46,1001 Keutsch, Frank Department of Chemistry, University of Wisconsin - Madison Formaldehyde mixing ratios from chemistry tower BEACHON-ROCS 2010 1,1 2010808,2010808 30 time_MST, (fractional day of year in MST at midpoint of measurement, where Jan. 1, 12:00am = 1) 10 1,1,1,1,1,1,1,1,1,1 -999,-999,-999,-999,-999,-999,-999,-999,-999,-999 time_MST, fractional day of year date, date in mmddyy hours_MST, hour of day in MST minutes_MST, minutes of hour in MST seconds_MST, seconds of minute in MST start_TOD_MST, time of day in seconds since midnight until beginning of measurement averaging mean_TOD_MST, average time of day in seconds since midnight of measurement averaging stop_TOD_MST, time of day in seconds since midnight until end of measurement averaging Altitude_AGL_m, altitude Above Ground Level in meters HCHO_ppbv, Mixing ratio of formaldehyde in ppbv HCHO_precision_ppbv, 1 sigma precision of mixing ratio of formaldehyde in ppbv 3 Data is presented as 1/30 Hz gradient data. Air was sampled at multiple heights on tower, via ~100'-125' 1/2" OD unheated PFA tubing 2 m measurements sampled outside instrument trailer, height value +/- 0.5 m 18 PI_CONTACT_INFO: Address: UW-Madison Dept of Chemistry, 1101 University Ave, Madison WI 53706; email: keutsch@wisc.edu; 608-262-7904 PLATFORM: Chemistry Tower near Rocky Mountain Research Station in Manitou Experimental Forest, CO LOCATION: Manitou Experimental Forest, CO; lat: 38.099; lon: -105.101; elev: 2360m amsl. ASSOCIATED_DATA: N/A INSTRUMENT_INFO: Fiber Laser-Induced Fluorescence of Gas-Phase Formaldehyde DATA_INFO: all concentration data are in ppbv. Raw data were recorded at 1Hz. Most large gaps in data stream correspond to gradient data, presented in other files. Data were filtered for known errors, points removed by this filtering are considered "missing" and given -999 UNCERTAINTY: +/-(.1 m) altitude (except 2 m measurements-see special comments); +/- 30% concentration (accuracy); concentration precision reported in columns ULOD_FLAG: -777 ULOD_VALUE: N/A LLOD_FLAG: -888 LLOD_VALUE: N/A DM_CONTACT_INFO: Joshua DiGangi; UW-Madison Chemistry Dept.; digangi@wisc.edu; 608-262-0269 PROJECT_INFO: BEARPEX field intensive; 15 June - 31 July, 2009; CA Sierra Nevada. STIPULATIONS_ON_USE: Do not quote or present without permission. Please contact PI before use. OTHER_COMMENTS: For absolute concentration error, accuracy and precision errors must be propagated. Diagnostics (cell pressure, temperature, beam power) available upon request. REVISION: R0 R0: Calibration not finalized, accuracy should improve by next revision time_PST date hours minutes seconds start_TOD_MST mean_TOD_MST stop_TOD_MST Altitude_AGL_m HCHO_ppbv HCHO_precision_ppbv 220.000390 080510 0 0 33.671 18.671 33.671 48.671 2.0 2.031250 0.030713 220.000766 080510 0 1 6.211 51.211 66.211 81.211 2.0 1.995031 0.029200 220.001143 080510 0 1 38.759 83.759 98.759 113.759 2.0 2.021165 0.030643 220.001520 080510 0 2 11.318 116.318 131.318 146.318 2.0 2.075430 0.032645 220.001897 080510 0 2 43.895 148.895 163.895 178.895 2.0 2.107869 0.038220 