46,1001 Keutsch, Frank Department of Chemistry, University of Wisconsin - Madison Formaldehyde mixing ratios from chemistry tower BEACHON-ROCS 2010 1,1 2010829,2010829 30 time_MST, (fractional day of year in MST at midpoint of measurement, where Jan. 1, 12:00am = 1) 10 1,1,1,1,1,1,1,1,1,1 -999,-999,-999,-999,-999,-999,-999,-999,-999,-999 time_MST, fractional day of year date, date in mmddyy hours_MST, hour of day in MST minutes_MST, minutes of hour in MST seconds_MST, seconds of minute in MST start_TOD_MST, time of day in seconds since midnight until beginning of measurement averaging mean_TOD_MST, average time of day in seconds since midnight of measurement averaging stop_TOD_MST, time of day in seconds since midnight until end of measurement averaging Altitude_AGL_m, altitude Above Ground Level in meters HCHO_ppbv, Mixing ratio of formaldehyde in ppbv HCHO_precision_ppbv, 1 sigma precision of mixing ratio of formaldehyde in ppbv 3 Data is presented as 1/30 Hz gradient data. Air was sampled at multiple heights on tower, via ~100'-125' 1/2" OD unheated PFA tubing 2 m measurements sampled outside instrument trailer, height value +/- 0.5 m 18 PI_CONTACT_INFO: Address: UW-Madison Dept of Chemistry, 1101 University Ave, Madison WI 53706; email: keutsch@wisc.edu; 608-262-7904 PLATFORM: Chemistry Tower near Rocky Mountain Research Station in Manitou Experimental Forest, CO LOCATION: Manitou Experimental Forest, CO; lat: 38.099; lon: -105.101; elev: 2360m amsl. ASSOCIATED_DATA: N/A INSTRUMENT_INFO: Fiber Laser-Induced Fluorescence of Gas-Phase Formaldehyde DATA_INFO: all concentration data are in ppbv. Raw data were recorded at 1Hz. Most large gaps in data stream correspond to gradient data, presented in other files. Data were filtered for known errors, points removed by this filtering are considered "missing" and given -999 UNCERTAINTY: +/-(.1 m) altitude (except 2 m measurements-see special comments); +/- 30% concentration (accuracy); concentration precision reported in columns ULOD_FLAG: -777 ULOD_VALUE: N/A LLOD_FLAG: -888 LLOD_VALUE: N/A DM_CONTACT_INFO: Joshua DiGangi; UW-Madison Chemistry Dept.; digangi@wisc.edu; 608-262-0269 PROJECT_INFO: BEARPEX field intensive; 15 June - 31 July, 2009; CA Sierra Nevada. STIPULATIONS_ON_USE: Do not quote or present without permission. Please contact PI before use. OTHER_COMMENTS: For absolute concentration error, accuracy and precision errors must be propagated. Diagnostics (cell pressure, temperature, beam power) available upon request. REVISION: R0 R0: Calibration not finalized, accuracy should improve by next revision time_PST date hours minutes seconds start_TOD_MST mean_TOD_MST stop_TOD_MST Altitude_AGL_m HCHO_ppbv HCHO_precision_ppbv 241.000335 080510 0 0 28.934 12.840 28.934 45.052 25.1 1.726432 0.002376 241.000708 080510 0 1 1.134 45.052 61.134 77.263 25.1 1.718458 0.002376 241.001080 080510 0 1 33.334 77.263 93.334 109.475 25.1 1.695764 0.002376 241.001454 080510 0 2 5.584 109.475 125.584 141.687 25.1 1.724463 0.002373 241.001815 080510 0 2 36.790 109.475 125.584 141.687 25.1 -999 -999 