29 40 # first data record, number of data records Reference: JPL Publication 94-26 Chemical Kinetics and Photochemical Data for Use in Stratospheric Modeling Evaluation Number 11 December 15, 1994 page 165 ff CF3Br (Halon-1301) + hv -> Products "The preferred absorption cross sections at 298K, listed in Table 54, are the mean of the values reported by Gillotay and Simon [568] at 2 nm intervals and Burkholder et al. [219] at 1 nm intervals over the wavelength range where the agreement is acceptable, i.e., better than 70%. At longer wavelengths Burkholder et al. [219] measure larger values than those reported by Gillotay and Simon. However, the agreement in the wavelength range 190-230 nm among the three studies is excellent. The temperature dependence of the cross sections has been measured by Gillotay and Simon as well as Burkholder et al. [219]. The agreement between these two studies is poor. We have not evaluated the temperature dependedence of the cross sections and the readers are referred to the original publications for this information. For all the bromofluoromethanes, photolysis is expected to cleave the C-Br bond with unit quantum efficiency." Table 54. Absorption Cross Sections of CF3Br at 298 K. ------------------------------------------------------------------------- lambda (nm) 1E20 sigma (cm^2) ------------------------------------------------------------------------- 190 6.4 192 7.5 194 8.5 196 9.5 198 10.4 200 11.2 202 11.8 204 12.2 206 12.4 208 12.4 210 12.0 212 11.4 214 10.7 216 9.8 218 8.8 220 7.7 222 6.7 224 5.7 226 4.7 228 3.8 230 3.1 232 2.4 234 1.9 236 1.4 238 1.1 240 0.81 242 0.59 244 0.43 246 0.31 248 0.22 250 0.16 252 0.11 254 0.076 256 0.053 258 0.037 260 0.026 262 0.018 264 0.012 266 0.009 268 0.006