46,1001 Keutsch, Frank Department of Chemistry, University of Wisconsin - Madison Formaldehyde mixing ratios from chemistry tower BEACHON-ROCS 2010 1,1 2010821,2010821 30 time_MST, (fractional day of year in MST at midpoint of measurement, where Jan. 1, 12:00am = 1) 10 1,1,1,1,1,1,1,1,1,1 -999,-999,-999,-999,-999,-999,-999,-999,-999,-999 time_MST, fractional day of year date, date in mmddyy hours_MST, hour of day in MST minutes_MST, minutes of hour in MST seconds_MST, seconds of minute in MST start_TOD_MST, time of day in seconds since midnight until beginning of measurement averaging mean_TOD_MST, average time of day in seconds since midnight of measurement averaging stop_TOD_MST, time of day in seconds since midnight until end of measurement averaging Altitude_AGL_m, altitude Above Ground Level in meters HCHO_ppbv, Mixing ratio of formaldehyde in ppbv HCHO_precision_ppbv, 1 sigma precision of mixing ratio of formaldehyde in ppbv 3 Data is presented as 1/30 Hz gradient data. Air was sampled at multiple heights on tower, via ~100'-125' 1/2" OD unheated PFA tubing 2 m measurements sampled outside instrument trailer, height value +/- 0.5 m 18 PI_CONTACT_INFO: Address: UW-Madison Dept of Chemistry, 1101 University Ave, Madison WI 53706; email: keutsch@wisc.edu; 608-262-7904 PLATFORM: Chemistry Tower near Rocky Mountain Research Station in Manitou Experimental Forest, CO LOCATION: Manitou Experimental Forest, CO; lat: 38.099; lon: -105.101; elev: 2360m amsl. ASSOCIATED_DATA: N/A INSTRUMENT_INFO: Fiber Laser-Induced Fluorescence of Gas-Phase Formaldehyde DATA_INFO: all concentration data are in ppbv. Raw data were recorded at 1Hz. Most large gaps in data stream correspond to gradient data, presented in other files. Data were filtered for known errors, points removed by this filtering are considered "missing" and given -999 UNCERTAINTY: +/-(.1 m) altitude (except 2 m measurements-see special comments); +/- 30% concentration (accuracy); concentration precision reported in columns ULOD_FLAG: -777 ULOD_VALUE: N/A LLOD_FLAG: -888 LLOD_VALUE: N/A DM_CONTACT_INFO: Joshua DiGangi; UW-Madison Chemistry Dept.; digangi@wisc.edu; 608-262-0269 PROJECT_INFO: BEARPEX field intensive; 15 June - 31 July, 2009; CA Sierra Nevada. STIPULATIONS_ON_USE: Do not quote or present without permission. Please contact PI before use. OTHER_COMMENTS: For absolute concentration error, accuracy and precision errors must be propagated. Diagnostics (cell pressure, temperature, beam power) available upon request. REVISION: R0 R0: Calibration not finalized, accuracy should improve by next revision time_PST date hours minutes seconds start_TOD_MST mean_TOD_MST stop_TOD_MST Altitude_AGL_m HCHO_ppbv HCHO_precision_ppbv 233.000495 080510 0 0 42.779 27.836 42.779 57.934 25.1 1.510300 0.005468 233.000845 080510 0 1 12.998 57.934 72.998 88.033 25.1 1.533456 0.005516 233.001194 080510 0 1 43.185 88.033 103.185 118.131 25.1 1.537039 0.005525 233.001545 080510 0 2 13.516 118.131 133.516 148.229 25.1 1.520501 0.005516 233.001889 080510 0 2 43.198 148.229 163.198 178.328 25.1 1.554315 