220.002274 080510 0 3 16.476 181.476 196.476 211.476 2.0 2.071182 0.037495 220.002651 080510 0 3 49.054 214.054 229.054 244.054 2.0 2.089375 0.034757 220.003033 080510 0 4 22.033 247.033 262.033 277.033 2.0 2.040848 0.030565 220.003406 080510 0 4 54.266 279.266 294.266 309.266 2.0 2.002668 0.038599 220.003783 080510 0 5 26.886 311.886 326.886 341.886 2.0 2.028518 0.035416 220.004145 080510 0 5 58.091 311.886 326.886 341.886 2.0 -999 -999 220.004506 080510 0 6 29.297 311.886 326.886 341.886 2.0 -999 -999 220.004867 080510 0 7 0.503 311.886 326.886 341.886 2.0 -999 -999 220.005459 080510 0 7 51.675 456.675 471.675 486.675 2.0 1.938109 0.029249 220.005837 080510 0 8 24.286 489.286 504.286 519.286 2.0 1.941189 0.040433 220.006214 080510 0 8 56.901 521.901 536.901 551.901 2.0 1.933220 0.038190 220.006592 080510 0 9 29.520 554.520 569.520 584.520 2.0 2.052965 0.030213 220.006969 080510 0 10 2.125 587.125 602.125 617.125 2.0 2.025591 0.028779 220.007347 080510 0 10 34.745 619.745 634.745 649.745 2.0 1.857543 0.030309 220.007724 080510 0 11 7.357 652.357 667.357 682.357 2.0 1.854272 0.027364 220.008101 080510 0 11 39.963 684.963 699.963 714.963 2.0 1.901578 0.032027 220.008479 080510 0 12 12.578 717.578 732.578 747.578 2.0 1.783353 0.036701 220.008856 080510 0 12 45.187 750.187 765.187 780.187 2.0 1.855130 0.032277 220.009218 080510 0 13 16.393 750.187 765.187 780.187 2.0 -999 -999 220.009579 080510 0 13 47.599 750.187 765.187 780.187 2.0 -999 -999 220.009940 080510 0 14 18.805 750.187 765.187 780.187 2.0 -999 -999 220.010532 080510 0 15 9.976 894.976 909.976 924.976 12.0 1.880541 0.033950 220.010910 080510 0 15 42.586 927.586 942.586 957.586 12.0 1.860124 0.038439 220.011287 080510 0 16 15.193 960.193 975.193 990.193 12.0 1.908568 0.042114 220.011664 080510 0 16 47.807 992.807 1007.807 1022.807 12.0 1.892082 0.029193 220.012042 080510 0 17 20.416 1025.416 1040.416 1055.416 12.0 1.877637 0.031345 220.012419 080510 0 17 53.028 1058.028 1073.028 1088.028 12.0 1.949807 0.027378 220.012797 080510 0 18 25.652 1090.652 1105.652 1120.652 12.0 1.981293 0.039186 220.013174 080510 0 18 58.272 1123.272 1138.272 1153.272 12.0 1.951167 0.034890 220.013552 080510 0 19 30.886 1155.886 1170.886 1185.886 12.0 1.956677 0.038364 220.013929 080510 0 20 3.493 1188.493 1203.493 1218.493 12.0 1.981608 0.037302 220.014290 080510 0 20 34.699 1188.493 1203.493 1218.493 12.0 -999 -999 220.014652 080510 0 21 5.905 1188.493 1203.493 1218.493 12.0 -999 -999 220.015013 080510 0 21 37.111 1188.493 1203.493 1218.493 12.0 -999 -999 220.015606 080510 0 22 28.328 1333.328 1348.328 1363.328 8.5 2.017753 0.032216 220.015983 080510 0 23 0.936 1365.936 1380.936 1395.936 8.5 1.935376 0.029240 220.016361 080510 0 23 33.549 1398.549 1413.549 1428.549 8.5 1.934325 0.039367 220.016738 080510 0 24 6.156 1431.156 1446.156 1461.156 8.5 1.904086 0.036234 220.017115 080510 0 24 38.761 1463.761 1478.761 1493.761 8.5 1.964490 0.031916 220.017493 080510 0 25 11.373 1496.373 1511.373 1526.373 8.5 1.989045 0.037275 220.017870 080510 0 25 43.979 1528.979 1543.979 1558.979 8.5 1.911479 0.037664 