31 11 # first data record, number of data records Reference: JPL Publication 94-26 Chemical Kinetics and Photochemical Data for Use in Stratospheric Modeling Evaluation Number 11 December 15, 1994 page 154 ff. CH3CCl3 + hv -> Products "The absorption cross sections have been measured by Robbuns [1331], Vanlaethem-Meuree et al. [1615], Hubrich and Stuhl [712], and Nayak et al. [1148]. Hubrich and Stuhl corrected the results to account for the presence of a UV-absorbing stabilizer in their samples, a correction which might account for the rather large discrepancy with the other three sets of measurements, which are in good agreement with each other. The recommended values are taken from Vanlaethem-Meuree et al. [1615], who report values at 210 K, 230 K, 250 K, 270 K and 295 K, every 2 nm, and in a separate table at wavelengths corresponding to the wavenumber intervals generally used in stratospheric photodissociation calculations. Table 45 lists the values at 210 K, 250 K and 295 K, every 5 nm; the odd wavelength values were computed by linear interpolation. These values agree within 10% with those reported by Nayak et al.; these authors carried out measurements between 160 and 260 nm, from 220 to 330 K." Table 45. Absorption Cross Scetions of CH3CCl3. ----------------------------------------------------------------------- lambda 1E20 sigma (cm^2) (nm) 295K 250K 210K ----------------------------------------------------------------------- 185 265 265 265 190 192 192 192 200 81.0 81.0 81.0 205 46.0 44.0 42.3 210 24.0 21.6 19.8 215 10.3 8.67 7.47 220 4.15 3.42 2.90 225 1.76 1.28 0.97 230 0.700 0.470 0.330 235 0.282 0.152 0.088 240 0.102 0.048 0.024