46,1001 Keutsch, Frank Department of Chemistry, University of Wisconsin - Madison Formaldehyde mixing ratios from chemistry tower BEACHON-ROCS 2010 1,1 2010825,2010825 30 time_MST, (fractional day of year in MST at midpoint of measurement, where Jan. 1, 12:00am = 1) 10 1,1,1,1,1,1,1,1,1,1 -999,-999,-999,-999,-999,-999,-999,-999,-999,-999 time_MST, fractional day of year date, date in mmddyy hours_MST, hour of day in MST minutes_MST, minutes of hour in MST seconds_MST, seconds of minute in MST start_TOD_MST, time of day in seconds since midnight until beginning of measurement averaging mean_TOD_MST, average time of day in seconds since midnight of measurement averaging stop_TOD_MST, time of day in seconds since midnight until end of measurement averaging Altitude_AGL_m, altitude Above Ground Level in meters HCHO_ppbv, Mixing ratio of formaldehyde in ppbv HCHO_precision_ppbv, 1 sigma precision of mixing ratio of formaldehyde in ppbv 3 Data is presented as 1/30 Hz gradient data. Air was sampled at multiple heights on tower, via ~100'-125' 1/2" OD unheated PFA tubing 2 m measurements sampled outside instrument trailer, height value +/- 0.5 m 18 PI_CONTACT_INFO: Address: UW-Madison Dept of Chemistry, 1101 University Ave, Madison WI 53706; email: keutsch@wisc.edu; 608-262-7904 PLATFORM: Chemistry Tower near Rocky Mountain Research Station in Manitou Experimental Forest, CO LOCATION: Manitou Experimental Forest, CO; lat: 38.099; lon: -105.101; elev: 2360m amsl. ASSOCIATED_DATA: N/A INSTRUMENT_INFO: Fiber Laser-Induced Fluorescence of Gas-Phase Formaldehyde DATA_INFO: all concentration data are in ppbv. Raw data were recorded at 1Hz. Most large gaps in data stream correspond to gradient data, presented in other files. Data were filtered for known errors, points removed by this filtering are considered "missing" and given -999 UNCERTAINTY: +/-(.1 m) altitude (except 2 m measurements-see special comments); +/- 30% concentration (accuracy); concentration precision reported in columns ULOD_FLAG: -777 ULOD_VALUE: N/A LLOD_FLAG: -888 LLOD_VALUE: N/A DM_CONTACT_INFO: Joshua DiGangi; UW-Madison Chemistry Dept.; digangi@wisc.edu; 608-262-0269 PROJECT_INFO: BEARPEX field intensive; 15 June - 31 July, 2009; CA Sierra Nevada. STIPULATIONS_ON_USE: Do not quote or present without permission. Please contact PI before use. OTHER_COMMENTS: For absolute concentration error, accuracy and precision errors must be propagated. Diagnostics (cell pressure, temperature, beam power) available upon request. REVISION: R0 R0: Calibration not finalized, accuracy should improve by next revision time_PST date hours minutes seconds start_TOD_MST mean_TOD_MST stop_TOD_MST Altitude_AGL_m HCHO_ppbv HCHO_precision_ppbv 237.000117 080510 0 0 10.137 -5.364 10.137 25.709 25.1 1.033284 0.003583 237.000477 080510 0 0 41.237 25.709 41.237 56.782 25.1 1.071503 0.003583 237.000837 080510 0 1 12.337 56.782 72.337 87.855 25.1 1.076603 0.003583 237.001197 080510 0 1 43.387 87.855 103.387 118.929 25.1 1.083707 0.003589 237.001556 080510 0 2 14.437 118.929 134.437 150.002 25.1 1.079716 0.003583 