241.002176 080510 0 3 7.996 109.475 125.584 141.687 25.1 -999 -999 241.002537 080510 0 3 39.202 109.475 125.584 141.687 25.1 -999 -999 241.003110 080510 0 4 28.734 253.578 268.734 283.961 25.1 1.644001 0.002259 241.003462 080510 0 4 59.134 283.961 299.134 314.344 25.1 1.665838 0.002259 241.003814 080510 0 5 29.534 314.344 329.534 344.728 25.1 1.664667 0.002259 241.004166 080510 0 5 59.934 344.728 359.934 375.111 25.1 1.661752 0.002259 241.004518 080510 0 6 30.334 375.111 390.334 405.494 25.1 1.613667 0.002259 241.004869 080510 0 7 0.684 405.494 420.684 435.877 25.1 1.659401 0.002263 241.005220 080510 0 7 31.034 435.877 451.034 466.260 25.1 1.633653 0.002259 241.005572 080510 0 8 1.434 466.260 481.434 496.644 25.1 1.638020 0.002259 241.005924 080510 0 8 31.834 496.644 511.834 527.027 25.1 1.632665 0.002259 241.006236 080510 0 8 58.778 527.027 538.778 557.410 25.1 1.583998 0.002978 241.006628 080510 0 9 32.634 557.410 572.634 587.793 25.1 1.639960 0.004183 241.006979 080510 0 10 2.984 587.793 602.984 618.176 25.1 1.570978 0.004190 241.007330 080510 0 10 33.334 618.176 633.334 648.560 25.1 1.575699 0.004183 241.007682 080510 0 11 3.734 648.560 663.734 678.943 25.1 1.577451 0.004183 241.008034 080510 0 11 34.134 678.943 694.134 709.326 25.1 1.548691 0.004183 241.008386 080510 0 12 4.534 709.326 724.534 739.709 25.1 1.518050 0.004183 241.008738 080510 0 12 34.934 739.709 754.934 770.092 25.1 1.560111 0.004183 241.009089 080510 0 13 5.284 770.092 785.284 800.476 25.1 1.535105 0.004190 241.009440 080510 0 13 35.634 800.476 815.634 830.859 25.1 1.575436 0.004183 241.009772 080510 0 14 4.319 830.859 844.319 861.242 25.1 1.569513 0.005080 241.010144 080510 0 14 36.419 861.242 876.419 891.625 25.1 1.530726 0.003984 241.010496 080510 0 15 6.834 891.625 906.834 922.008 25.1 1.561484 0.003977 241.010848 080510 0 15 37.234 922.008 937.234 952.392 25.1 1.616232 0.003978 241.011199 080510 0 16 7.584 952.392 967.584 982.775 25.1 1.606585 0.003984 241.011550 080510 0 16 37.934 982.775 997.934 1013.158 25.1 1.527961 0.003977 241.011902 080510 0 17 8.334 1013.158 1028.334 1043.541 25.1 1.579399 0.003978 241.012254 080510 0 17 38.734 1043.541 1058.734 1073.924 25.1 1.620635 0.003978 241.012606 080510 0 18 9.134 1073.924 1089.134 1104.308 25.1 1.623208 0.003978 241.012958 080510 0 18 39.534 1104.308 1119.534 1134.691 25.1 1.581835 0.003978 241.013309 080510 0 19 9.884 1134.691 1149.884 1165.074 25.1 1.605836 0.004825 241.013660 080510 0 19 40.234 1165.074 1180.234 1195.457 25.1 1.611073 0.003815 241.014012 080510 0 20 10.634 1195.457 1210.634 1225.841 25.1 1.653109 0.003815 241.014364 080510 0 20 41.034 1225.841 1241.034 1256.224 25.1 1.603964 0.003815 241.014716 080510 0 21 11.434 1256.224 1271.434 1286.607 25.1 1.655762 0.003815 241.015068 080510 0 21 41.834 1286.607 1301.834 1316.990 25.1 1.617281 0.003815 241.015419 080510 0 22 12.184 1316.990 1332.184 1347.373 25.1 1.595085 0.003822 241.015770 080510 0 22 42.534 1347.373 1362.534 1377.757 25.1 1.608210 0.003815 241.016122 080510 0 23 12.934 1377.757 1392.934 1408.140 25.1 1.609773 0.003815 241.016474 080510 