29 44 # first data record, number of data records Reference: JPL Publication 94-26 Chemical Kinetics and Photochemical Data for Use in Stratospheric Modeling Evaluation Number 11 December 15, 1994 page 150 CCl4 + hv -> Products "Tables 39, 40 and 41 list the present recommendations for the cross sections of CCl4, CCl3F and CCl2F2, respectively. These data are given by the mean of the values reported by various groups, i.e., Hubrich et al. [713], Hubrich and Stuhl [712], Vanlaethem-Meuree et al. [1613, 1614], and Green and Wayne [594], as well as those referred to in earlier evaluations (CODATA [347]). Absorption cross sections for these species over the temperature range 295-210K have also been reported by Simon et al. [1425]. These results are in generally good agreement with the present recommendations. Expressions for the temperature dependence of the CCl3F and CCl2F2 cross sections are given at the bottom of Tables 40 and 41, respetively. These expressions are valid in the wavelength range of maximum solar photodissociation, i.e., about 190-210 nm, but may not exactly reproduce the experimental temperature dependences outside this wavelength range. However, J-value calculations should not be affected." Table 39. Absorption Cross Sections of CCl4 ------------------------------------------------------------------- lambda (nm) 1E20 sigma (cm^2) ------------------------------------------------------------------- 174 995 176 1007 178 976 180 772 182 589 184 450 186 318 188 218 190 144 192 98.9 194 74.4 196 68.2 198 66.0 200 64.8 202 62.2 204 60.4 206 56.5 208 52.0 210 46.6 212 39.7 214 33.3 216 27.2 218 21.8 220 17.0 222 13.0 224 9.61 226 7.19 228 5.49 230 4.07 232 3.01 234 2.16 236 1.51 238 1.13 240 0.784 242 0.579 244 0.414 246 0.314 248 0.240 250 0.183 255 0.0661 260 0.0253 265 0.0126 270 0.0061 275 0.0024