220.018248 080510 0 26 16.589 1561.589 1576.589 1591.589 8.5 1.952830 0.030019 220.018625 080510 0 26 49.201 1594.201 1609.201 1624.201 8.5 1.928240 0.032879 220.019002 080510 0 27 21.807 1626.807 1641.807 1656.807 8.5 1.828285 0.033003 220.019364 080510 0 27 53.013 1626.807 1641.807 1656.807 8.5 -999 -999 220.019725 080510 0 28 24.219 1626.807 1641.807 1656.807 8.5 -999 -999 220.020086 080510 0 28 55.425 1626.807 1641.807 1656.807 8.5 -999 -999 220.020678 080510 0 29 46.585 1771.585 1786.585 1801.585 2.0 1.840782 0.033853 220.021055 080510 0 30 19.195 1804.195 1819.195 1834.195 2.0 1.815354 0.026386 220.021433 080510 0 30 51.801 1836.801 1851.801 1866.801 2.0 1.892419 0.032602 220.021810 080510 0 31 24.418 1869.417 1884.417 1899.417 2.0 1.852452 0.024605 220.022188 080510 0 31 57.050 1902.050 1917.050 1932.050 2.0 1.824884 0.033746 220.022566 080510 0 32 29.666 1934.666 1949.666 1964.666 2.0 1.859836 0.035957 220.022943 080510 0 33 2.281 1967.281 1982.281 1997.281 2.0 1.897854 0.030237 220.023320 080510 0 33 34.890 1999.890 2014.890 2029.890 2.0 1.842180 0.036301 220.023698 080510 0 34 7.497 2032.497 2047.497 2062.497 2.0 1.894420 0.031886 220.024075 080510 0 34 40.119 2065.119 2080.119 2095.119 2.0 1.866826 0.020647 220.024437 080510 0 35 11.325 2065.119 2080.119 2095.119 2.0 -999 -999 220.024798 080510 0 35 42.531 2065.119 2080.119 2095.119 2.0 -999 -999 220.025159 080510 0 36 13.737 2065.119 2080.119 2095.119 2.0 -999 -999 220.025752 080510 0 37 4.931 2209.931 2224.931 2239.931 2.0 1.901218 0.031840 220.026129 080510 0 37 37.555 2242.555 2257.555 2272.555 2.0 1.889244 0.038545 220.026507 080510 0 38 10.170 2275.170 2290.170 2305.170 2.0 1.734761 0.032389 220.026884 080510 0 38 42.782 2307.782 2322.782 2337.782 2.0 1.759084 0.034332 220.027262 080510 0 39 15.400 2340.400 2355.400 2370.400 2.0 1.851903 0.033823 220.027639 080510 0 39 48.021 2373.021 2388.021 2403.021 2.0 1.883894 0.034150 220.028017 080510 0 40 20.632 2405.632 2420.632 2435.632 2.0 1.844265 0.031933 220.028394 080510 0 40 53.231 2438.231 2453.231 2468.231 2.0 1.878797 0.032488 220.028771 080510 0 41 25.843 2470.843 2485.843 2500.843 2.0 1.844328 0.027825 220.029149 080510 0 41 58.457 2503.457 2518.457 2533.457 2.0 1.790069 0.035955 220.029510 080510 0 42 29.662 2503.457 2518.457 2533.457 2.0 -999 -999 220.029871 080510 0 43 0.868 2503.457 2518.457 2533.457 2.0 -999 -999 220.030232 080510 0 43 32.074 2503.457 2518.457 2533.457 2.0 -999 -999 220.030825 080510 0 44 23.253 2648.253 2663.253 2678.253 12.0 1.918946 0.039257 220.031202 080510 0 44 55.865 2680.865 2695.865 2710.865 12.0 1.928795 0.033639 220.031580 080510 0 45 28.481 2713.481 2728.481 2743.481 12.0 1.912903 0.031777 220.031957 080510 0 46 1.089 2746.089 2761.089 2776.089 12.0 1.927824 0.031963 220.032334 080510 0 46 33.700 2778.700 2793.700 2808.700 12.0 1.924122 0.031497 220.032712 080510 0 47 6.317 2811.317 2826.317 2841.317 12.0 1.917651 0.041030 220.033090 080510 0 47 38.943 2843.943 2858.943 2873.943 12.0 1.837851 0.039398 220.033467 080510 0 48 11.557 2876.557 2891.557 2906.557 12.0 1.865181 