0.005468 233.002239 080510 0 3 13.429 178.328 193.429 208.426 25.1 1.489520 0.005440 233.002588 080510 0 3 43.636 208.426 223.636 238.524 25.1 1.519602 0.005468 233.002934 080510 0 4 13.483 238.524 253.483 268.623 25.1 1.489774 0.005430 233.003286 080510 0 4 43.874 268.623 283.874 298.721 25.1 1.476919 0.005477 233.003632 080510 0 5 13.770 298.721 313.770 328.819 25.1 1.502660 0.005477 233.003960 080510 0 5 42.147 328.819 342.147 358.918 25.1 1.562620 0.005013 233.004329 080510 0 6 14.005 358.918 374.005 389.016 25.1 1.670366 0.002957 233.004675 080510 0 6 43.918 389.016 403.918 419.114 25.1 1.542517 0.002967 233.005025 080510 0 7 14.191 419.114 434.191 449.213 25.1 1.487459 0.002951 233.005374 080510 0 7 44.327 449.213 464.327 479.311 25.1 1.466583 0.002972 233.005725 080510 0 8 14.620 479.311 494.620 509.409 25.1 1.494764 0.002977 233.006071 080510 0 8 44.499 509.409 524.499 539.507 25.1 1.492610 0.002930 233.006420 080510 0 9 14.677 539.507 554.677 569.606 25.1 1.472097 0.002925 233.006766 080510 0 9 44.565 569.606 584.565 599.704 25.1 1.497366 0.002946 233.007116 080510 0 10 14.794 599.704 614.794 629.802 25.1 1.488404 0.003015 233.007463 080510 0 10 44.805 629.802 644.805 659.901 25.1 1.478892 0.002966 233.007802 080510 0 11 14.065 659.901 674.065 689.999 25.1 1.511410 0.003904 233.008159 080510 0 11 44.898 689.999 704.898 720.097 25.1 1.480728 0.003458 233.008507 080510 0 12 15.045 720.097 735.045 750.196 25.1 1.522988 0.003446 233.008858 080510 0 12 45.300 750.196 765.300 780.294 25.1 1.518230 0.003446 233.009207 080510 0 13 15.495 780.294 795.495 810.392 25.1 1.474001 0.003440 233.009554 080510 0 13 45.426 810.392 825.426 840.491 25.1 1.410487 0.003458 233.009903 080510 0 14 15.643 840.491 855.643 870.589 25.1 1.393556 0.003440 233.010250 080510 0 14 45.565 870.589 885.565 900.687 25.1 1.403610 0.003446 233.010599 080510 0 15 15.750 900.687 915.750 930.786 25.1 1.530647 0.003446 233.010946 080510 0 15 45.774 930.786 945.774 960.884 25.1 1.464012 0.003434 233.011297 080510 0 16 16.069 960.884 976.069 990.982 25.1 1.491304 0.003404 233.011653 080510 0 16 46.829 990.982 1006.829 1021.081 25.1 1.428436 0.004457 233.011991 080510 0 17 16.061 1021.081 1036.061 1051.179 25.1 1.408029 0.003556 233.012338 080510 0 17 45.964 1051.179 1065.964 1081.277 25.1 1.441715 0.003581 233.012692 080510 0 18 16.588 1081.277 1096.588 1111.376 25.1 1.455720 0.003556 233.013037 080510 0 18 46.432 1111.376 1126.432 1141.474 25.1 1.436556 0.003587 233.013385 080510 0 19 16.501 1141.474 1156.501 1171.572 25.1 1.424966 0.003549 233.013735 080510 0 19 46.728 1171.572 1186.728 1201.671 25.1 1.441607 0.003543 233.014082 080510 0 20 16.712 1201.671 1216.712 1231.769 25.1 1.468746 0.003594 233.014433 080510 0 20 47.054 1231.769 1247.054 1261.867 25.1 1.525538 0.003556 233.014778 080510 0 21 16.796 1261.867 1276.796 1291.966 25.1 1.521085 0.003562 233.015124 080510 0 21 46.755 1291.966 1306.755 1322.064 25.1 1.466806 0.003600 233.015484 080510 0 22 17.860 1322.064 1337.860 1352.162 25.1 1.456415 0.004410 233.015824 080510 0 22 47.222 1352.162 1367.222 1382.261 25.1 