46,1001 Keutsch, Frank Department of Chemistry, University of Wisconsin - Madison Formaldehyde mixing ratios from chemistry tower BEACHON-ROCS 2010 1,1 2010813,2010813 30 time_MST, (fractional day of year in MST at midpoint of measurement, where Jan. 1, 12:00am = 1) 10 1,1,1,1,1,1,1,1,1,1 -999,-999,-999,-999,-999,-999,-999,-999,-999,-999 time_MST, fractional day of year date, date in mmddyy hours_MST, hour of day in MST minutes_MST, minutes of hour in MST seconds_MST, seconds of minute in MST start_TOD_MST, time of day in seconds since midnight until beginning of measurement averaging mean_TOD_MST, average time of day in seconds since midnight of measurement averaging stop_TOD_MST, time of day in seconds since midnight until end of measurement averaging Altitude_AGL_m, altitude Above Ground Level in meters HCHO_ppbv, Mixing ratio of formaldehyde in ppbv HCHO_precision_ppbv, 1 sigma precision of mixing ratio of formaldehyde in ppbv 3 Data is presented as 1/30 Hz gradient data. Air was sampled at multiple heights on tower, via ~100'-125' 1/2" OD unheated PFA tubing 2 m measurements sampled outside instrument trailer, height value +/- 0.5 m 18 PI_CONTACT_INFO: Address: UW-Madison Dept of Chemistry, 1101 University Ave, Madison WI 53706; email: keutsch@wisc.edu; 608-262-7904 PLATFORM: Chemistry Tower near Rocky Mountain Research Station in Manitou Experimental Forest, CO LOCATION: Manitou Experimental Forest, CO; lat: 38.099; lon: -105.101; elev: 2360m amsl. ASSOCIATED_DATA: N/A INSTRUMENT_INFO: Fiber Laser-Induced Fluorescence of Gas-Phase Formaldehyde DATA_INFO: all concentration data are in ppbv. Raw data were recorded at 1Hz. Most large gaps in data stream correspond to gradient data, presented in other files. Data were filtered for known errors, points removed by this filtering are considered "missing" and given -999 UNCERTAINTY: +/-(.1 m) altitude (except 2 m measurements-see special comments); +/- 30% concentration (accuracy); concentration precision reported in columns ULOD_FLAG: -777 ULOD_VALUE: N/A LLOD_FLAG: -888 LLOD_VALUE: N/A DM_CONTACT_INFO: Joshua DiGangi; UW-Madison Chemistry Dept.; digangi@wisc.edu; 608-262-0269 PROJECT_INFO: BEARPEX field intensive; 15 June - 31 July, 2009; CA Sierra Nevada. STIPULATIONS_ON_USE: Do not quote or present without permission. Please contact PI before use. OTHER_COMMENTS: For absolute concentration error, accuracy and precision errors must be propagated. Diagnostics (cell pressure, temperature, beam power) available upon request. REVISION: R0 R0: Calibration not finalized, accuracy should improve by next revision time_PST date hours minutes seconds start_TOD_MST mean_TOD_MST stop_TOD_MST Altitude_AGL_m HCHO_ppbv HCHO_precision_ppbv 225.000321 080510 0 0 27.747 12.747 27.747 42.747 8.5 1.006036 0.028605 225.000698 080510 0 1 0.322 45.322 60.322 75.322 8.5 1.031458 0.029896 225.001075 080510 0 1 32.885 77.885 92.885 107.885 8.5 1.100712 0.032519 225.001452 080510 0 2 5.464 110.464 125.464 140.464 8.5 1.135638 0.029527 225.001829 080510 0 2 38.064 143.064 158.064 173.064 8.5 1.086051 0.030656 