0.036220 220.033845 080510 0 48 44.176 2909.176 2924.176 2939.176 12.0 1.857492 0.037690 220.034222 080510 0 49 16.792 2941.792 2956.792 2971.792 12.0 1.855491 0.039500 220.034583 080510 0 49 47.998 2941.792 2956.792 2971.792 12.0 -999 -999 220.034944 080510 0 50 19.204 2941.792 2956.792 2971.792 12.0 -999 -999 220.035306 080510 0 50 50.409 2941.792 2956.792 2971.792 12.0 -999 -999 220.035898 080510 0 51 41.597 3086.597 3101.597 3116.597 8.5 1.917889 0.030558 220.036276 080510 0 52 14.214 3119.214 3134.214 3149.214 8.5 1.983857 0.023071 220.036653 080510 0 52 46.819 3151.819 3166.819 3181.819 8.5 1.865397 0.032590 220.037030 080510 0 53 19.426 3184.426 3199.426 3214.426 8.5 1.734668 0.052332 220.037408 080510 0 53 52.028 3217.028 3232.028 3247.028 8.5 1.775960 0.038272 220.037785 080510 0 54 24.648 3249.648 3264.648 3279.648 8.5 1.799733 0.033029 220.038163 080510 0 54 57.272 3282.272 3297.272 3312.272 8.5 1.774594 0.034581 220.038540 080510 0 55 29.878 3314.878 3329.878 3344.878 8.5 1.753765 0.039998 220.038918 080510 0 56 2.479 3347.479 3362.479 3377.479 8.5 1.820000 0.034010 220.039295 080510 0 56 35.099 3380.099 3395.099 3410.099 8.5 1.866052 0.028792 220.039656 080510 0 57 6.305 3380.099 3395.099 3410.099 8.5 -999 -999 220.040017 080510 0 57 37.511 3380.099 3395.099 3410.099 8.5 -999 -999 220.040379 080510 0 58 8.716 3380.099 3395.099 3410.099 8.5 -999 -999 220.040971 080510 0 58 59.875 3524.875 3539.875 3554.875 2.0 1.754532 0.028156 220.041348 080510 0 59 32.486 3557.486 3572.486 3587.486 2.0 1.710867 0.031235 220.041726 080510 1 0 5.097 3590.097 3605.097 3620.097 2.0 1.728447 0.030262 220.042103 080510 1 0 37.712 3622.712 3637.712 3652.712 2.0 1.691897 0.035974 220.042481 080510 1 1 10.320 3655.320 3670.320 3685.320 2.0 1.800539 0.035299 220.042858 080510 1 1 42.939 3687.939 3702.939 3717.939 2.0 1.665850 0.037114 220.043236 080510 1 2 15.555 3720.555 3735.555 3750.555 2.0 1.685119 0.034748 220.043613 080510 1 2 48.164 3753.164 3768.164 3783.164 2.0 1.670681 0.034687 220.043990 080510 1 3 20.766 3785.766 3800.766 3815.766 2.0 1.731497 0.035097 220.044368 080510 1 3 53.374 3818.374 3833.374 3848.374 2.0 1.668443 0.030773 220.044729 080510 1 4 24.580 3818.374 3833.374 3848.374 2.0 -999 -999 220.045090 080510 1 4 55.786 3818.374 3833.374 3848.374 2.0 -999 -999 220.045451 080510 1 5 26.991 3818.374 3833.374 3848.374 2.0 -999 -999 220.046044 080510 1 6 18.203 3963.203 3978.203 3993.203 2.0 1.760053 0.034201 220.046421 080510 1 6 50.817 3995.817 4010.817 4025.817 2.0 1.730812 0.031249 220.046797 080510 1 7 23.288 4028.288 4043.288 4058.288 2.0 1.804933 0.031165 220.047177 080510 1 7 56.050 4061.050 4076.050 4091.050 2.0 1.777792 0.030120 220.047554 080510 1 8 28.657 4093.657 4108.657 4123.657 2.0 1.786096 0.028132 220.047931 080510 1 9 1.261 4126.261 4141.261 4156.261 2.0 1.799189 0.033076 220.048309 080510 1 9 33.865 4158.865 4173.865 4188.865 2.0 1.808844 0.041127 220.048686 080510 1 10 6.469 4191.469 4206.469 4221.469 2.0 1.924364 0.035455 220.049063 080510 1 10 39.083 4224.083 4239.083 4254.083 2.0 1.797132 0.026576 220.049441 