4.00,7.70,4.30 5460,5519,5490,2.30,4.00,9.60,4.50 5520,5579,5550,1.50,4.00,8.00,4.40 5580,5639,5610,0.90,4.00,6.50,4.20 5640,5699,5670,1.00,4.00,3.90,4.10 5700,5759,5730,1.70,4.00,2.70,4.00 5760,5819,5790,3.20,4.10,5.30,4.20 5820,5879,5850,2.40,4.00,6.90,4.30 5880,5939,5910,2.40,4.00,9.40,4.50 5940,5999,5970,2.00,4.00,6.80,4.30 6000,6059,6030,4.10,4.10,5.50,4.20 6060,6119,6090,3.90,4.10,4.00,4.10 6120,6179,6150,2.30,4.00,3.00,4.10 6180,6239,6210,-0.20,4.00,2.00,4.00 6240,6299,6270,-0.80,4.00,1.20,4.00 6300,6359,6330,0.00,4.00,3.40,4.10 6360,6419,6390,0.50,4.00,4.00,4.10 6420,6479,6450,1.90,4.00,4.10,4.10 6480,6539,6510,2.50,4.00,3.20,4.10 6540,6599,6570,2.90,4.00,4.80,4.10 6600,6659,6630,-2.40,4.00,2.00,4.00 6660,6719,6690,-1.90,4.00,2.20,4.00 6720,6779,6750,-1.30,4.00,0.60,4.00 6780,6839,6810,4.20,4.10,2.60,4.00 6840,6899,6870,4.10,4.10,1.30,4.00 6900,6959,6930,4.50,4.10,1.00,4.00 6960,7019,6990,4.40,4.10,3.10,4.10 7020,7079,7050,4.20,4.10,6.40,4.20 7080,7139,7110,3.10,4.10,8.30,4.40 7140,7199,7170,1.50,4.00,7.50,4.30 7200,7259,7230,1.10,4.00,5.50,4.20 7260,7319,7290,1.30,4.00,3.70,4.10 7320,7379,7350,2.70,4.00,3.70,4.10 7380,7439,7410,2.20,4.00,3.10,4.10 7440,7499,7470,1.30,4.00,3.70,4.10 7500,7559,7530,1.80,4.00,4.30,4.10 7560,7619,7590,1.80,4.00,4.30,4.10 7620,7679,7650,2.30,4.00,3.60,4.10 7680,7739,7710,1.80,4.00,3.00,4.10 7740,7799,7770,2.10,4.00,2.40,4.00 7800,7859,7830,1.80,4.00,2.30,4.00 7860,7919,7890,0.60,4.00,2.20,4.00 7920,7979,7950,0.10,4.00,2.30,4.00 7980,8039,8010,0.90,4.00,2.30,4.00 8040,8099,8070,1.90,4.00,3.20,4.10 8100,8159,8130,1.90,4.00,3.80,4.10 8160,8219,8190,1.20,4.00,5.20,4.20 8220,8279,8250,0.10,4.00,3.50,4.10 8280,8339,8310,-0.20,4.00,3.50,4.10 8340,8399,8370,-0.40,4.00,5.30,4.20 8400,8459,8430,-0.30,4.00,6.60,4.30 8460,8519,8490,0.90,4.00,9.20,4.50 8520,8579,8550,1.60,4.00,8.60,4.40 8580,8639,8610,3.00,4.10,8.00,4.40 8640,8699,8670,4.00,4.10,5.10,4.20 8700,8759,8730,3.60,4.10,1.90,4.00 8760,8819,8790,3.10,4.10,2.60,4.00 8820,8879,8850,2.00,4.00,3.50,4.10 8880,8939,8910,3.10,4.10,5.30,4.20 8940,8999,8970,3.90,4.10,5.60,4.20 9000,9059,9030,4.90,4.10,5.20,4.20 9060,9119,9090,4.20,4.10,5.30,4.20 9120,9179,9150,3.30,4.10,5.40,4.20 9180,9239,9210,1.50,4.00,3.60,4.10 9240,9299,9270,2.00,4.00,2.50,4.00 9300,9359,9330,2.10,4.00,1.70,4.00 9360,9419,9390,2.90,4.10,4.40,4.10 9420,9479,9450,1.20,4.00,4.90,4.10 9480,9539,9510,1.30,4.00,3.80,4.10 9540,9599,9570,1.50,4.00,2.80,4.00 9600,9659,9630,4.10,4.10,3.00,4.10 9660,9719,9690,4.50,4.10,4.10,4.10 9720,9779,9750,4.20,4.10,5.20,4.20 9780,9839,9810,3.10,4.10,5.50,4.20 9840,9899,9870,2.50,4.00,5.80,4.20 9900,9959,9930,2.10,4.00,4.00,4.10 9960,10019,9990,1.30,4.00,5.20,4.20 