0 23 43.334 1408.140 1423.334 1438.523 25.1 1.611874 0.003815 241.016846 080510 0 24 15.502 1438.523 1455.502 1468.906 25.1 1.515230 0.004334 241.017177 080510 0 24 44.134 1468.906 1484.134 1499.289 25.1 1.509995 0.003379 241.017529 080510 0 25 14.484 1499.289 1514.484 1529.673 25.1 1.493440 0.003384 241.017880 080510 0 25 44.834 1529.673 1544.834 1560.056 25.1 1.547614 0.003379 241.018232 080510 0 26 15.234 1560.056 1575.234 1590.439 25.1 1.518015 0.003379 241.018584 080510 0 26 45.634 1590.439 1605.634 1620.822 25.1 1.479536 0.003379 241.018936 080510 0 27 16.034 1620.822 1636.034 1651.205 25.1 1.537795 0.003379 241.019287 080510 0 27 46.434 1651.205 1666.434 1681.589 25.1 1.532564 0.003379 241.019639 080510 0 28 16.784 1681.589 1696.784 1711.972 25.1 1.539512 0.003384 241.019990 080510 0 28 47.134 1711.972 1727.134 1742.355 25.1 1.518792 0.003379 241.020382 080510 0 29 21.043 1742.355 1761.043 1772.738 25.1 1.484478 0.005120 241.020694 080510 0 29 47.956 1772.738 1787.956 1803.121 25.1 1.396037 0.004373 241.021046 080510 0 30 18.334 1803.121 1818.334 1833.505 25.1 1.399195 0.004366 241.021397 080510 0 30 48.684 1833.505 1848.684 1863.888 25.1 1.418376 0.004373 241.021748 080510 0 31 19.034 1863.888 1879.034 1894.271 25.1 1.458162 0.004366 241.022100 080510 0 31 49.434 1894.271 1909.434 1924.654 25.1 1.434497 0.004366 241.022452 080510 0 32 19.834 1924.654 1939.834 1955.037 25.1 1.452092 0.004366 241.022804 080510 0 32 50.234 1955.037 1970.234 1985.421 25.1 1.401024 0.004366 241.023155 080510 0 33 20.634 1985.421 2000.634 2015.804 25.1 1.422714 0.004366 241.023507 080510 0 33 51.034 2015.804 2031.034 2046.187 25.1 1.373713 0.004366 241.023869 080510 0 34 22.240 2015.804 2031.034 2046.187 25.1 -999 -999 241.024230 080510 0 34 53.446 2015.804 2031.034 2046.187 25.1 -999 -999 241.024591 080510 0 35 24.652 2015.804 2031.034 2046.187 25.1 -999 -999 241.025153 080510 0 36 13.234 2158.078 2173.234 2188.459 25.1 1.435129 0.003425 241.025505 080510 0 36 43.634 2188.459 2203.634 2218.841 25.1 1.454042 0.003425 241.025857 080510 0 37 14.034 2218.841 2234.034 2249.222 25.1 1.397928 0.003425 241.026209 080510 0 37 44.434 2249.222 2264.434 2279.603 25.1 1.417833 0.003425 241.026561 080510 0 38 14.834 2279.603 2294.834 2309.985 25.1 1.433381 0.003425 241.026912 080510 0 38 45.184 2309.985 2325.184 2340.366 25.1 1.385066 0.003431 241.027263 080510 0 39 15.534 2340.366 2355.534 2370.747 25.1 1.378227 0.003425 241.027615 080510 0 39 45.934 2370.747 2385.934 2401.129 25.1 1.378835 0.003425 241.027967 080510 0 40 16.334 2401.129 2416.334 2431.510 25.1 1.391082 0.003425 241.028279 080510 0 40 43.278 2431.510 2443.278 2461.892 25.1 1.417472 0.004442 241.028670 080510 0 41 17.084 2461.892 2477.084 2492.273 25.1 1.368593 0.005035 241.029021 080510 0 41 47.434 2492.273 2507.434 2522.654 25.1 1.357886 0.005026 241.029373 080510 0 42 17.834 2522.654 2537.834 2553.036 25.1 1.325974 0.005026 241.029725 080510 0 42 48.234 2553.036 2568.234 2583.417 25.1 1.335364 0.005026 241.030077 080510 0 43 18.634 2583.417 2598.634 2613.798 25.1 1.366875 0.005026 241.030428 