225.002207 080510 0 3 10.657 175.657 190.657 205.657 8.5 1.006968 0.031718 225.002584 080510 0 3 43.266 208.266 223.266 238.266 8.5 1.066148 0.025016 225.002962 080510 0 4 15.888 240.888 255.888 270.888 8.5 1.040088 0.030135 225.003339 080510 0 4 48.518 273.518 288.518 303.518 8.5 1.037661 0.039284 225.003717 080510 0 5 21.157 306.157 321.157 336.157 8.5 0.945643 0.031856 225.004078 080510 0 5 52.363 306.157 321.157 336.157 8.5 -999 -999 225.004439 080510 0 6 23.569 306.157 321.157 336.157 8.5 -999 -999 225.004801 080510 0 6 54.775 306.157 321.157 336.157 8.5 -999 -999 225.005394 080510 0 7 46.079 451.079 466.079 481.079 17.7 0.983723 0.034940 225.005772 080510 0 8 18.718 483.718 498.718 513.718 17.7 1.019124 0.030662 225.006150 080510 0 8 51.365 516.365 531.365 546.365 17.7 1.000476 0.034297 225.006528 080510 0 9 24.008 549.008 564.008 579.008 17.7 0.982153 0.035505 225.006906 080510 0 9 56.643 581.643 596.643 611.643 17.7 0.984639 0.027104 225.007283 080510 0 10 29.280 614.280 629.280 644.280 17.7 1.014147 0.031119 225.007661 080510 0 11 1.926 646.925 661.925 676.925 17.7 1.027999 0.035565 225.008039 080510 0 11 34.565 679.565 694.565 709.565 17.7 1.011946 0.025961 225.008417 080510 0 12 7.192 712.192 727.192 742.192 17.7 0.991291 0.031382 225.008794 080510 0 12 39.821 744.821 759.821 774.821 17.7 1.007764 0.033066 225.009155 080510 0 13 11.027 744.821 759.821 774.821 17.7 -999 -999 225.009517 080510 0 13 42.232 744.821 759.821 774.821 17.7 -999 -999 225.009878 080510 0 14 13.438 744.821 759.821 774.821 17.7 -999 -999 225.010471 080510 0 15 4.698 889.698 904.698 919.698 8.5 0.887882 0.031510 225.010849 080510 0 15 37.343 922.343 937.343 952.343 8.5 0.971431 0.027206 225.011227 080510 0 16 9.976 954.976 969.976 984.976 8.5 0.945270 0.028746 225.011604 080510 0 16 42.620 987.620 1002.620 1017.620 8.5 1.031617 0.031563 225.011982 080510 0 17 15.258 1020.258 1035.258 1050.258 8.5 0.966015 0.030824 225.012360 080510 0 17 47.911 1052.911 1067.911 1082.911 8.5 0.971086 0.031830 225.012744 080510 0 18 21.091 1086.091 1101.091 1116.091 8.5 0.984130 0.033350 225.013115 080510 0 18 53.176 1118.175 1133.175 1148.175 8.5 0.909659 0.029777 225.013493 080510 0 19 25.812 1150.812 1165.812 1180.812 8.5 0.893517 0.027684 225.013871 080510 0 19 58.454 1183.454 1198.454 1213.454 8.5 0.934383 0.035523 225.014232 080510 0 20 29.659 1183.454 1198.454 1213.454 8.5 -999 -999 225.014593 080510 0 21 0.865 1183.454 1198.454 1213.454 8.5 -999 -999 225.014955 080510 0 21 32.071 1183.454 1198.454 1213.454 8.5 -999 -999 225.015471 080510 0 22 16.722 1322.329 1336.722 1352.601 25.1 0.923213 0.003494 225.015836 080510 0 22 48.242 1352.601 1368.242 1382.873 25.1 0.866895 0.003710 225.016180 080510 0 23 17.935 1382.873 1397.935 1413.145 25.1 0.969196 0.003556 225.016526 080510 0 23 47.872 1413.145 1427.872 1443.417 25.1 0.911808 0.003926 225.016884 080510 0 24 18.794 1443.417 1458.794 1473.689 25.1 0.886280 0.003855 225.017231 080510 0 24 48.775 1473.689 1488.775 1503.961 25.1 0.882647 0.004260 225.017576 080510 0 25 18.532 1503.961 1518.532 1534.233 25.1 0.927625 