BrO -> Br + O. The BrO radical has a banded spectrum in the 290¨C380 nm range. The strongest absorption feature is around 338 nm. The measured cross sections are both temperature- and resolution dependent. As an example, the spectrum measured by Wahner et al. [423] is shown in Figure 4-4. The bands are due to a vibrational progression in the A <- X system, and the location of the bands, along with the assignments and cross sections measured using 0.4 nm resolution, are shown in Table 4-62. BrO is expected to dissociate upon light absorption. As a guide, the cross sections averaged over 5 nm wavelength intervals are taken from the work of Cox et al. [92], and are listed in Table 4-63. These authors estimate a BrO lifetime against atmospheric photodissociation of ~20 seconds at the earth's surface, for a solar zenith angle of 30 deg. The earlier BrO cross section measurements were carried out mostly around 338 nm, and these have been reviewed by CODATA ([81,82]). wlow wupper xs, 1e-20 cm2 300 305 200 305 310 259 310 315 454 315 320 391 320 325 600 325 330 753 330 335 628 335 340 589 340 345 515 345 350 399 350 355 228 355 360 172 360 365 161 365 370 92 370 375 51