10020,10079,10050,2.50,4.00,5.60,4.20 10080,10139,10110,2.30,4.00,7.40,4.30 10140,10199,10170,3.70,4.10,7.10,4.30 10200,10259,10230,2.60,4.00,6.70,4.30 10260,10319,10290,2.70,4.00,5.50,4.20 10320,10379,10350,2.40,4.00,4.60,4.10 10380,10439,10410,3.10,4.10,4.60,4.10 10440,10499,10470,3.80,4.10,5.90,4.20 10500,10559,10530,3.40,4.10,6.10,4.20 10560,10619,10590,2.00,4.00,5.40,4.20 10620,10679,10650,2.30,4.00,6.40,4.20 10680,10739,10710,2.80,4.00,7.40,4.30 10740,10799,10770,3.40,4.10,7.50,4.30 10800,10859,10830,3.00,4.10,7.50,4.30 10860,10919,10890,3.00,4.10,6.50,4.20 10920,10979,10950,2.80,4.00,6.90,4.30 10980,11039,11010,2.00,4.00,6.00,4.20 11040,11099,11070,1.10,4.00,6.50,4.20 11100,11159,11130,0.70,4.00,6.00,4.20 11160,11219,11190,1.30,4.00,5.90,4.20 11220,11279,11250,2.70,4.00,4.50,4.10 11280,11339,11310,5.20,4.20,5.90,4.20 11340,11399,11370,4.20,4.10,6.00,4.20 11400,11459,11430,2.60,4.00,8.00,4.40 11460,11519,11490,0.60,4.00,7.10,4.30 11520,11579,11550,2.20,4.00,6.90,4.30 11580,11639,11610,3.50,4.10,5.60,4.20 11640,11699,11670,4.30,4.10,4.30,4.10 11700,11759,11730,4.40,4.10,3.60,4.10 11760,11819,11790,4.10,4.10,4.00,4.10 11820,11879,11850,2.50,4.00,6.20,4.20 11880,11939,11910,1.90,4.00,6.40,4.20 11940,11999,11970,2.00,4.00,7.30,4.30 12000,12059,12030,1.90,4.00,6.70,4.30 12060,12119,12090,1.90,4.00,8.00,4.40 12120,12179,12150,1.40,4.00,7.00,4.30 12180,12239,12210,2.80,4.00,6.70,4.30 12240,12299,12270,2.40,4.00,5.00,4.20 12300,12359,12330,3.90,4.10,6.90,4.30 12360,12419,12390,3.40,4.10,6.00,4.20 12420,12479,12450,4.60,4.10,6.30,4.20 12480,12539,12510,4.10,4.10,4.80,4.10 12540,12599,12570,3.40,4.10,6.40,4.20 12600,12659,12630,1.80,4.00,5.80,4.20 12660,12719,12690,1.60,4.00,5.80,4.20 12720,12779,12750,2.10,4.00,4.40,4.10 12780,12839,12810,2.50,4.00,4.80,4.10 12840,12899,12870,2.60,4.00,3.50,4.10 12900,12959,12930,3.90,4.10,2.50,4.00 12960,13019,12990,6.30,4.20,4.60,4.10 13020,13079,13050,6.30,4.20,5.90,4.20 13080,13139,13110,4.90,4.10,6.50,4.20 13140,13199,13170,2.90,4.10,5.40,4.20 13200,13259,13230,2.30,4.00,7.10,4.30 13260,13319,13290,2.70,4.00,8.60,4.40 13320,13379,13350,3.40,4.10,10.20,4.60 13380,13439,13410,2.60,4.00,9.90,4.60 13440,13499,13470,2.40,4.00,10.20,4.60 13500,13559,13530,3.30,4.10,9.90,4.60 13560,13619,13590,3.80,4.10,9.60,4.50 13620,13679,13650,3.90,4.10,11.50,4.70 13680,13739,13710,3.10,4.10,9.40,4.50 13740,13799,13770,4.90,4.10,7.50,4.30 13800,13859,13830,7.40,4.30,5.50,4.20 13860,13919,13890,6.60,4.30,5.30,4.20 13920,13979,13950,5.00,4.20,5.90,4.20 13980,14039,14010,3.40,4.10,5.50,4.20 14040,14099,14070,2.80,4.00,5.80,4.20 14100,14159,14130,2.60,4.00,7.80,4.40 14160,14219,14190,1.00,4.00,7.90,4.40 14220,14279,14250,2.20,4.00,9.10,4.50 