0.003636 225.017939 080510 0 25 49.915 1534.233 1549.915 1564.505 25.1 0.887715 0.003547 225.018281 080510 0 26 19.484 1564.505 1579.484 1594.777 25.1 0.903329 0.003631 225.018628 080510 0 26 49.418 1594.777 1609.418 1625.049 25.1 0.893009 0.003926 225.018987 080510 0 27 20.480 1625.049 1640.480 1655.321 25.1 0.903979 0.003072 225.019336 080510 0 27 50.588 1655.321 1670.588 1685.593 25.1 0.956861 0.003462 225.019679 080510 0 28 20.238 1685.593 1700.238 1715.865 25.1 0.934038 0.003685 225.020042 080510 0 28 51.643 1715.865 1731.643 1746.137 25.1 0.999455 0.003606 225.020389 080510 0 29 21.645 1746.137 1761.645 1776.409 25.1 1.058854 0.004101 225.020732 080510 0 29 51.282 1776.409 1791.282 1806.681 25.1 1.026077 0.003901 225.021092 080510 0 30 22.344 1806.681 1822.344 1836.952 25.1 0.989494 0.003302 225.021436 080510 0 30 52.092 1836.952 1852.092 1867.224 25.1 0.950899 0.003791 225.021783 080510 0 31 22.022 1867.224 1882.022 1897.496 25.1 0.968359 0.004158 225.022141 080510 0 31 53.016 1897.496 1913.016 1927.768 25.1 1.039992 0.003933 225.022490 080510 0 32 23.165 1927.768 1943.165 1958.040 25.1 0.991275 0.004242 225.022833 080510 0 32 52.790 1958.040 1972.790 1988.312 25.1 0.945722 0.003651 225.023194 080510 0 33 23.986 1988.312 2003.986 2018.584 25.1 0.959006 0.002898 225.023544 080510 0 33 54.201 2018.584 2034.201 2048.856 25.1 0.963704 0.003879 225.023888 080510 0 34 23.920 2048.856 2063.920 2079.128 25.1 0.951575 0.003190 225.024242 080510 0 34 54.544 2079.128 2094.544 2109.400 25.1 0.955110 0.003673 225.024590 080510 0 35 24.578 2109.400 2124.578 2139.672 25.1 0.937091 0.003201 225.024935 080510 0 35 54.391 2139.672 2154.391 2169.944 25.1 0.982603 0.003223 225.025291 080510 0 36 25.166 2169.944 2185.166 2200.216 25.1 0.978842 0.003707 225.025643 080510 0 36 55.555 2200.216 2215.555 2230.488 25.1 0.979689 0.003416 225.025991 080510 0 37 25.636 2230.488 2245.636 2260.760 25.1 0.980497 0.003574 225.026339 080510 0 37 55.649 2260.760 2275.649 2291.032 25.1 0.907930 0.003456 225.026687 080510 0 38 25.722 2291.032 2305.722 2321.304 25.1 0.933425 0.003204 225.027045 080510 0 38 56.721 2321.304 2336.721 2351.576 25.1 0.891913 0.003146 225.027391 080510 0 39 26.566 2351.576 2366.566 2381.848 25.1 0.953692 0.004222 225.027738 080510 0 39 56.574 2381.848 2396.574 2412.120 25.1 0.949441 0.003673 225.028094 080510 0 40 27.337 2412.120 2427.337 2442.392 25.1 0.923225 0.003347 225.028442 080510 0 40 57.420 2442.392 2457.420 2472.664 25.1 0.959812 0.003247 225.028792 080510 0 41 27.629 2472.664 2487.629 2502.936 25.1 0.975055 0.003689 225.029146 080510 0 41 58.204 2502.936 2518.204 2533.208 25.1 0.909693 0.003258 225.029493 080510 0 42 28.162 2533.208 2548.162 2563.480 25.1 0.969812 0.003247 225.029845 080510 0 42 58.614 2563.480 2578.614 2593.752 25.1 0.986525 0.003772 225.030196 080510 0 43 28.902 2593.752 2608.902 2624.024 25.1 0.988111 0.003862 225.030546 080510 0 43 59.161 2624.024 2639.161 2654.296 25.1 0.942123 0.003663 225.030894 080510 0 44 29.242 2654.296 2669.242 2684.568 25.1 0.985896 0.004276 225.031248 080510 0 44 59.790 2684.568 