Reference: JPL Publication 94-26 Chemical Kinetics and Photochemical Data for Use in Stratospheric Modeling Evaluation Number 11 December 15, 1994 page 125 ff. N2O + hv -> N2 + O(1D) "The recommended values are taken from the work of Selwyn et al. [1403], who measured the temperature dependence of the absorption cross section in the atmospherically relevant wavelength region. They have fitted their data with the expression shown in Table 16; Table 17 presents the romm temperature data. Hubrich and Stuhl [712] remeasured the N2O cross sections at 298K and 208K and Merienne et al [1072] in the range from 220K to 296K. The results of these two sets of measurements are in very good agreement with those of Selwyn et al. The quantum yield for photodissociation is unity and the products are N2 and O(1D) (Zelikoff and Aschenbrand [1777]; Paraskevopoulos and Cvetanovic [1223]; Preston and Barr [1282]; Simonaitis et al. [1427]). The yield of N(4s) and NO(2Pi) is less than 1% (Greenblatt and Ravishankara [596])." Table 16. Mathematical Expression for Absorption Cross Sections of N2O as a Function of Temperature ---------------------------------------------------------------------------- 4 3 __ n __ n ln sigma(lambda,T) = > A lambda + (T-300) exp( > B lambda ) -- n -- n n=0 n=0 Where T: temperature K; lambda: nm; A0 = 68.21023 B0 = 123.4014 A1 = -4.071805 B1 = -2.116255 A2 = 4.301146E-02 B2 = 1.111572E-02 A3 = -1.777846E-04 B3 = -1.881058E-05 A4 = 2.520672E-07 Range 173 to 240 nm; 194 to 320 K; ----------------------------------------------------------------------------