080510 1 11 11.687 4256.687 4271.687 4286.687 2.0 1.851138 0.026743 220.049802 080510 1 11 42.893 4256.687 4271.687 4286.687 2.0 -999 -999 220.050163 080510 1 12 14.099 4256.687 4271.687 4286.687 2.0 -999 -999 220.050524 080510 1 12 45.305 4256.687 4271.687 4286.687 2.0 -999 -999 220.051117 080510 1 13 36.503 4401.503 4416.503 4431.503 12.0 1.820637 0.030964 220.051494 080510 1 14 9.114 4434.114 4449.114 4464.114 12.0 1.825598 0.033228 220.051872 080510 1 14 41.728 4466.728 4481.728 4496.728 12.0 1.960780 0.039810 220.052249 080510 1 15 14.331 4499.331 4514.331 4529.331 12.0 1.938761 0.030012 220.052627 080510 1 15 46.942 4531.942 4546.942 4561.942 12.0 1.742823 0.031418 220.053004 080510 1 16 19.554 4564.554 4579.554 4594.554 12.0 1.805758 0.029926 220.053382 080510 1 16 52.168 4597.168 4612.168 4627.168 12.0 1.813447 0.031412 220.053759 080510 1 17 24.777 4629.777 4644.777 4659.777 12.0 1.816014 0.032738 220.054136 080510 1 17 57.392 4662.392 4677.392 4692.392 12.0 1.865006 0.030952 220.054514 080510 1 18 29.990 4694.990 4709.990 4724.990 12.0 1.884170 0.034899 220.054875 080510 1 19 1.196 4694.990 4709.990 4724.990 12.0 -999 -999 220.055236 080510 1 19 32.402 4694.990 4709.990 4724.990 12.0 -999 -999 220.055597 080510 1 20 3.608 4694.990 4709.990 4724.990 12.0 -999 -999 220.056190 080510 1 20 54.782 4839.782 4854.782 4869.782 8.5 1.810606 0.032391 220.056567 080510 1 21 27.391 4872.391 4887.391 4902.391 8.5 1.812852 0.038727 220.056945 080510 1 22 0.009 4905.009 4920.009 4935.009 8.5 1.718068 0.037451 220.057322 080510 1 22 32.620 4937.620 4952.620 4967.620 8.5 1.743557 0.028275 220.057699 080510 1 23 5.224 4970.224 4985.224 5000.224 8.5 1.768264 0.032219 220.058077 080510 1 23 37.834 5002.834 5017.834 5032.834 8.5 1.772325 0.036783 220.058454 080510 1 24 10.443 5035.443 5050.443 5065.443 8.5 1.656794 0.030991 220.058831 080510 1 24 43.040 5068.040 5083.040 5098.040 8.5 1.701034 0.028784 220.059209 080510 1 25 15.653 5100.653 5115.653 5130.653 8.5 1.734328 0.031270 220.059586 080510 1 25 48.267 5133.267 5148.267 5163.267 8.5 1.744336 0.034613 220.059948 080510 1 26 19.473 5133.267 5148.267 5163.267 8.5 -999 -999 220.060309 080510 1 26 50.679 5133.267 5148.267 5163.267 8.5 -999 -999 220.060670 080510 1 27 21.884 5133.267 5148.267 5163.267 8.5 -999 -999 220.061263 080510 1 28 13.085 5278.085 5293.085 5308.085 2.0 1.616978 0.035838 220.061640 080510 1 28 45.695 5310.695 5325.695 5340.695 2.0 1.604778 0.029853 220.062017 080510 1 29 18.308 5343.308 5358.308 5373.308 2.0 1.599133 0.030852 220.062395 080510 1 29 50.929 5375.929 5390.929 5405.929 2.0 1.627050 0.026853 220.062772 080510 1 30 23.538 5408.538 5423.538 5438.538 2.0 1.643261 0.032771 220.063150 080510 1 30 56.162 5441.162 5456.162 5471.162 2.0 1.665151 0.029995 220.063528 080510 1 31 28.781 5473.781 5488.781 5503.781 2.0 1.671044 0.034552 220.063905 080510 1 32 1.391 5506.391 5521.391 5536.391 2.0 1.528981 0.020562 220.064282 080510 1 32 34.007 5539.007 5554.007 5569.007 2.0 1.628858 0.029880 220.064660 080510 1 33 6.610 5571.610 5586.610 5601.610 2.0 1.679150 0.029874 