237.001916 080510 0 2 45.537 150.002 165.537 181.075 25.1 1.062140 0.003691 237.002276 080510 0 3 16.637 181.075 196.637 212.148 25.1 1.028102 0.002637 237.002635 080510 0 3 47.687 212.148 227.687 243.222 25.1 1.006125 0.002642 237.002995 080510 0 4 18.737 243.222 258.737 274.295 25.1 1.012314 0.002637 237.003355 080510 0 4 49.837 274.295 289.837 305.368 25.1 1.020682 0.002637 237.003715 080510 0 5 20.937 305.368 320.937 336.441 25.1 1.008682 0.002637 237.004074 080510 0 5 51.987 336.441 351.987 367.514 25.1 0.975252 0.002642 237.004433 080510 0 6 23.037 367.514 383.037 398.588 25.1 1.012685 0.002637 237.004793 080510 0 6 54.137 398.588 414.137 429.661 25.1 1.012046 0.002637 237.005153 080510 0 7 25.237 429.661 445.237 460.734 25.1 1.010621 0.002637 237.005514 080510 0 7 56.443 429.661 445.237 460.734 25.1 -999 -999 237.005876 080510 0 8 27.649 429.661 445.237 460.734 25.1 -999 -999 237.006237 080510 0 8 58.855 429.661 445.237 460.734 25.1 -999 -999 237.006804 080510 0 9 47.887 572.734 587.887 603.115 25.1 0.933969 0.003221 237.007156 080510 0 10 18.287 603.115 618.287 633.497 25.1 0.967505 0.003221 237.007508 080510 0 10 48.687 633.497 648.687 663.878 25.1 0.961881 0.003221 237.007860 080510 0 11 19.087 663.878 679.087 694.259 25.1 0.958239 0.003221 237.008212 080510 0 11 49.487 694.259 709.487 724.641 25.1 0.975756 0.003221 237.008563 080510 0 12 19.837 724.641 739.837 755.022 25.1 0.961495 0.003226 237.008914 080510 0 12 50.187 755.022 770.187 785.403 25.1 0.950319 0.003221 237.009266 080510 0 13 20.587 785.403 800.587 815.785 25.1 0.931969 0.003221 237.009618 080510 0 13 50.987 815.785 830.987 846.166 25.1 0.984401 0.003221 237.009930 080510 0 14 17.931 846.166 857.931 876.548 25.1 0.938004 0.003863 237.010321 080510 0 14 51.737 876.548 891.737 906.929 25.1 0.973790 0.002765 237.010672 080510 0 15 22.087 906.929 922.087 937.310 25.1 0.996455 0.002761 237.011024 080510 0 15 52.487 937.310 952.487 967.692 25.1 0.994668 0.002761 237.011376 080510 0 16 22.887 967.692 982.887 998.073 25.1 0.959338 0.002761 237.011728 080510 0 16 53.287 998.073 1013.287 1028.454 25.1 0.988823 0.002761 237.012079 080510 0 17 23.637 1028.454 1043.637 1058.836 25.1 0.984887 0.002765 237.012430 080510 0 17 53.987 1058.836 1073.987 1089.217 25.1 1.001058 0.002761 237.012782 080510 0 18 24.387 1089.217 1104.387 1119.598 25.1 1.009622 0.002761 237.013134 080510 0 18 54.787 1119.598 1134.787 1149.980 25.1 0.957945 0.002761 237.013466 080510 0 19 23.472 1149.980 1163.472 1180.361 25.1 1.026383 0.003454 237.013838 080510 0 19 55.587 1180.361 1195.587 1210.742 25.1 1.008987 0.002864 237.014189 080510 0 20 25.937 1210.742 1225.937 1241.124 25.1 0.987584 0.002869 237.014540 080510 0 20 56.287 1241.124 1256.287 1271.505 25.1 0.986276 0.002864 237.014892 080510 0 21 26.687 1271.505 1286.687 1301.887 25.1 0.993759 0.002864 237.015244 080510 0 21 57.087 1301.887 1317.087 1332.268 25.1 1.016737 0.002864 237.015596 080510 0 22 27.487 1332.268 1347.487 1362.649 25.1 1.001350 0.002864 237.015947 080510 0 22 57.837 1362.649 1377.837 1393.031 25.1 1.002414 0.002869 237.016298 