14280,14339,14310,1.50,4.00,6.10,4.20 14340,14399,14370,5.30,4.20,6.10,4.20 14400,14459,14430,4.80,4.10,6.60,4.30 14460,14519,14490,6.90,4.30,8.00,4.40 14520,14579,14550,5.30,4.20,7.50,4.30 14580,14639,14610,5.10,4.20,5.30,4.20 14640,14699,14670,4.30,4.10,6.90,4.30 14700,14759,14730,1.80,4.00,5.90,4.20 14760,14819,14790,2.50,4.00,7.70,4.30 14820,14879,14850,1.90,4.00,6.70,4.30 14880,14939,14910,2.40,4.00,8.60,4.40 14940,14999,14970,1.30,4.00,8.00,4.40 15000,15059,15030,2.50,4.00,6.90,4.30 15060,15119,15090,3.70,4.10,5.70,4.20 15120,15179,15150,4.40,4.10,5.10,4.20 15180,15239,15210,2.90,4.10,6.90,4.30 15240,15299,15270,2.50,4.00,7.30,4.30 15300,15359,15330,2.90,4.10,7.60,4.30 15360,15419,15390,4.50,4.10,5.10,4.20 15420,15479,15450,4.50,4.10,6.30,4.20 15480,15539,15510,3.10,4.10,5.90,4.20 15540,15599,15570,2.50,4.00,6.90,4.30 15600,15659,15630,1.70,4.00,3.50,4.10 15660,15719,15690,3.60,4.10,4.50,4.10 15720,15779,15750,3.80,4.10,4.20,4.10 15780,15839,15810,4.70,4.10,5.30,4.20 15840,15899,15870,3.60,4.10,4.90,4.10 15900,15959,15930,1.80,4.00,3.70,4.10 15960,16019,15990,3.00,4.10,3.80,4.10 16020,16079,16050,4.10,4.10,2.80,4.00 16080,16139,16110,6.10,4.20,2.80,4.00 16140,16199,16170,5.00,4.20,3.00,4.10 16200,16259,16230,3.50,4.10,4.10,4.10 16260,16319,16290,2.10,4.00,5.60,4.20 16320,16379,16350,1.00,4.00,6.10,4.20 16380,16439,16410,1.50,4.00,6.10,4.20 16440,16499,16470,3.10,4.10,6.70,4.30 16500,16559,16530,4.00,4.10,5.50,4.20 16560,16619,16590,5.40,4.20,10.40,4.60 16620,16679,16650,4.10,4.10,8.80,4.40 16680,16739,16710,5.00,4.10,11.50,4.70 16740,16799,16770,3.50,4.10,9.00,4.50 16800,16859,16830,3.80,4.10,8.40,4.40 16860,16919,16890,3.50,4.10,6.70,4.30 16920,16979,16950,4.20,4.10,4.20,4.10 16980,17039,17010,5.20,4.20,6.00,4.20 17040,17099,17070,3.80,4.10,6.10,4.20 17100,17159,17130,4.00,4.10,5.90,4.20 17160,17219,17190,3.30,4.10,5.50,4.20 17220,17279,17250,3.70,4.10,5.60,4.20 17280,17339,17310,2.50,4.00,5.30,4.20 17340,17399,17370,2.30,4.00,5.90,4.20 17400,17459,17430,2.80,4.00,6.80,4.30 17460,17519,17490,2.50,4.00,7.10,4.30 17520,17579,17550,3.00,4.10,6.30,4.20 17580,17639,17610,1.90,4.00,4.40,4.10 17640,17699,17670,3.60,4.10,4.60,4.10 17700,17759,17730,3.80,4.10,4.00,4.10 17760,17819,17790,5.50,4.20,4.70,4.10 17820,17879,17850,5.10,4.20,5.10,4.20 17880,17939,17910,5.30,4.20,6.00,4.20 17940,17999,17970,4.90,4.10,7.10,4.30 18000,18059,18030,4.60,4.10,5.90,4.20 18060,18119,18090,3.50,4.10,7.90,4.40 18120,18179,18150,3.20,4.10,7.10,4.30 18180,18239,18210,2.30,4.00,8.00,4.40 18240,18299,18270,1.00,4.00,5.50,4.20 18300,18359,18330,0.40,4.00,6.00,4.20 18360,18419,18390,0.00,4.00,5.60,4.20 18420,18479,18450,1.00,4.00,5.60,4.20 18480,18539,18510,1.60,4.00,4.80,4.10 