2699.790 2714.840 25.1 0.912203 0.003606 225.031595 080510 0 45 29.775 2714.840 2729.775 2745.112 25.1 0.980150 0.004691 225.031944 080510 0 45 59.946 2745.112 2759.946 2775.383 25.1 1.082583 0.003801 225.032298 080510 0 46 30.566 2775.383 2790.566 2805.655 25.1 0.985298 0.004152 225.032648 080510 0 47 0.812 2805.655 2820.812 2835.927 25.1 0.968678 0.003332 225.032997 080510 0 47 30.899 2835.927 2850.899 2866.199 25.1 0.983353 0.004268 225.033348 080510 0 48 1.300 2866.199 2881.300 2896.471 25.1 0.966071 0.003799 225.033698 080510 0 48 31.499 2896.471 2911.499 2926.743 25.1 0.935136 0.003986 225.034049 080510 0 49 1.852 2926.743 2941.852 2957.015 25.1 0.920098 0.003610 225.034400 080510 0 49 32.162 2957.015 2972.162 2987.287 25.1 0.961698 0.003694 225.034746 080510 0 50 2.075 2987.287 3002.075 3017.559 25.1 0.916871 0.003372 225.035097 080510 0 50 32.364 3017.559 3032.364 3047.831 25.1 0.903093 0.004397 225.035453 080510 0 51 3.132 3047.831 3063.132 3078.103 25.1 0.973426 0.003674 225.035796 080510 0 51 32.750 3078.103 3092.750 3108.375 25.1 0.965892 0.003569 225.036146 080510 0 52 2.976 3108.375 3122.976 3138.647 25.1 0.901527 0.004413 225.036505 080510 0 52 34.007 3138.647 3154.007 3168.919 25.1 0.905045 0.003703 225.036849 080510 0 53 3.763 3168.919 3183.763 3199.191 25.1 0.940992 0.003056 225.037198 080510 0 53 33.947 3199.191 3213.947 3229.463 25.1 0.886269 0.003079 225.037559 080510 0 54 5.133 3229.463 3245.133 3259.735 25.1 0.981856 0.003447 225.037921 080510 0 54 36.339 3229.463 3245.133 3259.735 25.1 -999 -999 225.038282 080510 0 55 7.545 3229.463 3245.133 3259.735 25.1 -999 -999 225.038643 080510 0 55 38.751 3229.463 3245.133 3259.735 25.1 -999 -999 225.039176 080510 0 56 24.804 3369.804 3384.804 3399.804 8.5 0.937952 0.029160 225.039554 080510 0 56 57.433 3402.433 3417.433 3432.433 8.5 0.882081 0.033914 225.039931 080510 0 57 30.065 3435.065 3450.065 3465.065 8.5 0.917573 0.034544 225.040309 080510 0 58 2.695 3467.695 3482.695 3497.695 8.5 0.900644 0.033058 225.040687 080510 0 58 35.340 3500.340 3515.340 3530.340 8.5 0.886868 0.029902 225.041065 080510 0 59 7.987 3532.987 3547.987 3562.987 8.5 0.839534 0.032891 225.041443 080510 0 59 40.634 3565.634 3580.634 3595.634 8.5 0.872986 0.034208 225.041815 080510 1 0 12.794 3597.794 3612.794 3627.794 8.5 0.855557 0.026547 225.042198 080510 1 0 45.925 3630.925 3645.925 3660.925 8.5 0.827925 0.028666 225.042576 080510 1 1 18.552 3663.552 3678.552 3693.552 8.5 0.861897 0.033587 225.042937 080510 1 1 49.758 3663.552 3678.552 3693.552 8.5 -999 -999 225.043298 080510 1 2 20.964 3663.552 3678.552 3693.552 8.5 -999 -999 225.043659 080510 1 2 52.170 3663.552 3678.552 3693.552 8.5 -999 -999 225.044253 080510 1 3 43.428 3808.428 3823.428 3838.428 17.7 0.938197 0.028442 225.044630 080510 1 4 16.066 3841.066 3856.066 3871.066 17.7 0.989604 0.029967 225.045008 080510 1 4 48.692 3873.692 3888.692 3903.692 17.7 0.990602 0.029272 225.045386 080510 1 5 21.343 3906.343 3921.343 3936.343 17.7 0.992292 0.031078 225.045764 080510 1 5 53.979 3938.979 3953.979 3968.979 17.7 0.997705 0.031551 225.046142 080510 