080510 0 23 28.187 1393.031 1408.187 1423.412 25.1 0.961693 0.002864 237.016650 080510 0 23 58.587 1423.412 1438.587 1453.793 25.1 1.024860 0.002864 237.017002 080510 0 24 29.005 1453.793 1469.005 1484.175 25.1 1.023487 0.003552 237.017354 080510 0 24 59.387 1484.175 1499.387 1514.556 25.1 0.980481 0.002870 237.017706 080510 0 25 29.787 1514.556 1529.787 1544.937 25.1 1.012526 0.002870 237.018057 080510 0 26 0.137 1544.937 1560.137 1575.319 25.1 1.017737 0.002874 237.018408 080510 0 26 30.487 1575.319 1590.487 1605.700 25.1 0.987683 0.002870 237.018760 080510 0 27 0.887 1605.700 1620.887 1636.081 25.1 1.019154 0.002870 237.019112 080510 0 27 31.287 1636.081 1651.287 1666.463 25.1 1.034783 0.002870 237.019464 080510 0 28 1.687 1666.463 1681.687 1696.844 25.1 1.009230 0.002870 237.019815 080510 0 28 32.037 1696.844 1712.037 1727.226 25.1 1.034036 0.002874 237.020167 080510 0 29 2.387 1727.226 1742.387 1757.607 25.1 1.021541 0.002870 237.020538 080510 0 29 34.502 1757.607 1774.502 1787.988 25.1 1.002628 0.003826 237.020870 080510 0 30 3.187 1787.988 1803.187 1818.370 25.1 0.994497 0.003233 237.021222 080510 0 30 33.587 1818.370 1833.587 1848.751 25.1 1.001552 0.003233 237.021573 080510 0 31 3.937 1848.751 1863.937 1879.132 25.1 0.986759 0.003238 237.021925 080510 0 31 34.287 1879.132 1894.287 1909.514 25.1 0.972327 0.003233 237.022276 080510 0 32 4.687 1909.514 1924.687 1939.895 25.1 0.989965 0.003233 237.022628 080510 0 32 35.087 1939.895 1955.087 1970.276 25.1 1.000550 0.003233 237.022980 080510 0 33 5.487 1970.276 1985.487 2000.658 25.1 0.990460 0.003233 237.023332 080510 0 33 35.887 2000.658 2015.887 2031.039 25.1 0.987956 0.003233 237.023683 080510 0 34 6.237 2031.039 2046.237 2061.420 25.1 0.997331 0.003238 237.024075 080510 0 34 40.043 2061.420 2080.043 2091.802 25.1 1.045524 0.004224 237.024386 080510 0 35 6.987 2091.802 2106.987 2122.183 25.1 1.024909 0.003460 237.024738 080510 0 35 37.387 2122.183 2137.387 2152.565 25.1 1.072841 0.003460 237.025090 080510 0 36 7.787 2152.565 2167.787 2182.946 25.1 1.038676 0.003460 237.025441 080510 0 36 38.137 2182.946 2198.137 2213.327 25.1 1.064375 0.003466 237.025793 080510 0 37 8.487 2213.327 2228.487 2243.709 25.1 1.077920 0.003460 237.026145 080510 0 37 38.887 2243.709 2258.887 2274.090 25.1 1.032808 0.003460 237.026496 080510 0 38 9.287 2274.090 2289.287 2304.471 25.1 1.026821 0.003460 237.026848 080510 0 38 39.687 2304.471 2319.687 2334.853 25.1 1.049835 0.003460 237.027200 080510 0 39 10.087 2334.853 2350.087 2365.234 25.1 1.012510 0.003460 237.027561 080510 0 39 41.293 2334.853 2350.087 2365.234 25.1 -999 -999 237.027922 080510 0 40 12.499 2334.853 2350.087 2365.234 25.1 -999 -999 237.028284 080510 0 40 43.705 2334.853 2350.087 2365.234 25.1 -999 -999 237.028847 080510 0 41 32.387 2477.234 2492.387 2507.615 25.1 1.118536 0.003251 237.029199 080510 0 42 2.787 2507.615 2522.787 2537.997 25.1 1.129332 0.003251 237.029551 080510 0 42 33.187 2537.997 2553.187 2568.378 25.1 1.139238 0.003251 237.029903 080510 0 43 3.587 2568.378 2583.587 2598.759 25.1 1.142141 0.003251 237.030254 080510 