1.370570 0.003470 233.016172 080510 0 23 17.230 1382.261 1397.230 1412.359 25.1 1.390998 0.003495 233.016522 080510 0 23 47.488 1412.359 1427.488 1442.457 25.1 1.489820 0.003489 233.016871 080510 0 24 17.619 1442.457 1457.619 1472.556 25.1 1.537126 0.003447 233.017218 080510 0 24 47.653 1472.556 1487.653 1502.654 25.1 1.412696 0.003495 233.017566 080510 0 25 17.691 1502.654 1517.691 1532.752 25.1 1.363867 0.003538 233.017915 080510 0 25 47.838 1532.752 1547.838 1562.850 25.1 1.457311 0.003458 233.018263 080510 0 26 17.940 1562.850 1577.940 1592.949 25.1 1.464963 0.003476 233.018613 080510 0 26 48.151 1592.949 1608.151 1623.047 25.1 1.429065 0.003495 233.018960 080510 0 27 18.106 1623.047 1638.106 1653.145 25.1 1.450362 0.003464 233.019346 080510 0 27 51.503 1653.145 1671.503 1683.244 25.1 1.478714 0.003999 233.019656 080510 0 28 18.247 1683.244 1698.247 1713.342 25.1 1.532808 0.003037 233.020005 080510 0 28 48.419 1713.342 1728.419 1743.440 25.1 1.531035 0.003053 233.020352 080510 0 29 18.447 1743.440 1758.447 1773.539 25.1 1.530642 0.003047 233.020701 080510 0 29 48.577 1773.539 1788.577 1803.637 25.1 1.534487 0.003058 233.021049 080510 0 30 18.676 1803.637 1818.676 1833.735 25.1 1.515527 0.003031 233.021399 080510 0 30 48.859 1833.735 1848.859 1863.834 25.1 1.483190 0.003042 233.021746 080510 0 31 18.825 1863.834 1878.825 1893.932 25.1 1.546399 0.003037 233.022097 080510 0 31 49.206 1893.932 1909.206 1924.030 25.1 1.586396 0.003080 233.022445 080510 0 32 19.251 1924.030 1939.251 1954.129 25.1 1.579917 0.003063 233.022792 080510 0 32 49.267 1954.129 1969.267 1984.227 25.1 1.527335 0.003074 233.023154 080510 0 33 20.473 1954.129 1969.267 1984.227 25.1 -999 -999 233.023515 080510 0 33 51.679 1954.129 1969.267 1984.227 25.1 -999 -999 233.023876 080510 0 34 22.885 1954.129 1969.267 1984.227 25.1 -999 -999 233.024237 080510 0 34 54.090 1954.129 1969.267 1984.227 25.1 -999 -999 233.024598 080510 0 35 25.296 1954.129 1969.267 1984.227 25.1 -999 -999 233.024960 080510 0 35 56.502 1954.129 1969.267 1984.227 25.1 -999 -999 233.025517 080510 0 36 44.689 2189.689 2204.689 2219.689 8.5 1.292319 0.025489 233.025895 080510 0 37 17.297 2222.297 2237.297 2252.297 8.5 1.299808 0.021827 233.026272 080510 0 37 49.910 2254.910 2269.910 2284.910 8.5 1.261561 0.022290 233.026650 080510 0 38 22.529 2287.529 2302.529 2317.529 8.5 1.331856 0.026067 233.027027 080510 0 38 55.165 2320.165 2335.165 2350.165 8.5 1.317613 0.024191 233.027405 080510 0 39 27.809 2352.809 2367.809 2382.809 8.5 1.220051 0.022867 233.027783 080510 0 40 0.469 2385.469 2400.469 2415.469 8.5 1.226062 0.025650 233.028161 080510 0 40 33.130 2418.130 2433.130 2448.130 8.5 1.249756 0.023214 233.028539 080510 0 41 5.784 2450.784 2465.784 2480.784 8.5 1.221624 0.023239 233.028917 080510 0 41 38.436 2483.436 2498.436 2513.436 8.5 1.221681 0.026646 233.029278 080510 0 42 9.642 2483.436 2498.436 2513.436 8.5 -999 -999 233.029639 080510 0 42 40.847 2483.436 2498.436 2513.436 8.5 -999 -999 233.030001 080510 0 43 12.053 2483.436 2498.436 2513.436 8.5 -999 -999 233.030362 080510 0 43 43.259 2483.436 