1 6 26.626 3971.626 3986.626 4001.626 17.7 0.961607 0.029159 225.046519 080510 1 6 59.268 4004.268 4019.268 4034.268 17.7 1.012254 0.028896 225.046897 080510 1 7 31.917 4036.917 4051.917 4066.917 17.7 0.995279 0.031013 225.047275 080510 1 8 4.562 4069.562 4084.562 4099.562 17.7 0.989347 0.032925 225.047653 080510 1 8 37.200 4102.200 4117.200 4132.200 17.7 1.042263 0.030705 225.048014 080510 1 9 8.406 4102.200 4117.200 4132.200 17.7 -999 -999 225.048375 080510 1 9 39.612 4102.200 4117.200 4132.200 17.7 -999 -999 225.048736 080510 1 10 10.818 4102.200 4117.200 4132.200 17.7 -999 -999 225.049330 080510 1 11 2.082 4247.082 4262.082 4277.082 8.5 0.836348 0.027700 225.049707 080510 1 11 34.722 4279.722 4294.722 4309.722 8.5 0.799897 0.028214 225.050085 080510 1 12 7.368 4312.368 4327.368 4342.368 8.5 0.745097 0.029832 225.050463 080510 1 12 40.014 4345.014 4360.014 4375.014 8.5 0.812648 0.027982 225.050841 080510 1 13 12.664 4377.664 4392.664 4407.664 8.5 0.884607 0.033271 225.051219 080510 1 13 45.308 4410.308 4425.308 4440.308 8.5 0.843818 0.025574 225.051597 080510 1 14 17.948 4442.948 4457.948 4472.948 8.5 0.852231 0.031832 225.051974 080510 1 14 50.592 4475.592 4490.592 4505.592 8.5 0.835426 0.031273 225.052352 080510 1 15 23.230 4508.230 4523.230 4538.230 8.5 0.802746 0.023890 225.052730 080510 1 15 55.863 4540.863 4555.863 4570.863 8.5 0.780919 0.024225 225.053091 080510 1 16 27.069 4540.863 4555.863 4570.863 8.5 -999 -999 225.053452 080510 1 16 58.275 4540.863 4555.863 4570.863 8.5 -999 -999 225.053813 080510 1 17 29.481 4540.863 4555.863 4570.863 8.5 -999 -999 225.054333 080510 1 18 14.391 4679.735 4694.391 4710.143 25.1 0.901497 0.004043 225.054696 080510 1 18 45.740 4710.143 4725.740 4740.550 25.1 0.944442 0.003648 225.055045 080510 1 19 15.846 4740.550 4755.846 4770.958 25.1 0.959766 0.003303 225.055391 080510 1 19 45.771 4770.958 4785.771 4801.366 25.1 1.006206 0.003724 225.055754 080510 1 20 17.178 4801.366 4817.178 4831.774 25.1 0.990609 0.004241 225.056102 080510 1 20 47.240 4831.774 4847.240 4862.181 25.1 0.974755 0.003647 225.056446 080510 1 21 16.940 4862.181 4876.940 4892.589 25.1 1.017356 0.003410 225.056810 080510 1 21 48.361 4892.589 4908.361 4922.997 25.1 0.963576 0.003673 225.057160 080510 1 22 18.663 4922.997 4938.663 4953.404 25.1 0.888848 0.004268 225.057505 080510 1 22 48.397 4953.404 4968.397 4983.812 25.1 0.920485 0.003671 225.057865 080510 1 23 19.512 4983.812 4999.512 5014.220 25.1 0.923413 0.003386 225.058215 080510 1 23 49.792 5014.220 5029.792 5044.628 25.1 1.003198 0.002990 225.058562 080510 1 24 19.725 5044.628 5059.725 5075.035 25.1 0.931548 0.003524 225.058918 080510 1 24 50.555 5075.035 5090.555 5105.443 25.1 1.006286 0.004207 225.059269 080510 1 25 20.835 5105.443 5120.835 5135.851 25.1 1.072876 0.003864 225.059616 080510 1 25 50.827 5135.851 5150.827 5166.258 25.1 1.002264 0.003595 225.059972 080510 1 26 21.570 5166.258 5181.570 5196.666 25.1 1.011362 0.003592 225.060321 080510 1 26 51.774 5196.666 5211.774 5227.074 25.1 0.961031 0.004661 225.060674 080510 1 27 22.203 5227.074 5242.203 5257.482 