0 43 33.987 2598.759 2613.987 2629.141 25.1 1.126265 0.003251 237.030606 080510 0 44 4.337 2629.141 2644.337 2659.522 25.1 1.117909 0.003256 237.030957 080510 0 44 34.687 2659.522 2674.687 2689.903 25.1 1.111171 0.003251 237.031309 080510 0 45 5.087 2689.903 2705.087 2720.285 25.1 1.123483 0.003251 237.031661 080510 0 45 35.487 2720.285 2735.487 2750.666 25.1 1.094656 0.003250 237.031973 080510 0 46 2.431 2750.666 2762.431 2781.048 25.1 1.020760 0.004080 237.032364 080510 0 46 36.237 2781.048 2796.237 2811.429 25.1 0.919143 0.003592 237.032715 080510 0 47 6.587 2811.429 2826.587 2841.810 25.1 0.926192 0.003586 237.033067 080510 0 47 36.987 2841.810 2856.987 2872.192 25.1 0.915562 0.003586 237.033419 080510 0 48 7.387 2872.192 2887.387 2902.573 25.1 0.901085 0.003586 237.033771 080510 0 48 37.787 2902.573 2917.787 2932.954 25.1 0.931052 0.003586 237.034121 080510 0 49 8.097 2932.954 2948.097 2963.336 25.1 0.909287 0.003598 237.034473 080510 0 49 38.487 2963.336 2978.487 2993.717 25.1 0.923448 0.003586 237.034825 080510 0 50 8.887 2993.717 3008.887 3024.098 25.1 0.913519 0.003586 237.035177 080510 0 50 39.287 3024.098 3039.287 3054.480 25.1 0.934932 0.003586 237.035508 080510 0 51 7.919 3054.480 3067.919 3084.861 25.1 0.956484 0.003898 237.035881 080510 0 51 40.087 3084.861 3100.087 3115.242 25.1 1.002041 0.002613 237.036232 080510 0 52 10.437 3115.242 3130.437 3145.624 25.1 0.983235 0.002617 237.036583 080510 0 52 40.787 3145.624 3160.787 3176.005 25.1 1.013215 0.002613 237.036935 080510 0 53 11.187 3176.005 3191.187 3206.387 25.1 0.983986 0.002613 237.037287 080510 0 53 41.587 3206.387 3221.587 3236.768 25.1 0.989772 0.002613 237.037639 080510 0 54 11.987 3236.768 3251.987 3267.149 25.1 0.991585 0.002613 237.037990 080510 0 54 42.337 3267.149 3282.337 3297.531 25.1 0.964161 0.002617 237.038341 080510 0 55 12.687 3297.531 3312.687 3327.912 25.1 0.953706 0.002613 237.038693 080510 0 55 43.087 3327.912 3343.087 3358.293 25.1 1.015460 0.002613 237.039045 080510 0 56 13.461 3358.293 3373.461 3388.675 25.1 0.956106 0.003394 237.039397 080510 0 56 43.887 3388.675 3403.887 3419.056 25.1 0.911308 0.002904 237.039749 080510 0 57 14.287 3419.056 3434.287 3449.437 25.1 0.978198 0.002904 237.040100 080510 0 57 44.637 3449.437 3464.637 3479.819 25.1 0.972368 0.002908 237.040451 080510 0 58 14.987 3479.819 3494.987 3510.200 25.1 0.949678 0.002904 237.040803 080510 0 58 45.387 3510.200 3525.387 3540.581 25.1 0.943704 0.002904 237.041155 080510 0 59 15.787 3540.581 3555.787 3570.963 25.1 0.936870 0.002904 237.041507 080510 0 59 46.187 3570.963 3586.187 3601.344 25.1 0.988403 0.002904 237.041858 080510 1 0 16.537 3601.344 3616.537 3631.726 25.1 0.944581 0.002908 237.042209 080510 1 0 46.887 3631.726 3646.887 3662.107 25.1 0.969171 0.002904 237.042581 080510 1 1 19.002 3662.107 3679.002 3692.488 25.1 0.975844 0.004228 237.042913 080510 1 1 47.687 3692.488 3707.687 3722.870 25.1 0.969853 0.003817 237.043265 080510 1 2 18.087 3722.870 3738.087 3753.251 25.1 0.970517 0.003817 237.043616 080510 1 2 48.437 3753.251 3768.437 3783.632 25.1 0.971197 0.003823 