220.065021 080510 1 33 37.816 5571.610 5586.610 5601.610 2.0 -999 -999 220.065382 080510 1 34 9.022 5571.610 5586.610 5601.610 2.0 -999 -999 220.065743 080510 1 34 40.228 5571.610 5586.610 5601.610 2.0 -999 -999 220.066336 080510 1 35 31.412 5716.412 5731.412 5746.412 2.0 1.684932 0.033607 220.066713 080510 1 36 4.029 5749.029 5764.029 5779.029 2.0 1.639442 0.036057 220.067091 080510 1 36 36.639 5781.639 5796.639 5811.639 2.0 1.668443 0.037755 220.067468 080510 1 37 9.246 5814.246 5829.246 5844.246 2.0 1.679054 0.034514 220.067846 080510 1 37 41.860 5846.860 5861.860 5876.860 2.0 1.576392 0.031367 220.068223 080510 1 38 14.476 5879.476 5894.476 5909.476 2.0 1.665399 0.032507 220.068600 080510 1 38 47.082 5912.082 5927.082 5942.082 2.0 1.646301 0.031163 220.068978 080510 1 39 19.691 5944.691 5959.691 5974.691 2.0 1.583455 0.030335 220.069355 080510 1 39 52.307 5977.307 5992.307 6007.307 2.0 1.591314 0.026488 220.069733 080510 1 40 24.914 6009.914 6024.914 6039.914 2.0 1.549527 0.024002 220.070094 080510 1 40 56.120 6009.914 6024.914 6039.914 2.0 -999 -999 220.070455 080510 1 41 27.326 6009.914 6024.914 6039.914 2.0 -999 -999 220.070816 080510 1 41 58.532 6009.914 6024.914 6039.914 2.0 -999 -999 220.071409 080510 1 42 49.715 6154.715 6169.715 6184.715 12.0 1.654892 0.032442 220.071786 080510 1 43 22.332 6187.332 6202.332 6217.332 12.0 1.665846 0.028485 220.072164 080510 1 43 54.949 6219.949 6234.949 6249.949 12.0 1.738356 0.036358 220.072541 080510 1 44 27.547 6252.547 6267.547 6282.547 12.0 1.619192 0.034008 220.072918 080510 1 45 0.154 6285.154 6300.154 6315.154 12.0 1.705272 0.029538 220.073296 080510 1 45 32.755 6317.755 6332.755 6347.755 12.0 1.721923 0.031486 220.073673 080510 1 46 5.364 6350.364 6365.364 6380.364 12.0 1.750339 0.031222 220.074051 080510 1 46 37.966 6382.966 6397.966 6412.966 12.0 1.714404 0.021446 220.074428 080510 1 47 10.579 6415.579 6430.579 6445.579 12.0 1.699663 0.027432 220.074805 080510 1 47 43.186 6448.186 6463.186 6478.186 12.0 1.674411 0.028518 220.075167 080510 1 48 14.391 6448.186 6463.186 6478.186 12.0 -999 -999 220.075528 080510 1 48 45.597 6448.186 6463.186 6478.186 12.0 -999 -999 220.075889 080510 1 49 16.803 6448.186 6463.186 6478.186 12.0 -999 -999 220.076481 080510 1 50 7.996 6592.996 6607.996 6622.996 8.5 1.568388 0.027680 220.076859 080510 1 50 40.608 6625.608 6640.608 6655.608 8.5 1.581604 0.041165 220.077236 080510 1 51 13.225 6658.225 6673.225 6688.225 8.5 1.487110 0.032326 220.077614 080510 1 51 45.834 6690.834 6705.834 6720.834 8.5 1.536188 0.035448 220.077991 080510 1 52 18.448 6723.448 6738.448 6753.448 8.5 1.574670 0.036658 220.078369 080510 1 52 51.058 6756.058 6771.058 6786.058 8.5 1.567840 0.029884 220.078746 080510 1 53 23.675 6788.675 6803.675 6818.675 8.5 1.495271 0.029570 220.079124 080510 1 53 56.289 6821.289 6836.289 6851.289 8.5 1.541968 0.034353 220.079501 080510 1 54 28.907 6853.907 6868.907 6883.907 8.5 1.508830 0.034964 220.079879 080510 1 55 1.523 6886.523 6901.523 6916.523 8.5 1.528620 0.033173 220.080240 080510 1 55 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