080510 0 43 48.984 2613.798 2628.984 2644.180 25.1 1.369014 0.005035 241.030779 080510 0 44 19.334 2644.180 2659.334 2674.561 25.1 1.367794 0.005026 241.031131 080510 0 44 49.734 2674.561 2689.734 2704.942 25.1 1.334514 0.005026 241.031483 080510 0 45 20.134 2704.942 2720.134 2735.324 25.1 1.332532 0.005026 241.031815 080510 0 45 48.819 2735.324 2748.819 2765.705 25.1 1.403931 0.005129 241.032187 080510 0 46 20.934 2765.705 2780.934 2796.086 25.1 1.471970 0.003253 241.032538 080510 0 46 51.284 2796.086 2811.284 2826.468 25.1 1.464757 0.003258 241.032889 080510 0 47 21.634 2826.468 2841.634 2856.849 25.1 1.422824 0.003253 241.033241 080510 0 47 52.034 2856.849 2872.034 2887.231 25.1 1.414949 0.003253 241.033593 080510 0 48 22.434 2887.231 2902.434 2917.612 25.1 1.457605 0.003253 241.033945 080510 0 48 52.834 2917.612 2932.834 2947.993 25.1 1.441838 0.003253 241.034296 080510 0 49 23.184 2947.993 2963.184 2978.375 25.1 1.472090 0.003258 241.034647 080510 0 49 53.534 2978.375 2993.534 3008.756 25.1 1.408843 0.003253 241.034999 080510 0 50 23.934 3008.756 3023.934 3039.137 25.1 1.449432 0.003253 241.035351 080510 0 50 54.360 3039.137 3054.360 3069.519 25.1 1.388979 0.004156 241.035703 080510 0 51 24.734 3069.519 3084.734 3099.900 25.1 1.314418 0.003482 241.036055 080510 0 51 55.134 3099.900 3115.134 3130.281 25.1 1.330768 0.003482 241.036406 080510 0 52 25.484 3130.281 3145.484 3160.663 25.1 1.267112 0.003488 241.036757 080510 0 52 55.834 3160.663 3175.834 3191.044 25.1 1.306949 0.003482 241.037109 080510 0 53 26.234 3191.044 3206.234 3221.425 25.1 1.387432 0.003483 241.037461 080510 0 53 56.634 3221.425 3236.634 3251.807 25.1 1.313491 0.003482 241.037812 080510 0 54 26.987 3251.807 3266.987 3282.188 25.1 1.299466 0.003488 241.038164 080510 0 54 57.384 3282.188 3297.384 3312.570 25.1 1.310591 0.003488 241.038515 080510 0 55 27.734 3312.570 3327.734 3342.951 25.1 1.318087 0.003482 241.038887 080510 0 55 59.849 3342.951 3359.849 3373.332 25.1 1.392142 0.004567 241.039219 080510 0 56 28.534 3373.332 3388.534 3403.714 25.1 1.405950 0.003819 241.039571 080510 0 56 58.934 3403.714 3418.934 3434.095 25.1 1.382783 0.003819 241.039922 080510 0 57 29.284 3434.095 3449.284 3464.476 25.1 1.391470 0.003825 241.040274 080510 0 57 59.634 3464.476 3479.634 3494.858 25.1 1.342244 0.003818 241.040625 080510 0 58 30.034 3494.858 3510.034 3525.239 25.1 1.345801 0.003818 241.040977 080510 0 59 0.434 3525.239 3540.434 3555.620 25.1 1.390676 0.003819 241.041329 080510 0 59 30.834 3555.620 3570.834 3586.002 25.1 1.339177 0.003818 241.041680 080510 1 0 1.184 3586.002 3601.184 3616.383 25.1 1.351036 0.003825 241.042032 080510 1 0 31.534 3616.383 3631.534 3646.764 25.1 1.356893 0.003818 241.042423 080510 1 1 5.390 3646.764 3665.390 3677.146 25.1 1.335205 0.005315 241.042735 080510 1 1 32.334 3677.146 3692.334 3707.527 25.1 1.325589 0.004425 241.043087 080510 1 2 2.734 3707.527 3722.734 3737.909 25.1 1.340223 0.004425 241.043439 080510 1 2 33.134 3737.909 3753.134 3768.290 25.1 1.297568 0.004425 241.043790 080510 1 3 3.484 3768.290 3783.484 3798.671 25.1 1.347752 