237.043967 080510 1 3 18.787 3783.632 3798.787 3814.014 25.1 0.954329 0.003817 237.044319 080510 1 3 49.187 3814.014 3829.187 3844.395 25.1 0.934344 0.003817 237.044671 080510 1 4 19.587 3844.395 3859.587 3874.776 25.1 0.974941 0.003817 237.045023 080510 1 4 49.987 3874.776 3889.987 3905.158 25.1 0.957125 0.003817 237.045375 080510 1 5 20.387 3905.158 3920.387 3935.539 25.1 0.960483 0.003817 237.045726 080510 1 5 50.737 3935.539 3950.737 3965.920 25.1 0.933857 0.003823 237.046117 080510 1 6 24.543 3965.920 3984.543 3996.302 25.1 0.988872 0.004543 237.046429 080510 1 6 51.487 3996.302 4011.487 4026.683 25.1 0.967018 0.003648 237.046781 080510 1 7 21.887 4026.683 4041.887 4057.065 25.1 0.981025 0.003648 237.047133 080510 1 7 52.287 4057.065 4072.287 4087.446 25.1 0.970445 0.003648 237.047484 080510 1 8 22.637 4087.446 4102.637 4117.827 25.1 0.972499 0.003654 237.047835 080510 1 8 52.987 4117.827 4132.987 4148.209 25.1 0.957542 0.003648 237.048187 080510 1 9 23.387 4148.209 4163.387 4178.590 25.1 0.971629 0.003648 237.048539 080510 1 9 53.787 4178.590 4193.787 4208.971 25.1 0.974395 0.003648 237.048891 080510 1 10 24.187 4208.971 4224.187 4239.353 25.1 0.936266 0.003648 237.049243 080510 1 10 54.587 4239.353 4254.587 4269.734 25.1 0.945121 0.003648 237.049604 080510 1 11 25.793 4239.353 4254.587 4269.734 25.1 -999 -999 237.049965 080510 1 11 56.999 4239.353 4254.587 4269.734 25.1 -999 -999 237.050326 080510 1 12 28.205 4239.353 4254.587 4269.734 25.1 -999 -999 237.050891 080510 1 13 16.987 4381.843 4396.987 4412.224 25.1 0.953010 0.003085 237.051243 080510 1 13 47.387 4412.224 4427.387 4442.606 25.1 0.979363 0.003086 237.051595 080510 1 14 17.787 4442.606 4457.787 4472.987 25.1 0.986921 0.003086 237.051947 080510 1 14 48.187 4472.987 4488.187 4503.368 25.1 0.978117 0.003086 237.052298 080510 1 15 18.587 4503.368 4518.587 4533.750 25.1 0.993132 0.003086 237.052650 080510 1 15 48.937 4533.750 4548.937 4564.131 25.1 1.001161 0.003091 237.053001 080510 1 16 19.287 4564.131 4579.287 4594.512 25.1 0.972314 0.003086 237.053353 080510 1 16 49.687 4594.512 4609.687 4624.894 25.1 0.986839 0.003086 237.053705 080510 1 17 20.087 4624.894 4640.087 4655.275 25.1 0.982542 0.003086 237.054017 080510 1 17 47.031 4655.275 4667.031 4685.657 25.1 1.010419 0.003933 237.054408 080510 1 18 20.887 4685.657 4700.887 4716.038 25.1 1.050184 0.003824 237.054760 080510 1 18 51.237 4716.038 4731.237 4746.419 25.1 1.026129 0.003830 237.055111 080510 1 19 21.590 4746.419 4761.590 4776.801 25.1 1.015483 0.003831 237.055463 080510 1 19 51.987 4776.801 4791.987 4807.182 25.1 1.029833 0.003824 237.055815 080510 1 20 22.387 4807.182 4822.387 4837.563 25.1 0.996850 0.003824 237.056167 080510 1 20 52.787 4837.563 4852.787 4867.945 25.1 1.039465 0.003824 237.056518 080510 1 21 23.137 4867.945 4883.137 4898.326 25.1 1.014681 0.003831 237.056869 080510 1 21 53.487 4898.326 4913.487 4928.707 25.1 1.015130 0.003824 237.057221 080510 1 22 23.887 4928.707 4943.887 4959.089 25.1 1.030579 0.003824 237.057552 080510 1 22 52.519 4959.089 4972.519 4989.470 25.1 1.022284 0.004438 237.057925 