18540,18599,18570,2.40,4.00,4.60,4.10 18600,18659,18630,2.70,4.00,5.00,4.10 18660,18719,18690,3.50,4.10,5.30,4.20 18720,18779,18750,5.30,4.20,6.80,4.30 18780,18839,18810,4.60,4.10,8.40,4.40 18840,18899,18870,4.80,4.10,12.80,4.90 18900,18959,18930,3.70,4.10,11.20,4.70 18960,19019,18990,5.20,4.20,10.10,4.60 19020,19079,19050,3.70,4.10,5.50,4.20 19080,19139,19110,2.40,4.00,6.50,4.30 19140,19199,19170,1.60,4.00,5.80,4.20 19200,19259,19230,2.20,4.00,5.70,4.20 19260,19319,19290,2.30,4.00,5.50,4.20 19320,19379,19350,2.10,4.00,8.10,4.40 19380,19439,19410,1.60,4.00,10.40,4.60 19440,19499,19470,2.50,4.00,10.20,4.60 19500,19559,19530,3.60,4.10,7.50,4.30 19560,19619,19590,3.90,4.10,3.60,4.10 19620,19679,19650,6.90,4.30,5.90,4.20 19680,19739,19710,6.40,4.20,6.80,4.30 19740,19799,19770,6.50,4.20,10.70,4.60 19800,19859,19830,3.30,4.10,8.40,4.40 19860,19919,19890,3.50,4.10,7.60,4.30 19920,19979,19950,3.80,4.10,5.50,4.20 19980,20039,20010,3.60,4.10,6.30,4.20 20040,20099,20070,2.10,4.00,5.20,4.20 20100,20159,20130,2.30,4.00,6.50,4.20 20160,20219,20190,2.00,4.00,6.10,4.20 20220,20279,20250,3.00,4.10,9.40,4.50 20280,20339,20310,2.70,4.00,7.50,4.30 20340,20399,20370,3.80,4.10,6.60,4.30 20400,20459,20430,3.60,4.10,4.30,4.10 20460,20519,20490,2.50,4.00,7.10,4.30 20520,20579,20550,1.30,4.00,8.00,4.40 20580,20639,20610,2.00,4.00,11.30,4.70 20640,20699,20670,1.30,4.00,8.30,4.40 20700,20759,20730,3.10,4.10,7.70,4.30 20760,20819,20790,3.00,4.10,3.70,4.10 20820,20879,20850,3.60,4.10,1.50,4.00 20880,20939,20910,3.30,4.10,1.80,4.00 20940,20999,20970,2.40,4.00,2.80,4.00 21000,21059,21030,3.40,4.10,6.40,4.20 21060,21119,21090,1.90,4.00,7.20,4.30 21120,21179,21150,1.70,4.00,9.10,4.50 21180,21239,21210,1.00,4.00,11.80,4.80 21240,21299,21270,0.50,4.00,9.90,4.60 21300,21359,21330,0.80,4.00,8.30,4.40 21360,21419,21390,1.80,4.00,6.90,4.30 21420,21479,21450,3.40,4.10,11.50,4.70 21480,21539,21510,2.90,4.10,13.40,5.00 21540,21599,21570,2.30,4.00,10.80,4.60 21600,21659,21630,2.20,4.00,6.70,4.30 21660,21719,21690,3.70,4.10,5.40,4.20 21720,21779,21750,3.50,4.10,6.40,4.20 21780,21839,21810,3.80,4.10,8.50,4.40 21840,21899,21870,1.90,4.00,7.50,4.30 21900,21959,21930,2.50,4.00,7.00,4.30 21960,22019,21990,1.80,4.00,5.20,4.20 22020,22079,22050,3.10,4.10,6.10,4.20 22080,22139,22110,3.00,4.10,6.90,4.30 22140,22199,22170,3.00,4.10,7.00,4.30 22200,22259,22230,3.10,4.10,8.50,4.40 22260,22319,22290,3.10,4.10,9.00,4.50 22320,22379,22350,3.40,4.10,8.90,4.40 22380,22439,22410,2.60,4.00,6.90,4.30 22440,22499,22470,2.80,4.00,5.90,4.20 22500,22559,22530,1.80,4.00,4.70,4.10 22560,22619,22590,3.00,4.10,6.10,4.20 22620,22679,22650,1.40,4.00,5.10,4.20 22680,22739,22710,1.50,4.00,8.30,4.40 22740,22799,22770,-0.50,4.00,7.30,4.30 