2498.436 2513.436 8.5 -999 -999 233.031070 080510 0 44 44.461 2669.461 2684.461 2699.461 17.7 1.393690 0.024003 233.031448 080510 0 45 17.132 2702.132 2717.132 2732.132 17.7 1.418936 0.020810 233.031826 080510 0 45 49.802 2734.802 2749.802 2764.802 17.7 1.394949 0.024104 233.032205 080510 0 46 22.477 2767.477 2782.477 2797.477 17.7 1.442483 0.026612 233.032583 080510 0 46 55.148 2800.148 2815.148 2830.148 17.7 1.447457 0.026497 233.032961 080510 0 47 27.829 2832.829 2847.829 2862.829 17.7 1.409022 0.023769 233.033339 080510 0 48 0.481 2865.481 2880.481 2895.481 17.7 1.445963 0.021378 233.033717 080510 0 48 33.149 2898.149 2913.149 2928.149 17.7 1.465499 0.025252 233.034095 080510 0 49 5.818 2930.818 2945.818 2960.818 17.7 1.422353 0.024829 233.034473 080510 0 49 38.486 2963.486 2978.486 2993.486 17.7 1.450635 0.021832 233.034834 080510 0 50 9.692 2963.486 2978.486 2993.486 17.7 -999 -999 233.035196 080510 0 50 40.897 2963.486 2978.486 2993.486 17.7 -999 -999 233.035557 080510 0 51 12.103 2963.486 2978.486 2993.486 17.7 -999 -999 233.035918 080510 0 51 43.309 2963.486 2978.486 2993.486 17.7 -999 -999 233.036626 080510 0 52 44.509 3149.509 3164.509 3179.509 1.6 1.224465 0.023108 233.037004 080510 0 53 17.169 3182.169 3197.169 3212.169 1.6 1.184161 0.019926 233.037382 080510 0 53 49.828 3214.828 3229.828 3244.828 1.6 1.217016 0.025893 233.037760 080510 0 54 22.486 3247.486 3262.486 3277.486 1.6 1.228615 0.025926 233.038138 080510 0 54 55.144 3280.144 3295.144 3310.144 1.6 1.210250 0.027456 233.038516 080510 0 55 27.804 3312.804 3327.804 3342.804 1.6 1.203829 0.024729 233.038894 080510 0 56 0.471 3345.471 3360.471 3375.471 1.6 1.175664 0.025095 233.039272 080510 0 56 33.142 3378.142 3393.142 3408.142 1.6 1.233477 0.020195 233.039651 080510 0 57 5.815 3410.815 3425.815 3440.815 1.6 1.218826 0.029056 233.040029 080510 0 57 38.472 3443.472 3458.472 3473.472 1.6 1.209007 0.020185 233.040390 080510 0 58 9.677 3443.472 3458.472 3473.472 1.6 -999 -999 233.040751 080510 0 58 40.883 3443.472 3458.472 3473.472 1.6 -999 -999 233.041112 080510 0 59 12.089 3443.472 3458.472 3473.472 1.6 -999 -999 233.041473 080510 0 59 43.295 3443.472 3458.472 3473.472 1.6 -999 -999 233.042163 080510 1 0 42.841 3627.836 3642.841 3658.164 25.1 1.387698 0.004171 233.042516 080510 1 1 13.372 3658.164 3673.372 3688.491 25.1 1.386749 0.004149 233.042867 080510 1 1 43.671 3688.491 3703.671 3718.819 25.1 1.413484 0.004128 233.043217 080510 1 2 13.960 3718.819 3733.960 3749.147 25.1 1.490385 0.004186 233.043569 080510 1 2 44.389 3749.147 3764.389 3779.474 25.1 1.451704 0.004178 233.043922 080510 1 3 14.855 3779.474 3794.855 3809.802 25.1 1.416156 0.004208 233.044270 080510 1 3 44.893 3809.802 3824.893 3840.130 25.1 1.391177 0.004163 233.044622 080510 1 4 15.303 3840.130 3855.303 3870.457 25.1 1.393302 0.004156 233.044974 080510 1 4 45.726 3870.457 3885.726 3900.785 25.1 1.366098 0.004185 233.045322 080510 1 5 15.855 3900.785 3915.855 3931.112 25.1 1.435781 0.004178 233.045639 080510 1 5 43.196 3931.112 3943.196 3961.440 25.1 1.492340 0.004744 233.046027 080510 1 6 16.692 3961.440 