080510 1 23 24.687 4989.470 5004.687 5019.851 25.1 1.037808 0.003226 237.058276 080510 1 23 55.037 5019.851 5035.037 5050.233 25.1 1.034724 0.003231 237.058627 080510 1 24 25.387 5050.233 5065.387 5080.614 25.1 1.037095 0.003226 237.058979 080510 1 24 55.787 5080.614 5095.787 5110.996 25.1 1.043549 0.003226 237.059331 080510 1 25 26.187 5110.996 5126.187 5141.377 25.1 1.075240 0.003226 237.059683 080510 1 25 56.587 5141.377 5156.587 5171.758 25.1 1.056356 0.003226 237.060034 080510 1 26 26.937 5171.758 5186.937 5202.140 25.1 1.045708 0.003231 237.060385 080510 1 26 57.287 5202.140 5217.287 5232.521 25.1 1.038726 0.003226 237.060737 080510 1 27 27.687 5232.521 5247.687 5262.902 25.1 1.050426 0.003226 237.061089 080510 1 27 58.061 5262.902 5278.061 5293.284 25.1 1.065334 0.003868 237.061441 080510 1 28 28.487 5293.284 5308.487 5323.665 25.1 1.075452 0.003040 237.061793 080510 1 28 58.887 5323.665 5338.887 5354.046 25.1 1.070036 0.003040 237.062144 080510 1 29 29.237 5354.046 5369.237 5384.428 25.1 1.099998 0.003045 237.062495 080510 1 29 59.587 5384.428 5399.587 5414.809 25.1 1.077289 0.003040 237.062847 080510 1 30 29.987 5414.809 5429.987 5445.190 25.1 1.022120 0.003040 237.063199 080510 1 31 0.387 5445.190 5460.387 5475.572 25.1 1.097798 0.003040 237.063551 080510 1 31 30.787 5475.572 5490.787 5505.953 25.1 1.095845 0.003040 237.063902 080510 1 32 1.137 5505.953 5521.137 5536.335 25.1 1.113421 0.003045 237.064253 080510 1 32 31.487 5536.335 5551.487 5566.716 25.1 1.085466 0.003040 237.064625 080510 1 33 3.602 5566.716 5583.602 5597.097 25.1 0.972984 0.004398 237.064957 080510 1 33 32.287 5597.097 5612.287 5627.479 25.1 0.912024 0.003947 237.065309 080510 1 34 2.687 5627.479 5642.687 5657.860 25.1 0.893252 0.003947 237.065661 080510 1 34 33.087 5657.860 5673.087 5688.241 25.1 0.888773 0.003948 237.066012 080510 1 35 3.437 5688.241 5703.437 5718.623 25.1 0.895549 0.003954 237.066363 080510 1 35 33.787 5718.623 5733.787 5749.004 25.1 0.889691 0.003948 237.066715 080510 1 36 4.187 5749.004 5764.187 5779.385 25.1 0.893089 0.003948 237.067067 080510 1 36 34.587 5779.385 5794.587 5809.767 25.1 0.865883 0.003948 237.067419 080510 1 37 4.987 5809.767 5824.987 5840.148 25.1 0.855006 0.003948 237.067770 080510 1 37 35.337 5840.148 5855.337 5870.529 25.1 0.862161 0.003954 237.068161 080510 1 38 9.143 5870.529 5889.143 5900.911 25.1 1.015753 0.003388 237.068473 080510 1 38 36.087 5900.911 5916.087 5931.292 25.1 1.008712 0.002606 237.068825 080510 1 39 6.487 5931.292 5946.487 5961.674 25.1 1.026299 0.002606 237.069177 080510 1 39 36.887 5961.674 5976.887 5992.055 25.1 1.023027 0.002606 237.069528 080510 1 40 7.237 5992.055 6007.237 6022.436 25.1 1.048364 0.002610 237.069879 080510 1 40 37.587 6022.436 6037.587 6052.818 25.1 1.067916 0.002606 237.070231 080510 1 41 7.987 6052.818 6067.987 6083.199 25.1 1.033357 0.002606 237.070583 080510 1 41 38.387 6083.199 6098.387 6113.580 25.1 1.055347 0.002606 237.070935 080510 1 42 8.787 6113.580 6128.787 6143.962 25.1 1.007178 0.002606 237.071287 080510 1 42 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