22800,22859,22830,-0.60,4.00,8.00,4.40 22860,22919,22890,0.50,4.00,5.30,4.20 22920,22979,22950,1.70,4.00,5.70,4.20 22980,23039,23010,2.80,4.00,9.00,4.50 23040,23099,23070,2.60,4.00,11.20,4.70 23100,23159,23130,2.90,4.10,13.00,4.90 23160,23219,23190,3.50,4.10,11.20,4.70 23220,23279,23250,2.60,4.00,10.60,4.60 23280,23339,23310,1.90,4.00,8.50,4.40 23340,23399,23370,0.70,4.00,7.30,4.30 23400,23459,23430,1.10,4.00,6.80,4.30 23460,23519,23490,1.40,4.00,6.70,4.30 23520,23579,23550,2.40,4.00,6.70,4.30 23580,23639,23610,2.50,4.00,8.10,4.40 23640,23699,23670,2.80,4.00,8.30,4.40 23700,23759,23730,2.90,4.10,9.60,4.50 23760,23819,23790,2.70,4.00,8.40,4.40 23820,23879,23850,2.10,4.00,7.80,4.40 23880,23939,23910,2.20,4.00,8.70,4.40 23940,23999,23970,2.30,4.00,9.50,4.50 24000,24059,24030,3.60,4.10,11.20,4.70 24060,24119,24090,3.40,4.10,10.50,4.60 24120,24179,24150,4.00,4.10,10.10,4.60 24180,24239,24210,3.60,4.10,9.00,4.50 24240,24299,24270,3.40,4.10,7.40,4.30 24300,24359,24330,2.80,4.00,9.90,4.60 24360,24419,24390,2.70,4.00,10.90,4.70 24420,24479,24450,2.10,4.00,11.50,4.70 24480,24539,24510,3.00,4.10,13.90,5.00 24540,24599,24570,2.20,4.00,13.20,4.90 24600,24659,24630,3.10,4.10,12.90,4.90 24660,24719,24690,3.80,4.10,13.10,4.90 24720,24779,24750,5.10,4.20,12.90,4.90 24780,24839,24810,5.30,4.20,13.90,5.00 24840,24899,24870,4.50,4.10,8.80,4.40 24900,24959,24930,4.60,4.10,12.50,4.90 24960,25019,24990,4.30,4.10,13.20,4.90 25020,25079,25050,3.80,4.10,13.10,4.90 25080,25139,25110,4.00,4.10,11.40,4.70 25140,25199,25170,3.10,4.10,11.10,4.70 25200,25259,25230,3.20,4.10,14.90,5.20 25260,25319,25290,1.80,4.00,16.60,5.40 25320,25379,25350,3.30,4.10,18.30,5.70 25380,25439,25410,4.40,4.10,13.50,5.00 25440,25499,25470,5.20,4.20,11.70,4.80 25500,25559,25530,4.40,4.10,10.80,4.70 25560,25619,25590,4.30,4.10,15.20,5.20 25620,25679,25650,4.20,4.10,15.40,5.20 25680,25739,25710,4.60,4.10,14.60,5.10 25740,25799,25770,4.10,4.10,11.80,4.80 25800,25859,25830,4.00,4.10,11.40,4.70 25860,25919,25890,2.70,4.00,10.30,4.60 25920,25979,25950,1.80,4.00,9.60,4.50 25980,26039,26010,0.90,4.00,13.10,4.90 26040,26099,26070,1.20,4.00,17.60,5.60 26100,26159,26130,2.10,4.00,20.80,6.10 26160,26219,26190,3.80,4.10,18.30,5.70 26220,26279,26250,5.80,4.20,16.90,5.50 26280,26339,26310,6.60,4.30,15.20,5.20 26340,26399,26370,5.40,4.20,13.40,5.00 26400,26459,26430,3.90,4.10,11.80,4.80 26460,26519,26490,1.90,4.00,10.20,4.60 26520,26579,26550,1.70,4.00,10.40,4.60 26580,26639,26610,2.60,4.00,12.20,4.80 26640,26699,26670,3.60,4.10,13.60,5.00 26700,26759,26730,4.80,4.10,15.10,5.20 26760,26819,26790,2.30,4.00,13.50,5.00 26820,26879,26850,1.10,4.00,12.10,4.80 26880,26939,26910,0.90,4.00,13.60,5.00 