3976.692 3991.768 25.1 1.577461 0.002975 233.046375 080510 1 6 46.815 3991.768 4006.815 4022.095 25.1 1.582089 0.002965 233.046729 080510 1 7 17.388 4022.095 4037.388 4052.423 25.1 1.566390 0.002991 233.047079 080510 1 7 47.599 4052.423 4067.599 4082.751 25.1 1.601456 0.002959 233.047430 080510 1 8 17.961 4082.751 4097.961 4113.078 25.1 1.565500 0.002949 233.047780 080510 1 8 48.193 4113.078 4128.193 4143.406 25.1 1.555488 0.002949 233.048134 080510 1 9 18.738 4143.406 4158.738 4173.734 25.1 1.572391 0.002986 233.048483 080510 1 9 48.963 4173.734 4188.963 4204.061 25.1 1.585692 0.002986 233.048833 080510 1 10 19.202 4204.061 4219.202 4234.389 25.1 1.603399 0.002949 233.049184 080510 1 10 49.536 4234.389 4249.536 4264.717 25.1 1.615735 0.002954 233.049508 080510 1 11 17.483 4264.717 4277.483 4295.044 25.1 1.602967 0.003911 233.049888 080510 1 11 50.299 4295.044 4310.299 4325.372 25.1 1.407643 0.003803 233.050239 080510 1 12 20.633 4325.372 4340.633 4355.700 25.1 1.391858 0.003776 233.050589 080510 1 12 50.885 4355.700 4370.885 4386.027 25.1 1.398477 0.003810 233.050939 080510 1 13 21.119 4386.027 4401.119 4416.355 25.1 1.372906 0.003803 233.051292 080510 1 13 51.595 4416.355 4431.595 4446.682 25.1 1.378108 0.003796 233.051643 080510 1 14 21.937 4446.682 4461.937 4477.010 25.1 1.412323 0.003763 233.051992 080510 1 14 52.151 4477.010 4492.151 4507.338 25.1 1.418092 0.003770 233.052342 080510 1 15 22.359 4507.338 4522.359 4537.665 25.1 1.374678 0.003776 233.052695 080510 1 15 52.862 4537.665 4552.862 4567.993 25.1 1.375117 0.003750 233.053043 080510 1 16 22.891 4567.993 4582.891 4598.321 25.1 1.375976 0.003803 233.053381 080510 1 16 52.109 4598.321 4612.109 4628.648 25.1 1.368468 0.004780 233.053748 080510 1 17 23.841 4628.648 4643.841 4658.976 25.1 1.405579 0.003893 233.054096 080510 1 17 53.879 4658.976 4673.879 4689.304 25.1 1.409964 0.003832 233.054451 080510 1 18 24.608 4689.304 4704.608 4719.631 25.1 1.373185 0.003846 233.054803 080510 1 18 54.949 4719.631 4734.949 4749.959 25.1 1.369746 0.003859 233.055151 080510 1 19 25.022 4749.959 4765.022 4780.287 25.1 1.312535 0.003813 233.055502 080510 1 19 55.352 4780.287 4795.352 4810.614 25.1 1.357596 0.003893 233.055853 080510 1 20 25.710 4810.614 4825.710 4840.942 25.1 1.401921 0.003893 233.056206 080510 1 20 56.226 4840.942 4856.226 4871.269 25.1 1.336591 0.003845 233.056558 080510 1 21 26.588 4871.269 4886.588 4901.597 25.1 1.311085 0.003900 233.056906 080510 1 21 56.663 4901.597 4916.663 4931.925 25.1 1.307607 0.003852 233.057268 080510 1 22 27.938 4931.925 4947.938 4962.252 25.1 1.306408 0.004804 233.057610 080510 1 22 57.489 4962.252 4977.489 4992.580 25.1 1.401366 0.003866 233.057961 080510 1 23 27.804 4992.580 5007.804 5022.908 25.1 1.455637 0.003839 233.058308 080510 1 23 57.786 5022.908 5037.786 5053.235 25.1 1.468510 0.003832 233.058662 080510 1 24 28.439 5053.235 5068.439 5083.563 25.1 1.473578 0.003832 233.059015 080510 1 24 58.895 5083.563 5098.895 5113.891 25.1 1.378672 0.003832 233.059363 080510 1 25 28.970 5113.891 5128.970 5144.218 25.1 1.351330 0.003852 233.059714 080510 