25.1 0.940038 0.003549 225.061030 080510 1 27 52.951 5257.482 5272.951 5287.889 25.1 1.058306 0.003757 225.061379 080510 1 28 23.187 5287.889 5303.187 5318.297 25.1 1.019385 0.004017 225.061731 080510 1 28 53.557 5318.297 5333.557 5348.705 25.1 0.944433 0.003431 225.062083 080510 1 29 23.983 5348.705 5363.983 5379.113 25.1 0.873162 0.003584 225.062432 080510 1 29 54.128 5379.113 5394.128 5409.520 25.1 1.051594 0.004362 225.062787 080510 1 30 24.765 5409.520 5424.765 5439.928 25.1 0.983696 0.003810 225.063140 080510 1 30 55.280 5439.928 5455.280 5470.336 25.1 1.008000 0.003828 225.063490 080510 1 31 25.508 5470.336 5485.508 5500.743 25.1 0.996725 0.003972 225.063842 080510 1 31 55.918 5500.743 5515.918 5531.151 25.1 1.039125 0.003672 225.064204 080510 1 32 27.251 5531.151 5547.251 5561.559 25.1 0.997071 0.003785 225.064551 080510 1 32 57.246 5561.559 5577.246 5591.967 25.1 1.079482 0.005036 225.064894 080510 1 33 26.852 5591.967 5606.852 5622.374 25.1 1.080346 0.003918 225.065254 080510 1 33 57.977 5622.374 5637.977 5652.782 25.1 1.027987 0.003413 225.065600 080510 1 34 27.864 5652.782 5667.864 5683.190 25.1 0.952302 0.004311 225.065947 080510 1 34 57.833 5683.190 5697.833 5713.597 25.1 0.924536 0.003677 225.066309 080510 1 35 29.103 5713.597 5729.103 5744.005 25.1 1.053473 0.003904 225.066658 080510 1 35 59.238 5744.005 5759.238 5774.413 25.1 1.073607 0.003653 225.067005 080510 1 36 29.218 5774.413 5789.218 5804.821 25.1 1.005995 0.003515 225.067368 080510 1 37 0.569 5804.821 5820.569 5835.228 25.1 1.066772 0.003921 225.067717 080510 1 37 30.723 5835.228 5850.723 5865.636 25.1 1.119392 0.004048 225.068066 080510 1 38 0.910 5865.636 5880.910 5896.044 25.1 1.050834 0.003144 225.068420 080510 1 38 31.517 5896.044 5911.517 5926.451 25.1 1.057809 0.003538 225.068770 080510 1 39 1.706 5926.451 5941.706 5956.859 25.1 1.025548 0.003755 225.069120 080510 1 39 31.930 5956.859 5971.930 5987.267 25.1 0.990473 0.004242 225.069474 080510 1 40 2.539 5987.267 6002.539 6017.675 25.1 0.983505 0.003717 225.069824 080510 1 40 32.779 6017.675 6032.779 6048.082 25.1 1.032007 0.004032 225.070174 080510 1 41 3.044 6048.082 6063.044 6078.490 25.1 0.987004 0.003717 225.070531 080510 1 41 33.863 6078.490 6093.863 6108.898 25.1 0.967710 0.003485 225.070880 080510 1 42 4.016 6108.898 6124.016 6139.305 25.1 0.970380 0.003917 225.071233 080510 1 42 34.521 6139.305 6154.521 6169.713 25.1 1.020083 0.003822 225.071579 080510 1 43 4.428 6169.713 6184.428 6200.121 25.1 0.937352 0.003938 225.071929 080510 1 43 34.659 6200.121 6214.659 6230.529 25.1 1.031895 0.003241 225.072292 080510 1 44 6.061 6230.529 6246.061 6260.936 25.1 1.034158 0.002625 225.072639 080510 1 44 35.973 6260.936 6275.973 6291.344 25.1 0.912104 0.004283 225.072988 080510 1 45 6.196 6291.344 6306.196 6321.752 25.1 0.991529 0.003971 225.073347 080510 1 45 37.217 6321.752 6337.217 6352.160 25.1 1.009846 0.003513 225.073695 080510 1 46 7.217 6352.160 6367.217 6382.567 25.1 0.918613 0.003043 225.074042 080510 1 46 37.199 6382.567 6397.199 6412.975 25.1 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