27 16 # first data line, number of data lines Reference: JPL Publication 97-4 Chemical Kinetics and Photochemical Data for Use in Stratospheric Modeling Evaluation Number 12 January 15, 1997 page 167 CH3OOH + hv -> Products "Vaghjiani and Ravishankara [310] mesured the cross sections of CH3OOH by monitoring the CH3OOH concentration via trapping and titration. These results are recommended and are listed in Table 24. The earlier results of Molina and Arguello [210] are consistently 40% higher than the values shown in Table 24; this difference is believed to be due to difficulty in trapping CH3OOH and measuring its concentration. CH3OOH dissociates upon light absorption to give CH3O with unit quantum yield (Vaghjiani and Ravishankara, [311]); these authors also observed some production of H and O atmos at shorter wavelengths (i.e. 193 nm). Thelen et al. [302] report unit quantum yield for OH production at 248 and 193 nm, in agreement with the results of Vaghjiani and Ravishankara." *** note some minor difference relative to JPL-94 Table 24. Absorption Cross section of CH3OOH -------------------- lambda 10E20 sigma (nm) (cm^2) -------------------- 210 31.2 220 15.4 230 9.62 240 6.05 250 3.98 260 2.56 270 1.70 280 1.09 290 0.69 300 0.41 310 0.24 320 0.14 330 0.079 340 0.047 350 0.027 360 0.016