1 25 59.309 5144.218 5159.309 5174.546 25.1 1.414729 0.003818 233.060064 080510 1 26 29.544 5174.546 5189.544 5204.874 25.1 1.475014 0.003852 233.060419 080510 1 27 0.229 5204.874 5220.229 5235.201 25.1 1.470461 0.003792 233.060767 080510 1 27 30.265 5235.201 5250.265 5265.529 25.1 1.489110 0.003866 233.061153 080510 1 28 3.589 5265.529 5283.589 5295.857 25.1 1.399688 0.003245 233.061470 080510 1 28 30.986 5295.857 5310.986 5326.184 25.1 1.396188 0.002391 233.061819 080510 1 29 1.203 5326.184 5341.203 5356.512 25.1 1.371629 0.002399 233.062170 080510 1 29 31.493 5356.512 5371.493 5386.839 25.1 1.380452 0.002391 233.062524 080510 1 30 2.088 5386.839 5402.088 5417.167 25.1 1.415000 0.002421 233.062876 080510 1 30 32.499 5417.167 5432.499 5447.495 25.1 1.402929 0.002378 233.063224 080510 1 31 2.547 5447.495 5462.547 5477.822 25.1 1.402158 0.002358 233.063576 080510 1 31 32.940 5477.822 5492.940 5508.150 25.1 1.391761 0.002370 233.063927 080510 1 32 3.277 5508.150 5523.277 5538.478 25.1 1.370723 0.002390 233.064279 080510 1 32 33.669 5538.478 5553.669 5568.805 25.1 1.353580 0.002382 233.064628 080510 1 33 3.895 5568.805 5583.895 5599.133 25.1 1.346264 0.002378 233.064990 080510 1 33 35.101 5568.805 5583.895 5599.133 25.1 -999 -999 233.065351 080510 1 34 6.307 5568.805 5583.895 5599.133 25.1 -999 -999 233.065712 080510 1 34 37.512 5568.805 5583.895 5599.133 25.1 -999 -999 233.066073 080510 1 35 8.718 5568.805 5583.895 5599.133 25.1 -999 -999 233.066434 080510 1 35 39.924 5568.805 5583.895 5599.133 25.1 -999 -999 233.066795 080510 1 36 11.130 5568.805 5583.895 5599.133 25.1 -999 -999 233.067192 080510 1 36 45.417 5790.417 5805.417 5820.417 8.5 1.244915 0.026312 233.067570 080510 1 37 18.079 5823.079 5838.079 5853.079 8.5 1.299496 0.027799 233.067948 080510 1 37 50.746 5855.746 5870.746 5885.746 8.5 1.296003 0.026539 233.068327 080510 1 38 23.427 5888.427 5903.427 5918.427 8.5 1.218241 0.030222 233.068705 080510 1 38 56.093 5921.093 5936.093 5951.093 8.5 1.262406 0.022527 233.069083 080510 1 39 28.765 5953.765 5968.765 5983.765 8.5 1.219568 0.023501 233.069461 080510 1 40 1.425 5986.425 6001.425 6016.425 8.5 1.239419 0.025363 233.069839 080510 1 40 34.092 6019.092 6034.092 6049.092 8.5 1.233487 0.027591 233.070217 080510 1 41 6.751 6051.750 6066.750 6081.750 8.5 1.235273 0.028535 233.070595 080510 1 41 39.418 6084.418 6099.418 6114.418 8.5 1.184698 0.024492 233.070956 080510 1 42 10.624 6084.418 6099.418 6114.418 8.5 -999 -999 233.071317 080510 1 42 41.829 6084.418 6099.418 6114.418 8.5 -999 -999 233.071679 080510 1 43 13.035 6084.418 6099.418 6114.418 8.5 -999 -999 233.072040 080510 1 43 44.241 6084.418 6099.418 6114.418 8.5 -999 -999 233.072748 080510 1 44 45.420 6270.420 6285.420 6300.420 17.7 1.331405 0.026556 233.073126 080510 1 45 18.079 6303.079 6318.079 6333.079 17.7 1.385714 0.021600 233.073504 080510 1 45 50.740 6335.740 6350.740 6365.740 17.7 1.406201 0.022117 233.073882 080510 1 46 23.406 6368.406 6383.406 6398.406 17.7 1.379942 0.025139 233.074260 080510 1 46 56.063 6401.063 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