0.004432 241.044142 080510 1 3 33.834 3798.671 3813.834 3829.053 25.1 1.348154 0.004425 241.044493 080510 1 4 4.234 3829.053 3844.234 3859.434 25.1 1.281158 0.004425 241.044845 080510 1 4 34.634 3859.434 3874.634 3889.815 25.1 1.268211 0.004425 241.045197 080510 1 5 5.034 3889.815 3905.034 3920.197 25.1 1.361550 0.004425 241.045549 080510 1 5 35.434 3920.197 3935.434 3950.578 25.1 1.344918 0.004425 241.045910 080510 1 6 6.640 3920.197 3935.434 3950.578 25.1 -999 -999 241.046271 080510 1 6 37.846 3920.197 3935.434 3950.578 25.1 -999 -999 241.046633 080510 1 7 9.052 3920.197 3935.434 3950.578 25.1 -999 -999 241.047196 080510 1 7 57.734 4062.578 4077.734 4092.961 25.1 1.299643 0.002567 241.047548 080510 1 8 28.134 4092.961 4108.134 4123.344 25.1 1.320670 0.002567 241.047900 080510 1 8 58.534 4123.344 4138.534 4153.728 25.1 1.299327 0.002567 241.048251 080510 1 9 28.893 4153.728 4168.893 4184.111 25.1 1.293009 0.002572 241.048603 080510 1 9 59.334 4184.111 4199.334 4214.494 25.1 1.290703 0.002567 241.048955 080510 1 10 29.684 4214.494 4229.684 4244.877 25.1 1.286642 0.002572 241.049306 080510 1 11 0.034 4244.877 4260.034 4275.260 25.1 1.327630 0.002567 241.049658 080510 1 11 30.434 4275.260 4290.434 4305.644 25.1 1.267806 0.002567 241.050010 080510 1 12 0.834 4305.644 4320.834 4336.027 25.1 1.293324 0.002567 241.050321 080510 1 12 27.725 4336.027 4347.725 4366.410 25.1 1.277288 0.003323 241.050713 080510 1 13 1.634 4366.410 4381.634 4396.793 25.1 1.248831 0.003746 241.051065 080510 1 13 31.984 4396.793 4411.984 4427.176 25.1 1.218574 0.003752 241.051416 080510 1 14 2.334 4427.176 4442.334 4457.560 25.1 1.259784 0.003746 241.051768 080510 1 14 32.734 4457.560 4472.734 4487.943 25.1 1.202749 0.003746 241.052120 080510 1 15 3.134 4487.943 4503.134 4518.326 25.1 1.206556 0.003746 241.052471 080510 1 15 33.534 4518.326 4533.534 4548.709 25.1 1.221863 0.003746 241.052823 080510 1 16 3.934 4548.709 4563.934 4579.092 25.1 1.209781 0.003746 241.053175 080510 1 16 34.284 4579.092 4594.284 4609.476 25.1 1.204992 0.003752 241.053526 080510 1 17 4.634 4609.476 4624.634 4639.859 25.1 1.234491 0.003746 241.053857 080510 1 17 33.266 4639.859 4653.266 4670.242 25.1 1.241256 0.004609 241.054230 080510 1 18 5.434 4670.242 4685.434 4700.625 25.1 1.383643 0.003696 241.054581 080510 1 18 35.834 4700.625 4715.834 4731.008 25.1 1.345968 0.003696 241.054933 080510 1 19 6.234 4731.008 4746.234 4761.392 25.1 1.320341 0.003696 241.055285 080510 1 19 36.584 4761.392 4776.584 4791.775 25.1 1.344016 0.003702 241.055636 080510 1 20 6.934 4791.775 4806.934 4822.158 25.1 1.317568 0.003696 241.055988 080510 1 20 37.334 4822.158 4837.334 4852.541 25.1 1.316566 0.003696 241.056340 080510 1 21 7.734 4852.541 4867.734 4882.924 25.1 1.307278 0.003696 241.056691 080510 1 21 38.134 4882.924 4898.134 4913.308 25.1 1.329806 0.003696 241.057043 080510 1 22 8.534 4913.308 4928.534 4943.691 25.1 1.285793 0.003696 241.057394 080510 1 22 38.884 4943.691 4958.884 4974.074 25.1 1.280054 0.003355 241.057746 080510 1 23 9.234 4974.074 4989.234 5004.457 25.1 1.260835 0.002238 241.058098 080510 