26940,26999,26970,2.20,4.00,14.30,5.10 27000,27059,27030,4.30,4.10,16.70,5.40 27060,27119,27090,3.60,4.10,13.30,5.00 27120,27179,27150,3.40,4.10,14.20,5.10 27180,27239,27210,3.40,4.10,14.80,5.20 27240,27299,27270,3.90,4.10,18.30,5.70 27300,27359,27330,4.60,4.10,17.70,5.60 27360,27419,27390,3.80,4.10,16.80,5.50 27420,27479,27450,2.50,4.00,16.10,5.30 27480,27539,27510,1.90,4.00,16.30,5.40 27540,27599,27570,2.70,4.00,15.60,5.30 27600,27659,27630,4.60,4.10,14.30,5.10 27660,27719,27690,5.20,4.20,15.50,5.30 27720,27779,27750,5.90,4.20,16.60,5.40 27780,27839,27810,4.00,4.10,18.50,5.70 27840,27899,27870,4.10,4.10,20.40,6.00 27900,27959,27930,3.50,4.10,21.60,6.20 27960,28019,27990,6.00,4.20,21.50,6.20 28020,28079,28050,6.50,4.20,23.10,6.50 28080,28139,28110,7.30,4.30,23.70,6.60 28140,28199,28170,6.40,4.20,23.50,6.50 28200,28259,28230,6.30,4.20,19.90,5.90 28260,28319,28290,4.80,4.10,17.90,5.60 28320,28379,28350,6.60,4.30,19.50,5.90 28380,28439,28410,6.60,4.30,20.40,6.00 28440,28499,28470,7.80,4.40,22.00,6.30 28500,28559,28530,8.20,4.40,22.10,6.30 28560,28619,28590,8.00,4.40,21.70,6.20 28620,28679,28650,8.00,4.40,20.80,6.10 28680,28739,28710,8.30,4.40,18.50,5.70 28740,28799,28770,10.50,4.60,18.00,5.60 28800,28859,28830,12.40,4.80,18.90,5.80 28860,28919,28890,12.70,4.90,20.00,6.00 28920,28979,28950,12.70,4.90,21.70,6.20 28980,29039,29010,12.50,4.90,20.90,6.10 29040,29099,29070,11.90,4.80,22.50,6.40 29100,29159,29130,12.30,4.80,23.10,6.50 29160,29219,29190,13.20,4.90,24.60,6.70 29220,29279,29250,12.80,4.90,24.50,6.70 29280,29339,29310,12.00,4.80,25.50,6.90 29340,29399,29370,9.90,4.60,32.30,8.10 29400,29459,29430,10.50,4.60,35.30,8.70 29460,29519,29490,11.40,4.70,34.30,8.50 29520,29579,29550,13.90,5.00,30.50,7.80 29580,29639,29610,12.70,4.90,29.80,7.70 29640,29699,29670,11.70,4.80,31.30,8.00 29700,29759,29730,10.60,4.60,30.30,7.80 29760,29819,29790,12.30,4.80,29.60,7.60 29820,29879,29850,13.20,4.90,30.30,7.80 29880,29939,29910,15.10,5.20,32.00,8.10 29940,29999,29970,14.50,5.10,30.60,7.80 30000,30059,30030,13.50,5.00,30.70,7.90 30060,30119,30090,12.30,4.80,33.20,8.30 30120,30179,30150,10.30,4.60,35.60,8.80 30180,30239,30210,10.30,4.60,36.00,8.90 30240,30299,30270,10.60,4.60,35.10,8.70 30300,30359,30330,13.30,5.00,35.00,8.70 30360,30419,30390,14.80,5.20,35.00,8.70 30420,30479,30450,16.60,5.40,33.80,8.40 30480,30539,30510,17.30,5.50,40.50,9.80 30540,30599,30570,17.50,5.60,38.20,9.30 30600,30659,30630,22.60,6.40,49.70,11.60 30660,30719,30690,23.50,6.50,47.60,11.20 30720,30779,30750,24.10,6.60,53.40,12.40 30780,30839,30810,18.40,5.70,45.10,10.70 30840,30899,30870,17.10,5.50,41.60,10.00 30900,30959,30930,18.00,5.60,39.70,9.60 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