1 23 39.634 5004.457 5019.634 5034.841 25.1 1.307607 0.002238 241.058449 080510 1 24 10.034 5034.841 5050.034 5065.224 25.1 1.297908 0.002238 241.058801 080510 1 24 40.434 5065.224 5080.434 5095.607 25.1 1.287023 0.002238 241.059153 080510 1 25 10.834 5095.607 5110.834 5125.990 25.1 1.310273 0.002239 241.059504 080510 1 25 41.184 5125.990 5141.184 5156.373 25.1 1.293668 0.002242 241.059856 080510 1 26 11.534 5156.373 5171.534 5186.757 25.1 1.283196 0.002238 241.060208 080510 1 26 41.934 5186.757 5201.934 5217.140 25.1 1.268751 0.002238 241.060559 080510 1 27 12.334 5217.140 5232.334 5247.523 25.1 1.271118 0.002238 241.060932 080510 1 27 44.501 5247.523 5264.501 5277.906 25.1 1.306741 0.003572 241.061263 080510 1 28 13.134 5277.906 5293.134 5308.289 25.1 1.269767 0.003519 241.061614 080510 1 28 43.484 5308.289 5323.484 5338.673 25.1 1.264125 0.003525 241.061966 080510 1 29 13.834 5338.673 5353.834 5369.056 25.1 1.249901 0.003519 241.062318 080510 1 29 44.234 5369.056 5384.234 5399.439 25.1 1.285674 0.003520 241.062669 080510 1 30 14.634 5399.439 5414.634 5429.822 25.1 1.294319 0.003520 241.063021 080510 1 30 45.034 5429.822 5445.034 5460.205 25.1 1.267272 0.003520 241.063373 080510 1 31 15.434 5460.205 5475.434 5490.589 25.1 1.243627 0.003520 241.063724 080510 1 31 45.784 5490.589 5505.784 5520.972 25.1 1.244074 0.003525 241.064076 080510 1 32 16.134 5520.972 5536.134 5551.355 25.1 1.286254 0.003520 241.064467 080510 1 32 49.990 5551.355 5569.990 5581.738 25.1 1.166484 0.005005 241.064779 080510 1 33 16.934 5581.738 5596.934 5612.121 25.1 1.096831 0.004192 241.065131 080510 1 33 47.334 5612.121 5627.334 5642.505 25.1 1.096899 0.004192 241.065482 080510 1 34 17.684 5642.505 5657.684 5672.888 25.1 1.092371 0.004199 241.065834 080510 1 34 48.034 5672.888 5688.034 5703.271 25.1 1.126458 0.004192 241.066186 080510 1 35 18.434 5703.271 5718.434 5733.654 25.1 1.126125 0.004192 241.066537 080510 1 35 48.834 5733.654 5748.834 5764.037 25.1 1.104343 0.004192 241.066889 080510 1 36 19.234 5764.037 5779.234 5794.421 25.1 1.143072 0.004192 241.067241 080510 1 36 49.634 5794.421 5809.634 5824.804 25.1 1.134080 0.004192 241.067593 080510 1 37 20.034 5824.804 5840.034 5855.187 25.1 1.066580 0.004192 241.067954 080510 1 37 51.240 5824.804 5840.034 5855.187 25.1 -999 -999 241.068315 080510 1 38 22.446 5824.804 5840.034 5855.187 25.1 -999 -999 241.068677 080510 1 38 53.652 5824.804 5840.034 5855.187 25.1 -999 -999 241.069240 080510 1 39 42.334 5967.187 5982.334 5997.568 25.1 1.315304 0.003168 241.069592 080510 1 40 12.734 5997.568 6012.734 6027.950 25.1 1.253059 0.003168 241.069944 080510 1 40 43.134 6027.950 6043.134 6058.331 25.1 1.271123 0.003168 241.070296 080510 1 41 13.534 6058.331 6073.534 6088.712 25.1 1.284969 0.003168 241.070647 080510 1 41 43.934 6088.712 6103.934 6119.094 25.1 1.289876 0.003168 241.070999 080510 1 42 14.284 6119.094 6134.284 6149.475 25.1 1.301003 0.003174 241.071350 080510 1 42 44.634 6149.475 6164.634 6179.856 25.1 1.307330 0.003168 241.071702 080510 1 43 15.034 6179.856 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